Now showing items 1-6 of 6
Serendipitous preparation of fac-(aceto-nitrile-κN)tri-chlorido-[(1,2,5,6-η)-cyclo-octa-1,5-diene]iridium(III).
(International Union of Crystallography, 2015-04-01)
A reaction between [(COD)IrCl]2 (COD is cyclo-octa-1,5-diene), HCl and indene failed to provide the hoped for chlorido-indenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an ...
mer-Trichloridotris(tetrahydrothiophene-κS)-iridium(III): preparation and comparison with other mer trichloridotris(tetrahydrothiophene-κS)metal complexes
(International Union of Crystallography, 2016-08-09)
The title complex, [IrCl₃(C₄H₈S)₃], was prepared according to a literature method. A suitable crystal was obtained by diffusion of pentane into a dichloromethane solution and analyzed by single-crystal X-ray diffraction ...
Crystal structure of di-μ-chlorido-bis-[di-chlorido-bis-(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chlorido-iridium(III) dinuclear complex with methanol ligands.
The reaction between IrCl3·xH2O in methanol led to the formation of small amounts of the title compound, [Ir2Cl6(CH3OH)4]·2H2O, which consists of two IrCl4O2 octa-hedra sharing an edge via chloride bridges. The mol-ecule ...
Epitaxial thin films of pyrochlore iridate Bi₂₊ₓIr₂₋ᵧO₇₋δ: structure, defects and transport properties
While pyrochlore iridate thin films are theoretically predicted to possess a variety of emergent topological properties, experimental verification of these predictions can be obstructed by the challenge in thin film growth. ...
Crystal structures of fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) monohydrate and fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs.
(International Union of Crystallography, 2015-02-01)
The crystal structures of two solvates of fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal ...
Crystal structures of (eta(4)-cycloocta-1,5-diene)bis-(1,3-dimethylimidazol-2-ylidene)iridium(I) iodide and (eta(4)-cycloocta-1,5-diene)bis(1,3-diethyl-imidazol-2-ylidene)iridium(I) iodide
The title complexes, (eta(4) -cycloocta-1,5-diene)bis(1,3-dimethylimidazol-2-yl-idene)iridium(I) iodide, [Ir(C5H8N2)(2)(C8H12)]I, (1) and (eta(4)-cycloocta-1,5-diene)bis(1,3-diethylimidazol-2-ylidene)iridium(I) iodide, ...