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dc.contributor.authorUsov, Pavel M.
dc.contributor.authorAhrenholtz, Spencer R.
dc.contributor.authorMaza, William A.
dc.contributor.authorStratakes, Bethany
dc.contributor.authorEpley, Charity C.
dc.contributor.authorKessinger, Matthew C.
dc.contributor.authorZhu, Jie
dc.contributor.authorMorris, Amanda
dc.date.accessioned2017-05-01T06:42:17Z
dc.date.available2017-05-01T06:42:17Z
dc.date.issued2016-10-06
dc.identifierc6ta05877a.pdf
dc.identifierc6ta05877a1.pdf
dc.identifier.issn2050-7488
dc.identifier.urihttp://hdl.handle.net/10919/77558
dc.description.abstractHere, we demonstrate a new strategy for cooperative catalysis and proton abstraction via the incorporation of independent species competent in the desired reactivity into a metal–organic framework (MOF) thin film. The highly porous MOF, designated as PCN-224-Ni, is constructed by Zr–oxo nodes and nickel(II) porphyrin linkers. Films of PCN-224-Ni were grown in situ on FTO and were found to electrochemically facilitate the water oxidation reaction at near neutral pH.
dc.format.extent16818-16823
dc.format.mimetypeapplication/pdf
dc.language.isoen_US
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofRoyal Society of Chemistry Gold Open Access - 2016
dc.rightsCreative Commons Attribution-NonCommercial 3.0 Unporteden
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/en
dc.titleCooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film
dc.typeArticle - Refereed
dc.rights.holderUsov, Pavel M.en
dc.rights.holderAhrenholtz, Spencer R.en
dc.rights.holderMaza, William A.en
dc.rights.holderStratakes, Bethanyen
dc.rights.holderEpley, Charity C.en
dc.rights.holderKessinger, Matthew C.en
dc.rights.holderZhu, Jieen
dc.rights.holderMorris, Amanda J.en
dc.contributor.departmentChemistryen_US
dc.title.serialJournal of Materials Chemistry A
dc.identifier.doihttps://doi.org/10.1039/c6ta05877a
dc.identifier.volume4
dc.identifier.issue43
dc.type.dcmitypeText
dc.type.dcmitypeDataset
dc.identifier.eissn2050-7496


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Creative Commons Attribution-NonCommercial 3.0 Unported
License: Creative Commons Attribution-NonCommercial 3.0 Unported