μ-Oxido-bis-[hydridotris(tri-methyl-phosphane-κP)iridium(III)](Ir-Ir) bis-(tetra-fluorido-borate) dihydrate.

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dc.contributor.authorMerola, Joseph S.en
dc.contributor.authorHusebo, Trang Leen
dc.contributor.departmentChemistryen
dc.coverage.spatialUnited Statesen
dc.date.accessioned2018-03-05T14:44:24Zen
dc.date.available2018-03-05T14:44:24Zen
dc.date.issued2014-04-01en
dc.description.abstractThe title compound, [Ir2H2O(C3H9P)6](BF4)2·2H2O, was isolated from the reaction between [Ir(COD)(PMe3)3]BF4 and H2 in water (COD is cyclo-octa-1,5-diene). The asymmetric unit consists of one Ir(III) atom bonded to three PMe3 groups, one hydride ligand and half an oxide ligand, in addition to a BF4 (-) counter-ion and one water molecule of hydration. The single oxide ligand bridging two Ir(III) atoms is disordered across an inversion center with each O atom having a 50% site occupancy. Each Ir(III) atom has three PMe3 groups occupying facial positions, with the half-occupancy O atoms, a hydride ligand and an Ir-Ir bond completing the coordination sphere. The Ir-Ir distance is 2.8614 (12) Å, comparable to other iridium(III) metal-metal bonds. Two water mol-ecules hydrogen bond to two BF4 (-) anions in the unit cell.en
dc.description.versionPublished versionen
dc.format.extentm122 - m123 page(s)en
dc.format.mimetypeapplication/pdfen
dc.identifier.doihttps://doi.org/10.1107/S160053681400453Xen
dc.identifier.issn1600-5368en
dc.identifier.issuePt 4en
dc.identifier.issue4en
dc.identifier.orcidMerola, J [0000-0002-1743-1777]en
dc.identifier.urihttp://hdl.handle.net/10919/82441en
dc.identifier.volume70en
dc.languageengen
dc.publisherElsevieren
dc.relation.urihttps://www.ncbi.nlm.nih.gov/pubmed/24826089en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.titleμ-Oxido-bis-[hydridotris(tri-methyl-phosphane-κP)iridium(III)](Ir-Ir) bis-(tetra-fluorido-borate) dihydrate.en
dc.title.serialActa Crystallogr Sect E Struct Rep Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
dc.type.otherJournal Articleen
dcterms.dateAccepted2014-02-26en
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen
pubs.organisational-group/Virginia Tech/University Research Institutesen
pubs.organisational-group/Virginia Tech/University Research Institutes/Fralin Life Sciencesen
pubs.organisational-group/Virginia Tech/University Research Institutes/Fralin Life Sciences/Fralin Affiliated Facultyen

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