Crystal structures of fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) monohydrate and fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs.

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dc.contributor.authorMerola, Joseph S.en
dc.contributor.authorFranks, Marion A.en
dc.contributor.departmentChemistryen
dc.coverage.spatialEnglanden
dc.date.accessioned2016-09-21T16:16:30Zen
dc.date.available2016-09-21T16:16:30Zen
dc.date.issued2015-02-01en
dc.description.abstractThe crystal structures of two solvates of fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3]·0.5CH3OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013). Polyhedron, 54, 67-73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.en
dc.description.sponsorshipACS–PRFen
dc.description.sponsorship23961-C1en
dc.description.sponsorshipNational Science Foundationen
dc.description.sponsorshipCHE-902244en
dc.description.sponsorshipVirginia Tech. Open Access Subvention Funden
dc.description.versionPublished versionen
dc.format.extent226 - 230 page(s)en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationMerola, J. S., & Franks, M. A. (2015). Crystal structures of fac-tri­chlorido­tris­­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs. Acta Crystallographica Section E, 71(2), 226-230. doi:doi:10.1107/S205698901500151en
dc.identifier.doihttps://doi.org/10.1107/S2056989015001516en
dc.identifier.eissn2056-9890en
dc.identifier.issuePt 2en
dc.identifier.sourceurlhttp://journals.iucr.org/e/issues/2015/02/00/pk2543/index.htmlen
dc.identifier.urihttp://hdl.handle.net/10919/72970en
dc.identifier.volume71en
dc.languageengen
dc.publisherInternational Union of Crystallographyen
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/25878826en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectcrystal structureen
dc.subjectiridiumen
dc.subjectisotypismen
dc.subjectphosphane ligandsen
dc.subjectrhodiumen
dc.titleCrystal structures of fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) monohydrate and fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs.en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
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pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
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