Self-Assembly Motifs of Water in Crystals of Palladium β-Amino Acid Complexes Influenced by Methyl Substitution on the Amino Acid Backbone

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dc.contributor.authorHobart, David B. Jr.en
dc.contributor.authorPatel, Vraj G.en
dc.contributor.authorPendergrass, Heatheren
dc.contributor.authorFlorio, Jacquelineen
dc.contributor.authorMerola, Joseph S.en
dc.contributor.departmentChemistryen
dc.date.accessioned2019-11-12T13:34:38Zen
dc.date.available2019-11-12T13:34:38Zen
dc.date.issued2019-11-09en
dc.date.updated2019-11-12T08:29:55Zen
dc.description.abstractAmino acid complexes of transition metals show interesting hydrogen-bonding motifs. In this paper, the syntheses and structures of three <i>&beta;</i>-amino acid complexes of palladium that differ only by the substitution on the <i>&beta;</i>-carbon will be discussed. With only hydrogen on the <i>&beta;</i>-carbon, no additional water is incorporated into the crystal lattice and hydrogen-bonding is all complex-to-complex. With the addition of one and two methyl groups on the amino acid <i>&beta;</i>-carbon, water is incorporated into the crystal lattice giving intricate water networks held together by complex-to-water and water-to-water hydrogen-bonding networks.en
dc.description.versionPublished versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationHobart, D.B.; Patel, V.G.; Pendergrass, H.; Florio, J.; Merola, J.S. Self-Assembly Motifs of Water in Crystals of Palladium β-Amino Acid Complexes Influenced by Methyl Substitution on the Amino Acid Backbone. Crystals 2019, 9, 590.en
dc.identifier.doihttps://doi.org/10.3390/cryst9110590en
dc.identifier.urihttp://hdl.handle.net/10919/95504en
dc.language.isoenen
dc.publisherMDPIen
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectpalladiumen
dc.subjectamino aciden
dc.subjectmetal complexen
dc.subjecthydrogen bondingen
dc.subjectcrystal latticeen
dc.titleSelf-Assembly Motifs of Water in Crystals of Palladium β-Amino Acid Complexes Influenced by Methyl Substitution on the Amino Acid Backboneen
dc.title.serialCrystalsen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
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