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Browsing by Author "Collier, C. Patrick"

Now showing 1 - 4 of 4
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    Controlling condensation and frost growth with chemical micropatterns
    Boreyko, Jonathan B.; Hansen, Ryan R.; Murphy, Kevin R.; Nath, Saurabh; Retterer, Scott T.; Collier, C. Patrick (Springer Nature, 2016-01-22)
    In-plane frost growth on chilled hydrophobic surfaces is an inter-droplet phenomenon, where frozen droplets harvest water from neighboring supercooled liquid droplets to grow ice bridges that propagate across the surface in a chain reaction. To date, no surface has been able to passively prevent the in-plane growth of ice bridges across the population of supercooled condensate. Here, we demonstrate that when the separation between adjacent nucleation sites for supercooled condensate is properly controlled with chemical micropatterns prior to freezing, inter-droplet ice bridging can be slowed and even halted entirely. Since the edge-to-edge separation between adjacent supercooled droplets decreases with growth time, deliberately triggering an early freezing event to minimize the size of nascent condensation was also necessary. These findings reveal that inter-droplet frost growth can be passively suppressed by designing surfaces to spatially control nucleation sites and by temporally controlling the onset of freezing events.
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    Droplet Evaporation on Hot Micro-Structured Superhydrophobic Surfaces: Analysis of Evaporation from Droplet Cap and Base Surfaces
    Huang, Wenge; He, Xukun; Liu, Cong; Li, Xiaojie; Liu, Yahua; Collier, C. Patrick; Srijanto, Bernadeta R.; Liu, Jiansheng; Cheng, Jiangtao (Elsevier, 2022-04-01)
    In this study, evaporation of sessile water droplets on hot micro-structured superhydrophobic surfaces is experimentally and theoretically investigated. Water droplets of 4 µL are placed on micro-pillared silicon substrates with the substrate temperature heated up to 120°C. A comprehensive thermal circuit model is developed to analyze the effects of substrate roughness and substrate temperature on the sessile droplet evaporation. For the first time, two components of heat and mass transfer, i.e., one from the droplet cap surface and the other from the droplet base surface, during droplet evaporation are distinguished and systematically studied. As such, the evaporation heat transfer rates from both the droplet cap surface and the interstitial liquid-vapor interface between micropillars at the droplet base are calculated in various conditions. For droplet evaporation on the heated substrates in the range of 40°C – 80°C, the predicted droplet cap temperature matches well with the experimental results. During the constant contact radius mode of droplet evaporation, the decrease of evaporation rate from the droplet base contributes most to the continuously decreasing overall evaporation heat transfer rate, whereas the decrease of evaporation rate from the droplet cap surface is dominant in the constant contact angle mode. The influence of internal fluid flow is considered for droplet evaporation on substrates heated above 100°C, and an effective thermal conductivity is adopted as a correction factor to account for the effect of convection heat transfer inside the droplet. Temperature differences between the droplet base and the substrate base are estimated to be about 2°C, 5°C, 8°C, 13°C and 18°C for droplet evaporation on substrates heated at 40°C, 60°C, 80°C, 100°C, and 120°C, respectively, elucidating the delayed or depressed boiling of water droplets on a heated rough surface due to evaporative cooling.
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    Passive anti-frosting surface comprised of microscopic wettability patterns containing sacrificial ice
    (United States Patent and Trademark Office, 2020-05-26)
    A method and device for reducing ice and frost on a surface comprising a wettable pattern on a surface. The pattern is wetted with water which is frozen into ice to create overlapping hygroscopic that cover the surface.
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    Self-Stabilizing Transpiration in Synthetic Leaves
    Shi, Weiwei; Vieitez, Joshua R.; Berrier, Austin S.; Roseveare, Matthew W.; Surinach, Daniel A.; Srijanto, Bernadeta R.; Collier, C. Patrick; Boreyko, Jonathan B. (2019-04-10)
    Over the past decade, synthetic trees have been engineered to mimic the transpiration cycle of natural plants, but the leaves are prone to dry out beneath a critical relative humidity. Here, we create large-area synthetic leaves whose transpiration process is remarkably stable over a wide range of humidities, even without synthetic stomatal chambers atop the nanopores of the leaf. While the water menisci cannot initially withstand the Kelvin stress of the subsaturated air, they self-stabilized by locally concentrating vapor within the top layers of nanopores that have dried up. Transpiration rates were found to vary nonmonotonically with the ambient humidity because of the tradeoff of dry air increasing the retreat length of the menisci. It is our hope that these findings will encourage the development of large-area synthetic trees that exhibit excellent stability and high throughput for water-harvesting applications.