VTechWorks Repository :: Browsing by Author "Daniels, W. Lee"

Browsing by Author "Daniels, W. Lee"

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An Analysis of Palustrine Mitigation Wetlands in the Virginia Coastal Plain
Cummings, Angela R. (Virginia Tech, 1999-05-13)
In recent years, the success of wetland mitigation projects and their ability to function as natural systems has been questioned. This study was conducted (i) to characterize and examine differences between mitigation and natural wetlands, (ii) to examine differences in soil morphology along a wetness gradient in mitigation and natural wetlands, and (iii) to observe changes in mitigation wetlands with time. Site characteristics, including soil properties, hydrology, and vegetation, were analyzed for three mitigation-reference wetland pairs located in the Virginia Coastal Plain. Hydrologic regimes of mitigation areas, when compared to reference areas, generally showed larger differentials between seasonal high and low watertables. Mitigation areas, dominated by herbaceous vegetation, tended to be lower in C and N levels and higher in soil pH, and much higher in bulk density than the mature forested reference wetland. Initially low levels of C and N did not increase significantly over the five-year study period. Soils in the mitigation area were more uniform and considerably less differentiated when compared to those of the reference area. Testing for Fe(II) with alpha-alpha, dipyridyl dye solution produced mixed results, obtaining both positive and negative reactions to saturated samples. Oxidized rhizospheres, associated with active root channels in surface horizons, formed in less than ten years under the current hydrologic conditions. These features were more abundant and more prominent in areas saturated at or above the surface for longer periods of time. Overall, site differences between mitigation and reference areas are mainly due to construction practices and a lack of organic matter accumulation. Better design methods should incorporate the addition of organic amendments, with attempts to minimize soil compaction.
Analysis of Reconstructed Mine Soils on Reclaimed Coal and Mineral Sands Mined Lands in Virginia
Angel, Hannah Zoe (Virginia Tech, 2022-09-01)
Post-mining land use potentials are greatly influenced by mine soil properties. I analyzed and classified coal mine soils in SW VA and mineral sands mine soils in SE VA to aid development of appropriate post-mining land use interpretations. For coal mine soils, long-term pedogenesis was assessed in sandstone (SS) and/or siltstone (SiS) spoils with and without surface amendments. For mineral sands mined lands, I evaluated their spatial variability with respect to underlying relic mining influences and rowcrop productivity. Coal mine subsoils densified as root-limiting layers formed that were not observed initially and all soils had weak pedogenic development (^Bw; cambic horizons), particularly SS derived soils. Initial rock spoil type strongly influenced coal mine soils over time (i.e., SS had coarser textures and lower subsoil pH vs. SiS). However, most soil chemical properties (e.g., pH, EC, CEC) became similar in ^A horizons over time. Fe-oxides increased, and extractable-P decreased with weathering, raising concerns for long-term P-availability. Organic amendments applied to rock spoil surfaces sustained higher total-N (sawdust and biosolids) and extractable P (biosolids). Soil carbon sequestration rates did not differ among rock types or amendments (0.16 to 0.28 Mg ha yr-1). Further, mineral sands mine soils were limited by densic contacts and short-range variability of important properties (texture) appeared related to underlying relic mining features (pits and berms). Yields in reclaimed soils were more variable than in adjacent undisturbed farmland, but mean yields were only slightly reduced for soybean in 2020. Coloration and Fe-oxide spectral indices had weak to moderate negative correlations with yield. Berm positions supported better soybean growth (three out of five sites), while pit positions were redder/darker (one out of five sites). Current Soil Taxonomy conveys anthropogenic origins at the family (e.g., spolic) and subgroup (e.g., Anthroportic) levels. Existing taxa and proposed Artesols order criteria both acknowledge effective soil depth x compaction limitations (Anthrodensic subgroup), but Artesols more effectively recognizes pedogenesis (Inceptic subgroup) and acknowledges mine soils at the highest level. The biggest management limitation for both mine soil types is root-limiting compaction; thus, future efforts should focus on defining depth ranges and taxonomic interpretations for densic contacts.
Appalachian Surface Mine Reforestation Techniques: Effects of Grading, Cultural Treatments and Species Selection
Fields-Johnson, Christopher Warren (Virginia Tech, 2011-01-21)
Surface mining for coal in the Appalachian region has removed over 0.6 million Ha of mixed mesophytic forest. Successful reforestation would be beneficial, but questions remain concerning application of reclamation and reforestation methods on operational scales. Four experiments were performed testing these methods on newly reclaimed and previously reclaimed, but unused, former mines. On newly reclaimed sites, loose grading during reclamation reduced erosion and increased plant community diversity compared to smooth grading. Seeding only annual ryegrass (Lolium multiflorum) for erosion control, along with tree planting, increased plant community diversity and improved survival and growth of hybrid American chestnut (Castanea dentata x Castanea mollissima), compared to conventional seeding. Surface water infiltration was positively correlated with herbaceous ground cover. On older mines, subsoil ripping to alleviate compaction improved tree survival and growth, in some cases, after five growing seasons. Of the three species groups planted, including Eastern white pine (Pinus strobus), mixed native hardwoods had the best survival and hybrid poplar (Populus deltoides x Populus trichocarpa) produced the most biomass. Hybrid American chestnuts survived and grew better when planted as bare-root seedlings than when planted as ungerminated nuts in tree tubes, demonstrating the potential for planting bare-root chestnut seedlings along with other species when reforesting reclaimed surface mines. This can aid in restoring American chestnut, functionally extinct since the blight (Cryphonectria parasitica), to its former range. These cultural practices can be employed to accelerate reforestation of mined lands, but many questions remain about their capability to fully restore ecosystem structure and processes.
An approach to studying soil-landscape relationships in Virginia
Stolt, Mark H. (Virginia Tech, 1990)
Various methods and techniques were used to examine soil-landscape relationships for residual and colluvial soils of Virginia. Soil micromorphology indicated that although some BC and C horizons in the field appeared structureless, evidence of pedogenic process was observed. These were designated as either BCt, BC, or CB horizons depending on the amount of oriented clay and the rates of change with depth of clay, DCB extractable Fe, and sand contents. Soil variability was examined for the overall study, as well as within toposequences, pedons, and individual horizons. Most of the overall variability was attributed to differences between study sites or between horizons, with minimal amounts due to landscape position. Substantial lateral variability occurred within horizons indicating a strong need for subsampling within horizons of the same pedon. Lithologic discontinuities were found to be difficult to recognize without obvious field evidence. Reconstruction analysis was used to examine soil and saprolite formation. Summit and backslope soils were found to be essentially the same in both morphology and degree of profile development. Sand weathering and clay eluviation/illuviation were the major soil forming processes occurring within these soils. Footslope soils were less developed than associated summit and backslope soils, with both depositional and pedologic processes contributing to soil formation and development. Thickness of saprolite was found to decrease. from the summit to the footslope. Thicker saprolite at the summit was apparently related to the greater stability of the summit position compared to the backslope and footslopes. A bucket auger was modified to obtain undisturbed samples of deep saprolite for reconstruction analysis. Saprolite reconstruction indicated that between 20 and 36 % of the mass of the partially weathered rock, which is the precursor to saprolite, is lost during saprolite formation. Most of these losses were either Al or Si. Initial soil formation was shown to occur at a faster rate than saprolite formation, but after substantial profile development, soil formation is reduced to a rate below that of saprolite formation, and saprolite accumulates below the solum. Reconstruction analysis was found to be a valuable tool in studying soil-landscape relationships.
Approaches and Barriers to Incorporating Sustainable Development Into Coal Mine Design
Craynon, John Raymond (Virginia Tech, 2011-07-27)
It is widely recognized that coal is and will continue to be a crucial element in a modern, balanced energy portfolio, providing a bridge to the future as an important low-cost and secure energy solution to sustainability challenges. The designer of coal mining operations needs to simultaneously consider legal, environmental, and sustainability goals, along with traditional mining engineering parameters, as integral parts of the design process. However, traditional coal mining planning seldom considers key “sustainability factors” such as societal impacts; dislocation of towns and residences; physical and economic impact on neighboring communities and individuals; infrastructure concerns; post-mining land use habitat disruption and reconstruction; and long-term community benefit. This work demonstrates the advantage of using a systems engineering approach based on the premise that systems can only be optimized if all factors are considered at one time. Utilizing systems engineering and optimization approaches allows for the incorporation of regulatory and sustainability factors into coal mine design. Graphical approaches, based on the use of GIS tools, are shown as examples of the development of models for the positive and negative impacts of coal mining operations. However, this work also revealed that there are significant challenges inherent in optimizing the design of large-scale surface coal mining operations in Appalachia. Regulatory and permitting programs in the United States, which give conflicting and ill-defined responsibilities to a variety of federal and state agencies, often focus on single parameters, rather than the full suite of desirable outcomes for sustainability, and serve as barriers to innovation. Sustainable development requires a delicate balance between competing economic, environmental and social interests. In the context of coal mining in the U.S., the current regulatory frameworks and policy-guidance vehicles impede this balance. To address this problem, and thus effectively and efficiently provide energy resources while protecting the communities and environments, the U.S. will likely need to fundamentally restructure regulatory programs. Ideally, revisions should be based upon the key concepts of public ecology and allow for a systems engineering approach to coal mine design.
Aspen mycorrhizae: ecology, syntheses and growth studies
Cripps, Cathy Lynn (Virginia Tech, 1992-04-05)
The ectomycorrhizal communities of three aspen-covered sites in southwestern Montana and southeastern Idaho with varying stand age, conditions, and soil types were compared. In all, 39 species of ectomycorrhizal fungi were associated with P. tremuloides. Dominant fungal species varied by site. Species reported on acidic soils in Europe and other species reported to be "early colonizers" were found exclusively on the acidic soils of the Butte site. Many "late stage" fungi such as Amanitas and Cortinarii were found on the older and more productive sites. Nine isolates of ectomycorrhizal fungi were tested for their ability to form mycorrhizae with P. tremuloides. Amanita muscaria v. formosa, A. pantherina, Paxillus vernalis, and Pisolithus tinctorius formed mantles and Hartig nets. Inocybe lacera and Piloderma croceum formed mantles but no Hartig nets. Dry weight, stem diameter, height and number of roottips increased in the young aspen seedlings inoculated with a majority of the fungi listed above. The implications for aspen survival and growth are discussed.
Assessing Coastal Plain Wetland Composition using Advanced Spaceborne Thermal Emission and Reflection Radiometer Imagery
Pantaleoni, Eva (Virginia Tech, 2007-05-03)
Establishing wetland gains and losses, delineating wetland boundaries, and determining their vegetative composition are major challenges that can be improved through remote sensing studies. In this study, we used the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) to separate wetlands from uplands in a study of 870 locations on the Virginia Coastal Plain. We used the first five bands from each of two ASTER scenes (6 March 2005 and 16 October 2005), covering the visible to the short-wave infrared region (0.52-2.185υm). We included GIS data layers for soil survey, topography, and presence or absence of water in a logistic regression model that predicted the location of over 78% of the wetlands. While this was slightly less accurate (78% vs. 86%) than current National Wetland Inventory (NWI) aerial photo interpretation procedures of locating wetlands, satellite imagery analysis holds great promise for speeding wetland mapping, lowering costs, and improving update frequency. To estimate wetland vegetation composition classs of the study locations, we generated a Classification and Regression Tree (CART) model and a Multinomial Logistic Regression (logit) model, and compared their accuracy in separating woody wetlands, emergent wetlands and open water. The overall accuracy of the CART model was 73.3%, while the overall accuracy of the logit model was 76.7%. Although the CART producer's accuracy (correct category classification) of the emergent wetlands was higher than the accuracy from the multinomial logit (57.1% vs. 40.7%), we obtained the opposite result for the woody wetland category (68.7% vs. 52.6%). A McNemar test between the two models and NWI maps showed that their accuracies were not statistically different. We conducted a sub-pixel analysis of the ASTER images to establish canopy cover of forested wetlands. The canopy cover ranged from 0 to 225 m2. We used visble-near-infrared ASTER bands, Delta Normalized Difference Vegetation Index, and a Tasselled Cap transformation in an ordinary linear regression (OLS) model. The model achieved an adjusted-R2 of 0.69 and an RMSE of 2.73% when the canopy cover is less than 16%. For higher canopy cover values, the adjusted-R2 was 0.4 and the RMSE was19.79%. Taken together, these findings suggest that satellite remote sensing, in concert with other spatial data, has strong potential for mapping both wetland presence and type.
Assessment of Exceptional Quality Biosolids for Urban Agriculture
Alvarez-Campos, Odiney Maria (Virginia Tech, 2019-03-28)
Biosolids have been used as soil conditioners and fertilizers in agriculture and mine land reclamation, but application of Exceptional Quality (EQ) biosolids to rehabilitate anthropogenic soils for urban agriculture is recent and requires greater study to ensure their appropriate use. The objectives were: 1) to quantify plant available nitrogen (PAN) of new EQ biosolids in a greenhouse bioassay; 2) to quantify PAN of EQ biosolids applied to an urban degraded subsoil via tall fescue N fertilizer equivalency, and compare field results to laboratory tests; 3) to investigate EQ biosolids and inorganic fertilizer effects on urban soil properties, vegetable yields, and potential N and phosphorus (P) loss. Biosolids evaluated were products of thermal hydrolysis plus anaerobic digestion (BLOOM), blending with woody mulch (BM) and sand/sawdust (BSS), composting (LBC), and heat-drying (OCB). Organic N mineralization of new blended biosolids products ranged between 20-25% in the greenhouse bioassay. Products BLOOM, BM, and OCB had the highest organic N mineralization as estimated by the 7-day anaerobic incubation, and this test and soil nitrate-N had the highest correlations with tall fescue N uptake (r=0.49 and r=0.505, respectively). We conducted a two-year field study with four growing seasons (fall 2016-2017 and summer 2017-2018) in an urban disturbed subsoil where EQ biosolids were applied seasonally at agronomic N rates, and yearly at reclamation rates (5x agronomic N). Cabbage yields were greater with reclamation rates (~3.0 kg m-2) and bell pepper yields were greater with BLOOM reclamation rate (~1.0 kg m-2) than with the inorganic fertilizer (1.0 kg m-2 and 0.2 kg m-2, respectively) during second year growing seasons. Soil carbon (C) accumulation (%C remaining in the soil) two years after biosolids additions ranged between 37 to 84%. Soil N availability and mineralization were limited most likely due to lack of residual soil C and N, and high clay content. Nitrogen leaching losses from reclamation rates were not greater than agronomic N rates. Leachate P was below detection during most of the experiment. Despite limiting soil conditions, biosolids amendment at reclamation rates showed greatest potential to increase vegetable yield and improve soil properties after two years of application, while not impairing water quality.
Assessment of silvicultural practices to improve survival and growth of pioneer and mid-successional hardwoods on old field restoration sites
Steele, Jason Keith (Virginia Tech, 2020-07-01)
Survival and growth of planted trees are common indices used to evaluate success of wetland restoration efforts used to compensate for wetland losses. Restoration efforts on marginal agricultural lands typically result in less than satisfactory survival and growth of desired tree species. This study evaluated seed source ecotype, greenhouse preconditioning and combinations of five mechanical site preparation techniques (mound, bed, rip, disk, pit), four levels of planting stock (gallon, tubeling, bare root, and direct seed), and three planting aids (mat, tube, none) on the survival and growth of American sycamore (Platanus occidentalis L.) and willow oak (Quercus phellos L.) planted on an old field riparian area in the Virginia Piedmont. American sycamore seedlings subjected to greenhouse flood preconditioning had 25% greater height and willow oak seedlings grown under normal greenhouse conditions had 18% greater diameter, but these greenhouse adaptations did not confer greater survivability or growth after field planting. American sycamore seeds sourced from dry ecotypes were 14% taller than wet ecotype seeds, and willow oak acorns sourced from wet ecotypes were 11% taller than dry ecotype acorns, indicating that parental ecotype may influence survivability and growth. The combination of mounding site preparation and gallon planting stock increased mean survival to 100% and aboveground dry biomass (5.44 Mg/ha/yr) in American sycamore. Willow oak had 45% greater woody stem volume with mounding site preparation 80% greater woody stem volume with gallon and bare root planting stock. Tubeling planting stock provided significant benefit relative to the low planting stock cost for American sycamore, while bare root seedlings were shown to be an effective planting stock for willow oak. The use of appropriate ecotype seed sources, use of mounding mechanical site preparation techniques and planting of species appropriate planting stock increased survival and growth of common early and mid-successional Piedmont tree species on marginal agricultural lands. Treatments that appear to be economically viable for restoration and mitigation efforts could potentially offer other economic incentives such as short rotation woody crops and timber value, which might induce additional private landowners to attempt restoration efforts in marginal old field riparian areas.
Batch extraction method to estimate total dissolved solids (TDS) release from coal refuse and overburden
Castillo-Meza, Luis E.; Cravotta, Charles A.; Tasker, Travis L.; Warner, Nathaniel R.; Daniels, W. Lee; Orndorff, Zenah W.; Bergstresser, Tim; Douglass, A.; Kimble, George; Streczywilk, Joelle; Barton, Christopher D.; Fulton, Stephanie; Thompson, Aaron; Burgos, William D. (2020-04)
A rapid batch extraction method was evaluated to estimate potential for total dissolved solids (TDS) release by 65 samples of rock from coal and gas-bearing strata of the Appalachian Basin in eastern USA. Three different extractant solutions were considered: deionized water (DI), DI equilibrated with 10% CO2 atmosphere (DI thorn CO2), or 30% H2O2 under 10% CO2 (H2O2+CO2). In all extractions, 10 g of pulverized rock (<0.5-mm) were mixed with 20 mL of extractant solution and shaken for 4 h at 50 rpm and 20-22 degrees C. The 65 rock samples were classified as coal (n =3), overburden (n = 17), coal refuse that had weathered in the field (n = 14), unleached coal refuse that had oxidized during indoor storage (n = 20), gas-bearing shale (n = 10), and pyrite (n = 1). Extracts were analyzed for specific conductance (SC), TDS, pH, and major and trace elements, and subsequently speciated to determine ionic contributions to SC. The pH of extractant blanks decreased in the order DI (6.0), DI thorn CO2 (5.1), and H2O2+CO2 (2.6). The DI extractant was effective for mobilizing soluble SO4 and Cl salts. The DI thorn CO2 extractant increased weathering of carbonates and resulted in equivalent or greater TDS than the DI leach of the same material. The H2O2+CO2 extractant increased weathering of sulfides (and carbonates) and resulted in the greatest TDS production and lowest pH values. Of the 65 samples, 19 had leachate chemistry data from previous column experiments and 35 were paired to 10 field sites with leachate chemistry data. When accounting for the water-to-rock ratio, TDS from DI and DI thorn CO2 extractions were correlated to TDS from column experiments while TDS from H2O2+CO2 extractions was not. In contrast to column experiments, field SC was better correlated to SC measured from H2O2+CO2 extractions than DI extractions. The field SC and SC from H2O2+CO2 extractions were statistically indistinguishable for 7 of 9 paired data sets while SC from DI extractions underestimated field SC in 5 of 9 cases. Upscaling comparisons suggest that (1) weathering reactions in the field are more aggressive than DI water or synthetic rainwater extractants used in batch or column tests, and (2) a batch extraction method utilizing 30% H2O2 (which is mildly acidic without CO2 enrichment) could be effective for identifying rocks that will release high amounts of TDS.
Beneficial Reuse of Dredged Materials in Upland Environments
Haus, Nicholas Wes (Virginia Tech, 2011-12-13)
Sediments excavated from dredging operations are known as dredged materials. Beneficial reuse of dredged materials in confined utilization facilities (CUFs) is a new approach that has the potential to productively utilize large quantities of dredged materials. However, several factors can inhibit the use of dredged materials in CUFs. In this study, high levels of salts and polycyclic aromatic hydrocarbons (PAHs) were investigated. In the first part of this study, 176,000 m3 of saline dredged materials was placed into a CUF. In less than 4 years, most of the dredged materials had developed horizonation and converted to Inceptisols. The formation of pedogenic Bg horizons in these soils occurred after a polygonal prism network had developed which partially disintegrated into a blocky structured, oxidized horizon with an abundance of redoximorphic features. During the study period, the soil chemistry of the weathering dredged materials shifted from Na-dominated to Ca and Mg-dominated system, allowing plant invasion. In the second part of the study, a bench-scale greenhouse bioremediation experiment was conducted to test the effectiveness of biosolids, compost, and straw at enhancing PAH degradation. Initial concentrations of PAHs decreased significantly after 150 days using standard methods of extraction. However, at 327 days the concentrations of many PAHs, especially those with higher molecular weights, had rebounded close to initial levels. This indicates that PAH bioremediation studies using organic matter additions and conducted using standard methods of extraction need to be carried out longer periods of time or that extraction methods need to be improved.
Biogeochemistry of Carbon on Disturbed Forest Landscapes
Amichev, Beyhan Y. (Virginia Tech, 2007-04-11)
Carbon accreditation of forest development projects is essential for sequestering atmospheric CO2 under the provisions of the Kyoto Protocol. The carbon sequestration potential of surface coal-mined lands is not well known. The purpose of this work was to determine how to measure carbon sequestration and estimate the additional amount that could be sequestered using different reforestation methods compared to the common practice of establishing grasslands. I developed a thermal oxidation technique for differentiating sequestered soil carbon from inorganic and fossilized carbon found at high levels in mine soils along with a geospatial and statistical protocol for carbon monitoring and accounting. I used existing tree, litter, and soil carbon data for 14 mined and 8 adjacent, non-mined forests in the Midwestern and Eastern coal regions to determine, and model sequestered carbon across the spectrum of site index and stand age in pine, mixed, and hardwood forest stands. Finally, I developed the framework of a decision support system consisting of the first iteration of a dynamic model to predict carbon sequestration for a 60-year period for three forest types (white pine, hybrid poplar, and native hardwoods) at three levels of management intensity: low (weed control), medium (weed control and tillage) and high (weed control, tillage, and fertilization). On average, the highest amount of ecosystem carbon on mined land was sequestered by pine stands (148 Mg ha-1), followed by hardwood (130 Mg ha-1) and mixed stands (118 Mg ha-1). Non-mined hardwood stands contained 210 Mg C ha-1, which was about 62% higher than the average of all mined stands. After 60 years, the net carbon in ecosystem components, wood products, and landfills ranged from 20 to 235 Mg ha-1 among all scenarios. The highest net amount of carbon was estimated under mixed hardwood vegetation established by the highest intensity treatment. Under this scenario, a surface-mined land of average site quality would sequester net carbon stock at 235 Mg C ha-1, at a rate of 3.9 Mg C ha-1 yr-1, which was 100% greater than a grassland scenario. Reforestation is a logical choice for mined land reclamation if carbon sequestration is a management objective.
A case study of investment in agricultural sustainability: adoption and policy issues for nitrogen pollution control in the Chesapeake Bay drainage
Norris, Patricia E. (Virginia Polytechnic Institute and State University, 1988)
Nutrient loadings to the Chesapeake Bay are a source of concern for water quality agencies. In particular, excess nitrogen loadings from agricultural production activities threaten water quality in the Bay. Questions have been raised about how effectively traditional BMPs can control nitrogen loss from crop production. This study examines agricultural nitrogen pollution control from an input management perspective. Using an economic and physical model, seven production systems and nitrogen management strategies are compared in terms of input use, profitability, and nitrogen loss potential. Results suggest that several of the production systems will reduce residual nitrogen without reducing profits. However, it is recognized that factors in addition to profitability will influence producers' nitrogen management decisions. Therefore, using the results of a farmer survey, adoption models are estimated to examine the impact of production system characteristics and producer characteristics on the decision to use an alternative production system and nitrogen management strategy. Finally, a sensitivity analysis is conducted to examine the impact of alternative policy tools on adoption incentives. Both financial incentives and education and information programs are found to be important tools for influencing producers' decisions. Producers' interest in the alternative systems and desire for information on the systems suggest that agricultural research will contribute by assuring that producers have access to adequate information on the alternative systems.
Changes in Soil Nitrogen Following Biosolids Application to Loblolly Pine (Pinus Taeda L.) Forest in the Virginia Piedmont
Arellano Ogaz, Eduardo (Virginia Tech, 2009-01-12)
Application of biosolids as an alternative source of Nitrogen (N) is becoming a common silviculture practices on loblolly pine forest. However, little is known about how biosolids type, application rate, and timing affect forest floor and soil N availability in pine plantations. The objectives of this study were to determine the effect of different types, rates, and season of application of biosolids on forest floor and soil N. The study was established in a 17-year-old loblolly pine plantation in Amelia County, VA. Anaerobically digested (AD225), lime stabilized (LS225), and pelletized (Pellet225) biosolids and a conventional inorganic urea plus diammonium phosphate fertilizer (U+DAP225) were surface applied at a rate of 225 kg ha-1 based on Plant Available Nitrogen (PAN) between March 5th and 10th, 2006. Anaerobically digested biosolids were also surface applied at the rates of 900 kg PAN ha-1 and 1800 kg PAN ha^-
Characterizing TDS Risk in Appalachian Landscapes: Techniques to Identify Mine Spoil TDS Generation Potentials
Johnson, Daniel K.; Daniels, W. Lee (Virginia Tech. Powell River Project, 2016)
Surface mining for coal in the Central Appalachians contributes total dissolved solids (TDS) to headwater streams, especially below larger mines and associated valley fills. The objective of this study was to characterize the geochemical properties of a range of surface soils and associated geologic strata from the Central Appalachian coalfields and to relate those properties to simple field indicators, such as color or rock type. We hypothesized that these indicators can accurately predict certain geochemical properties. Thirty‐three vertical weathering sequences were sampled from eight surface mines throughout the Central Appalachian coalfields, for a total of 204 individual samples. No differences were found among sites in overall saturated paste specific conductance (SC; used as a proxy for TDS) levels, but significant geochemical differences existed among samples. Sulfate release dominated SC levels, followed closely by Ca and Mg. Surficial soils and sandstones were yellowish‐brown in color and low in SC, compared to the underlying grayish to black sandstones, shales, and mudstones. Saturated paste extractable As and P levels were higher in A horizons, whereas Se was significantly higher in unweathered bedrock than in soil or weathered bedrock. Samples generating exothermic reactions with 30% H2O2 produced higher SC levels, sulfate, Mg, and Se. In the field, weathered surface materials were frequently abruptly separated from underlying non‐weathered strata by thin shale layers or coal seams. In conclusion, the mine spoils studied varied widely in geochemical properties. The simple field indicators presented here, such as color, weathering status, rock type, and H2O2 reaction can provide valuable guidance for identifying TDS risk which would greatly improve operator’s ability to actively minimize TDS release. We recommend using soil and weathered, yellowish‐brown sandstone layers as a source of low TDS spoil material whenever possible. Underlying unweathered bedrock layers should be treated as "potentially high TDS spoils". The H2O2 field test is useful for identification of both TDS and Se risk in these layers. Particularly high risk spoils include gray to black mudstones and shales, coals, and coal associated shales, mudstones, and clays directly associated with coal seams. We recommend hydrologically isolating these spoils using techniques similar to those used historically for acid‐forming materials.
Chemical Monitoring of a Primary Water Supply: Lake Pelham in Culpeper, Virginia
Morgan, John (Virginia Tech, 2011-12)
Over the last decade there has been an increase in public and government concern over water quality in the United States, especially water bodies that are sources of drinking water. A study conducted by the United States Geologic Survey (USGS) and the National Water-Quality Assessment (NAQWA), has indicated that nutrient concentrations in streams and groundwater in basins with significant agricultural or urban development are substantially greater than naturally occurring or “background” levels (Dubrovsky, 2010). Various academic studies throughout the United States have demonstrated that many water sources are in danger of being severely polluted, with accelerated eutrophication occurring in many lakes. Specifically, the EPA, who has the task of monitoring these water bodies along with the USGS, has tightened the regulations about point and non-point sources of pollution, in an attempt to reduce the amount of eutrophication in sensitive water bodies. Lake Pelham, located in Culpeper, Virginia has experienced an increase in water quality problems; specifically an increase in nutrients in the lake, causing significant algae blooms. Increasing concern over the amount of nutrients found in lakes, rivers, streams and other water ways (i.e. the Chesapeake Bay) have yielded an increase in the amount of money spent on studies, both at the Federal (EPA) and state level (DEQ). Furthermore, several counties and towns have taken it upon themselves to conduct monitoring programs on their local water sources, to ensure the health of potable water as well as the health of their constituents. The objectives of this research program for Lake Pelham were to: 1.) conduct a literature review of similar surface water systems to highlight current trends in nutrient concentrations 2.) measure and monitor the total phosphorus and nitrogen levels in the lake and examine relationships between nutrient concentrations, water temperature, dissolved oxygen content, and pH and 3.) outline future actions for monitoring Lake Pelham and possible preventive actions for nutrient control. In 2010, the interaction between pH, temperature, nitrogen and phosphorous was investigated. The total nitrogen concentration of Lake Pelham is highly dependent on the leachate entering the lake. Large increases in nitrogen occur during even the smallest rainfall events, suggesting nitrogen is entering the lake from the surrounding environment. The current study indicates that the mean annual average total nitrogen concentration of the lake is approximately 10 mg/l. This value provides a baseline which can be used while the total nitrogen is being monitored over the next several years. In previous years, an increase in pH values (< 1.0 between test dates) was associated with algal blooms in the lake and necessitated the treatment with copper sulfate. Between 1992 and 2010, the nitrogen concentration doubled and the phosphorus concentration increased 7 fold. Algae concentrations and pH fluctuation decrease as the water temperature decreases. Similar to nitrogen, phosphorus concentrations in the lake increase with rainfall events suggesting a relationship to runoff and/or leeching entering from the surrounding watershed. Even during lower water levels, similar to what occurred in August of 2010, when the lake was 15 inches below peak level, a small rainstorm had a large impact on the amount of phosphorus entering the lake requiring the addition of copper sulfate. The trophic state for Lake Pelham was calculated from the average values of the total phosphorus measured in the lake over 2010 and the Secchi disk readings from the same time period. The Tropic State Index (TSI) was calculated to be 59.75 when using the total concentration of phosphorus in Lake Pelham. The TSI calculated from the Sechhi Disk values was 54.5. This gives a average TSI value of 57.1, which indicates that the lake is in a eutrophic state. This was the first attempt at determining the trophic state of Lake Pelham. The study is an important first step for understanding nutrient loading in Lake Pelham and applying protective measures to preserve water quality. Similar to a study conducted in King County, Washington, long term data (decade or more) and in depth statistical analysis will be needed to explain the seasonal variability of Lake Pelham.
Chemistry and Transport of Metals from Entrenched Biosolids at a Reclaimed Mineral Sands Mining Site in Dinwiddie County, Virginia
Lasley, Katrina (Virginia Tech, 2008-06-30)
Deep row incorporation of biosolids is an alternative land application method that may allow higher than currently permitted mine land reclamation application rates. Biosolids treated by various processes possess characteristics that uniquely affect metal solubility and mobility due to their influence on metal speciation. The objectives of this research were to compare the effects of biosolids stabilization type and rate on heavy metal solubility, mobility, and speciation. Two rates each of Alexandria, (Virginia) anaerobically digested (213 and 426 dry Mg ha-1) and Blue Plains (Washington, DC) lime-stabilized (329 and 657 dry Mg ha-1) biosolids were placed in trenches at a mineral sands mine reclamation site in Dinwiddie County, Virginia in June and July 2006. Vertical and lateral transport of heavy metals from the biosolids seams were determined by analyzing leachate collected in zero tension lysimeters below the trenches and suction lysimeters adjacent to the trenches. Chloride (Cl-), sulfate (SO42-), nitrate (NO3-), phosphate (PO43-), dissolved organic carbon (DOC), and pH were also determined within the dissolved fractions (< 0.45 Âµm) collected on September 8, 2006, November 3, 2006, January 5, 2007, June 8, 2007, and September 7, 2007 as input for the speciation program MINTEQA2. Silver, Cd, Pb, and Sn did not move vertically or laterally to any significant extent. Lime-stabilized biosolids produced higher cumulative metal mass transport per sampling period for Cu (967 g ha-1), Ni (171 g ha-1), and Zn (1027 g ha-1) than the anaerobically digested biosolids and control during the 15-month period following entrenching. Barium mass loss was similar for both biosolids. All metals moved primarily with particulates. MINTEQA2 predicted the majority of the metals within the dissolved fraction were present as free ions. As pH decreased and time increased, the amount of association with fulvic acids decreased allowing more free ions and binding with inorganic ligands. Little movement into groundwater demonstrates that anaerobically digested and lime-stabilized biosolids can be land-applied at high rates with little concern of heavy metal contamination of groundwater under these conditions.
Competitive Adsorption of Arsenite and Silicic Acid on Goethite
Luxton, Todd Peter (Virginia Tech, 2002-12-12)
The adsorption behavior of silicic acid and arsenite alone and competitively on goethite over a broad pH range (3-11) at environmentally relevant concentrations was investigated utilizing pH adsorption data and zeta potential measurements. Both addition scenarios (Si before As(III) and As(III) before Si) were examined. The results of the adsorption experiments and zeta potential measurements were then used to model the single ion and competitive ion adsorption on goethite with the CD-MUSIC model implemented in the FITEQL 4.0 computer program. Silicic acid adsorption was reduced by the presence of arsenite for all but one of the adsorption scenarios examined, while in contrast silicic acid had little effect upon arsenite adsorption. However, the presence of silicic acid, regardless of the addition scenario, dramatically increased the arsenite equilibrium solution concentration over the entire pH range investigated. The CD-MUSIC model was able to predict the single ion adsorption behavior of silicic acid and arsenite on goethite. The modeled zeta potential data provided further evidence of the CD-MUSIC model's ability to describe the single anion adsorption on goethite. Our model was also able to collectively describe adsorption and zeta potential data for the low Si-arsenite adsorption scenario quite well however, our model under-predicted silicic acid adsorption for the high Si-arsenite competitive scenario.
Complicated Composting: Persistent Pyridine Carboxylic Acid Herbicides
Reimer, Julie (Virginia Tech, 2013-05)
This paper reviews pyridine carboxylic acid herbicide impacts on compost. Pyridine carboxylic acid herbicides are not completely broken down during grass growth, harvest and drying of hay, in the digestive tract of livestock, or during composting. These herbicides are a popular choice for broadleaf weed control because of this persistence: they remain effective for months or years. Pyridine carboxylic acids are also more effective than the common herbicide 2, 4-dichlorophenoxyacetic acid and can be applied to pastures with grazing livestock because they have low mammalian toxicity. The growth-inhibitory action of naturally occurring pyridine compounds has been researched since the discovery of α-picoline-γ-carboxylic acid in the early 1900’s. These pyridine carboxylic acid compounds mimic plant growth hormones called auxins, causing plants to grow abnormally and then die. Plants injured by auxinic herbicides have poor seed germination, twisted growth, cupped or enlongated leaves, misshapen fruit, reduced yields, and ultimately die. Picloram (4-amino-3,5,6-trichloropyridine-2-carboxylic acid) was developed by Dow Chemical Company as a systemic herbicide for herbaceous weeds and woody plants in rights-of-way, forestry, rangelands, pastures, and small grain crops. Clopyralid (3,6-dichloropicolinic acid) was also developed by Dow Chemical Company to control annual and perennial broadleaf weeds in crops and turf. Another Dow herbicide, aminopyralid (4-amino-3,6-dichloro-2-pyridine carboxylic acid), is used for broad leaf weed control in pastures. Aminocyclopyrachlor (6-amino-5-chloro-2-cyclopropylpyrimidine-4-carboxylic acid) is the first pyrimidine carboxylic acid herbicide and was developed by DuPont for weed and brush control on uncultivated non-agricultural areas, uncultivated agricultural areas, industrial sites, and natural areas. Clopyralid compost contamination was reported in 2000 at four different facilities including Washington State University. In Vermont, compost samples were tested and found to contain aminopyralid, clopyralid, and picloram in 2012. Across the U.S. since 2000, there have been many reports of apparent plant injury from compost contaminated with auxinic herbicides. Because of the limited testing facilities and expense of chemical testing, the majority of these reports remain anecdotal. If the history of a compost feedstock is unknown, bioassays are recommended to test compost for the presence of auxinic herbicides. Even though pyridine carboxylic acid herbicides are sold with proper labeling and restrictions, compost contamination is continuing. Adjustments should be made for the registered uses of these herbicides, and herbicide applicators need improved education about the implications of contaminating compost feedstock.
Constructed Floodplain Wetland Effectiveness for Stormwater Management
Ludwig, Andrea L. (Virginia Tech, 2010-07-20)
A 0.2-hectare wetland was constructed in the floodplain of Opequon Creek in Northern Virginia as a best management practice (BMP) for stormwater management. The research goals were to 1) determine if wetland hydrology existed and quantify the role of groundwater exchange in the constructed wetland (CW) water budget, 2) estimate wetland hydraulic characteristics during overbank flows, and 3) quantify the event-scale nutrient assimilative capacity of the constructed wetland. CW water table elevations and hydraulic gradients were measured through an array of nested piezometers. During controlled flooding events, stream water was pumped from the creek and amended with nutrients and a conservative tracer in two seasons to determine hydraulic characteristics and nutrient reduction. Samples were collected at the inlet, outlet structure, and at three locations along three transects along the wetland flowpath. Water table elevation monitoring demonstrated that wetland hydrology existed on the site. The mean residence time of the wetland was found to be 100 min for flow-rates of 4.25-5.1 m3/min. Residence time distributions of the high and low marsh features identified a considerable degree of flow dispersion. Manning's n varied between macrotopographic features and was significantly higher in the spring event as compared to the fall event, likely due to the presence of rigid-stem vegetation. Average wetland n was 0.62. Total suspended solid concentrations decreased with increasing residence time during both experiments. Mass reduction of pollutants were 73% total suspended solids (TSS), 54% ammonia-nitrogen (NH3-N), 16% nitrate-N (NO3-N), 16% total nitrogen (TN), 23% orthophosphate-phosphorus (PO4-P), and 37% total P (TP) in the fall, and 69% TSS, 58% NH3-N, 7% NO3-N, 22% TN, 8% PO4-P, and 25% TP in the spring. Linear regression of mass flux over the event hydrograph was used to determine pollutant removal rates between the wetland inlet and outlet. Pollutant removal rates were determined through linear regression of mass flux and were higher in the spring event than in the fall. Dissolved nitrogen species were more rapidly removed than dissolved phosphorus. TSS, TP, and TN removal were greater and faster than dissolved nutrient species, suggesting that physical settling was the dominant removal mechanism for stormwater pollutants.

Browsing by Author "Daniels, W. Lee"

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