Virginia Tech
    • Log in
    View Item 
    •   VTechWorks Home
    • ETDs: Virginia Tech Electronic Theses and Dissertations
    • Masters Theses
    • View Item
    •   VTechWorks Home
    • ETDs: Virginia Tech Electronic Theses and Dissertations
    • Masters Theses
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Development of a Knudsen Cell Reactor for Measuring the Uptake of Atmospheric Gases on Particulate Matter

    Thumbnail
    View/Open
    Rockhold_TH_T_2011.pdf (2.589Mb)
    Downloads: 353
    Date
    2011-04-20
    Author
    Rockhold, Thomas Hall Jr.
    Metadata
    Show full item record
    Abstract
    Heterogeneous reactions between mineral dust aerosols and gas phase volatile organic compounds have the potential to impact important atmospheric chemical processes. However, little is known about the uptake and reactivity of volatile organic compounds on particulates found in the environment. A Knudsen cell was designed and constructed for providing precise measurement of reaction probabilities within these systems. The instrument was validated through a series of experiments. After validating the Knudsen cell against several key benchmarks, the instrument was used to measure the uptake coefficient for ethanol on particulate silicon dioxide. The uptake coefficient of ethanol on silicon dioxide, a common compound in mineral dust aerosols, was determined to be 7 x 10-7. Therefore, uptake of ethanol on silicon dioxide would be competitive with the loss of other volatile organic compounds on silicon dioxide, which show similar rates of uptake. The Knudsen cell was validated and measured the uptake of ethanol on silicon dioxide, and future work with the Knudsen cell will study the uptake of chemical warfare agent simulants on metal oxides.
    URI
    http://hdl.handle.net/10919/32194
    Collections
    • Masters Theses [19660]

    If you believe that any material in VTechWorks should be removed, please see our policy and procedure for Requesting that Material be Amended or Removed. All takedown requests will be promptly acknowledged and investigated.

    Virginia Tech | University Libraries | Contact Us
     

     

    VTechWorks

    AboutPoliciesHelp

    Browse

    All of VTechWorksCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsThis CollectionBy Issue DateAuthorsTitlesSubjects

    My Account

    Log inRegister

    Statistics

    View Usage Statistics

    If you believe that any material in VTechWorks should be removed, please see our policy and procedure for Requesting that Material be Amended or Removed. All takedown requests will be promptly acknowledged and investigated.

    Virginia Tech | University Libraries | Contact Us