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dc.contributor.authorOliveira, Willer deen
dc.date.accessioned2014-03-14T21:38:22Zen
dc.date.available2014-03-14T21:38:22Zen
dc.date.issued1987en
dc.identifier.otheretd-06122010-020340en
dc.identifier.urihttp://hdl.handle.net/10919/43255en
dc.description.abstractStar-like macromers were prepared from hydroxypropyl lignin by reaction with propylene oxide. The average number of arms per macromer was controlled by partial capping with diethylsulfate, and the average arm length by the degree of chain extension with propylene oxide. Six methods of analysis were applied for characterizing of the star-like macromers: total hydroxyl (by titration), vapor pressure osmometry, hydriotic acid/gas chromatography, ultraviolet spectroscopy, proton-nuclear magnetic resonance spectroscopy and thermal analysis. Number average molecular weights were measured by vapor pressure osmometry. Total hydroxyl content was determined after acetylation by potentiometric titration. Based on HPL molecular weight and hydroxyl content it was estimated that the average HPL molecule generates a star-like structure ("macromer”) with an average of 6 arms. Hydriodic acid/gas chromatography proved to be the most appropriate method for the quantitative determination of the degree of capping. Based on this technique it was possible to classify star-like macromers with between two and six radiating arms per average molecule. The same method could also be applied for the determination of arm length. Two different propoxylation reaction conditions produced macromers with an average of 2.5 and 3.5 propylene oxide units per arm. Ultraviolet spectroscopy was the simplest and most rapid method of analysis investigated. The decrease in copolymer absorptivity coefficient was found to be related to an increase in non-UV absorbing mass after capping and/or chain extension. Results indicated that H-NMR spectroscopy is an adequate method of analysis for star-like macromers. Macromer arm length was calculated from the ratio of signals representing the methyl group of acetyl (i.e. hydroxyl) and propoxyl functionality. Two levels of propoxylation produced star-like macromers with 2.2 - 2.5 and 3.9 - 4.0 propylene oxide units per arm. Thermal analysis by DMTA of lignin derivative-containing blends with ethylene-vinyl acetate copolymer indicated that the glass transition behavior of the star-like macromers follows the Gordon-Taylor relationship for copolymers. Although variable, the results revealed a consistent decrease in Tg as a consequence of an increase of propylene oxide chain length.en
dc.format.extentxii, 99 leavesen
dc.format.mediumBTDen
dc.format.mimetypeapplication/pdfen
dc.publisherVirginia Techen
dc.relation.isformatofOCLC# 17559208en
dc.relation.haspartLD5655.V855_1987.O448.pdfen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V855 1987.O448en
dc.subject.lcshLigninen
dc.subject.lcshWood -- Chemistryen
dc.titleStar-like macromers from ligninen
dc.typeThesisen
dc.contributor.departmentForest Productsen
dc.description.degreeMaster of Scienceen
thesis.degree.nameMaster of Scienceen
thesis.degree.levelmastersen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.disciplineForest Productsen
dc.type.dcmitypeTexten
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-06122010-020340/en
dc.date.sdate2010-06-12en
dc.date.rdate2010-06-12en
dc.date.adate2010-06-12en


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