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dc.contributor.authorJohnson, Richard Kwesien
dc.date.accessioned2014-03-14T21:40:35Zen
dc.date.available2014-03-14T21:40:35Zen
dc.date.issued2004-06-18en
dc.identifier.otheretd-07212004-172906en
dc.identifier.urihttp://hdl.handle.net/10919/43767en
dc.description.abstractFiber hybridization involves the blending of high and low performance fibers in a common matrix to yield a composite with a balance of properties that cannot be achieved by using either fiber alone. In this study, the random wetlay process was used as a compounding method to investigate the effects of fiber hybridization on the mechanical, viscoelastic, and sorption characteristics of steam-exploded wood (SEW) and lyocell (high performance regenerated cellulose) fiber-reinforced polypropylene (PP) composites. The two fiber types were blended in varying proportions within a fixed total fiber content of 50 wt. % and compared with non-hybrid lyocell- and SEW-PP controls. Using PP matrix as basis, it was observed that moduli of all composites generally increased with increasing lyocell concentration, ranging from a minimum 66 % for SP 50 (SEW/PP control) to a maximum 233 % for LP 50 (lyocell/PP control). Ultimate strengths on the other hand, declined for SP 50 but increased with the inclusion of lyocell fibers. Comparisons of hybrid (having 5 - 20 wt % lyocell) with non-hybrid (having 25 - 50 wt. % lyocell) composites revealed a surprisingly greater strength and modulus-building efficiency (by as much as 2.6 times) in the hybrid composites. This observation indicated possible synergism between lyocell and SEW. Analyses of composite property gains as a function of fiber cost also showed greater cost benefits (highest for tensile modulus) in favor of hybridization. The advantages of fiber hybridization on composite properties were again evident under dynamic mechanical analysis where no significant differences in the storage moduli were found between a hybrid composite with 20 wt. % lyocell and a non-hybrid composite with 50 wt. % lyocell loading. Application of the time-temperature superposition principle (TTSP) made it possible to predict storage moduli over extended frequencies for PP and its composites. Comparison of shift factor versus temperature plots revealed decreasing relaxation times of PP with increasing lyocell concentration, which indicated that PP interacted better with lyocell than with SEW fibers. Finally, it was observed from sorption tests that hybrid composites absorbed less moisture than non-hybrid counterparts of either fiber type. The reasons for this observation were not apparent. It is however possible that moisture transport mechanisms within the composites may have been modified as a result of hybridization.en
dc.publisherVirginia Techen
dc.relation.haspartTHESIS.pdfen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjecthybrid compositesen
dc.subjectviscoelastic propertiesen
dc.subjectsteam exploded wooden
dc.subjectrandom wetlay processen
dc.subjectsorptionen
dc.subjectlyocellen
dc.subjectmechanical propertiesen
dc.titleWetlaid Cellulose Fiber-Thermoplastic Hybrid Composites - Effects of Lyocell and Steam Exploded Wood Fiber Blendsen
dc.typeThesisen
dc.contributor.departmentWood Science and Forest Productsen
dc.description.degreeMaster of Scienceen
thesis.degree.nameMaster of Scienceen
thesis.degree.levelmastersen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.disciplineWood Science and Forest Productsen
dc.contributor.committeechairZink-Sharp, Audrey G.en
dc.contributor.committeememberFrazier, Charles E.en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-07212004-172906/en
dc.contributor.committeecochairGlasser, Wolfgang G.en
dc.date.sdate2004-07-21en
dc.date.rdate2004-07-27en
dc.date.adate2004-07-27en


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