Fabrication, Validation, and Performance Evaluation of a New Sampling System for the In-Situ Chemical Speciation of Chromium Ions in Groundwater Using Supported Liquid Membranes (SLMs)

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Date
2013-01-24
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Virginia Tech
Abstract

A sampler has been fabricated to facilitate the in-situ speciation of Cr. Teflon® was selected as the material for the samplers because of its inert chemical nature. The design of the sampler is based on the Supported Liquid Membrane (SLM) extraction technique, which utilizes charged organic carrier molecules loaded onto a polymeric (Teflon®) support membrane and the principles of electrostatics to selectively transport Cr ions through an ion-pairing mechanism. Cr ions in the feed solution that have an opposite charge from the carrier molecule form an ion-pair with the carrier and are transported through the membrane and deposited into a second aqueous phase referred to as the acceptor phase. A counter-ion from the acceptor phase is exchanged for the Cr ion to complete the extraction process. Since the acceptor phase is contained in a Teflon® bottle, the SLM sampler is capable of speciation and storage of Cr ions, which is a major advantage over current speciation techniques.

A food coloring test was used to check the samplers for leaks. A plastic barrier was used in place of the polymeric membrane and the acceptor phase bottle was filled with DI water. The sampler was submerged in a beaker containing food coloring and DI water. The bottle contents were checked for the presence of food coloring using UV-vis spectroscopy. The sampler was determined to be leak-free if the bottle did not contain food coloring. All systems prepared were validated upon the initial test and required no further manipulation to ensure structural soundness.

The SLM extraction technique involves two liquid-liquid extractions (LLEs). Before the samplers could be evaluated for their performance and stability in Cr speciation applications, liquid-liquid extraction studies were conducted on both systems (Cr (III) and Cr (VI)) to determine the optimal operating parameters (carrier concentration, decanol concentration, and acceptor phase concentration) of the SLM system. The selectivity of each system was also evaluated to validate proper SLM function.

The performance of the samplers was evaluated in a series of tank studies that focused on the uptake of Cr into the acceptor phase as well as the depletion of Cr ion from this phase. The goal of the performance studies was to determine the mechanical and chemical stability of the SLM samplers. As part of the validation process, selectivity studies and studies without the carrier molecule were conducted to ensure that the systems were functioning according to SLM theory. Tank studies that simulated natural sampling condition were also conducted.

The results of the tests conducted in the laboratory indicate that the SLM samplers are a stable, reliable, and viable method for Cr speciation. Future directions of this project will include the incorporation of the SLM sampler into the existing Multi-layer Sampler (MLS) technology as well as the analysis of the stability and performance of the incorporated systems in the ""in-situ speciation application.

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Keywords
Chromium (III), Chromium (VI), speciation, Supported Liquid Membranes (SLMs), sampler, kinetics, environment
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