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Nitrogenase bioelectrocatalysis: heterogeneous ammonia and hydrogen production by MoFe protein
(Royal Society of Chemistry, 2016-06-20)
Nitrogenase is the only enzyme known to catalyze the reduction of N2 to 2NH3. In vivo, the MoFe protein component of nitrogenase is exclusively reduced by the ATP-hydrolyzing Fe protein in a series of transient ...