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dc.contributor.authorMerola, Joseph S.en
dc.contributor.authorRoy, Christopher P.en
dc.coverage.spatialUnited Statesen
dc.date.accessioned2016-09-21T16:18:13Zen
dc.date.available2016-09-21T16:18:13Zen
dc.date.issued2014-02-01en
dc.identifier.citationMerola, J.S., Roy, C.P. Acta Cryst. E70, m73-m74. doi:10.1107/S160053681300860Xen
dc.identifier.urihttp://hdl.handle.net/10919/72971en
dc.description.abstractThe title complex, [Ir(C5H8NO2)H(C3H9P)3]PF6, has two independent anion-cation pairs in the asymmetric unit. The geometry about each Ir(III) atom is pseudo-octa-hedral with a meridional arrangement of the P(CH3)3 ligands, N,O-bidentate coordination of prolinate and a hydride ligand trans to the prolinate N atom. The independent Ir(III) moieties are joined by N-H⋯O hydrogen bonds and the N-H⋯O bonding motif continues throughout the structure, creating an extended chain parallel to the c-axis direction. The methyl groups of one P(CH3)3 ligand are rotationally disordered over two sets of sites in a 0.62 (2):0.38 (2) ratio.en
dc.description.sponsorshipFinancial support for this work was provided by ACS–PRF (grant #23961-C1) and by the National Science Foundation (CHE-902244)en
dc.format.extentm73 - m74 page(s)en
dc.languageengen
dc.publisherInternational Union of Crystallographyen
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/24764832en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectCrystal structureen
dc.subjectamino acidsen
dc.subjectprolineen
dc.subjecthydrogen-bondingen
dc.subjectiridium trimethylphosphineen
dc.titleHydrido(prolinato-κ(2) N,O)tris-(tri-methyl-phosphane-κP)iridium(III) hexa-fluorido-phosphate.en
dc.typeArticle - Refereeden
dc.contributor.departmentChemistryen
dc.description.notesPublished online (Publication status)en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.identifier.doihttps://doi.org/10.1107/S1600536814001834en
dc.identifier.volume70en
dc.identifier.issuePt 2en
dc.identifier.eissn1600-5368en
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen


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