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dc.contributor.authorMerola, Joseph S.en_US
dc.contributor.authorMorris, Daviden_US
dc.contributor.authorDe Weerd, Nicholasen_US
dc.coverage.spatialUnited Statesen_US
dc.date.accessioned2016-09-22T15:19:12Z
dc.date.available2016-09-22T15:19:12Z
dc.date.issued2013-03-01en_US
dc.identifier.citationActa Cryst. (2013). E69, m176 [ doi:10.1107/S1600536813005072 ]
dc.identifier.urihttp://hdl.handle.net/10919/73019
dc.description.abstractThe asymmetric unit of the title complex, [Ir2Cl4(C12H19)2], a versatile starting material for the preparation of uniquely substituted penta-alkyl-cyclo-penta-dien-yl-iridium complexes, consists of an iridium(III) atom, a substituted cyclo-penta-dienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two Ir(III) atoms and two bridging Cl atoms form a perfectly planar ring. The two Ir(III) atoms and the two terminal Cl atoms also form a rigorous plane that is orthogonal [89.48 (3)°] to the Ir2Cl2 ring. The plane of the cyclo-penta-dienyl ligand forms a dihedral angle of 54.06 (7)° with respect to the Ir2Cl2 ring.en_US
dc.format.extentm176 - ? page(s)en_US
dc.languageengen_US
dc.publisherInternational Union of Crystallography
dc.relation.ispartofseriesActa Crystallographica Section E: Structure Reports Online;
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/23476515en_US
dc.subjectiridium
dc.subjectcyclopentadienyl
dc.subjectx-ray
dc.subjectcrystal
dc.subjectstructure
dc.titleDi-μ2-chlorido-bis-[chlorido(η(5)-2,3,4,5-tetra-methyl-1-propyl-cyclo-penta-dien-yl)iridium(III)].en_US
dc.typeArticle - Refereed
dc.description.notesPublished (Publication status)en_US
dc.title.serialActa Crystallogr Sect E Struct Rep Onlineen_US
dc.identifier.doihttps://doi.org/10.1107/S1600536813005072
dc.identifier.volume69en_US
dc.identifier.issuePt 3en_US
dc.identifier.eissn1600-5368en_US
pubs.organisational-group/Virginia Tech
pubs.organisational-group/Virginia Tech/All T&R Faculty
pubs.organisational-group/Virginia Tech/Faculty of Health Sciences
pubs.organisational-group/Virginia Tech/Science
pubs.organisational-group/Virginia Tech/Science/Chemistry
pubs.organisational-group/Virginia Tech/Science/COS T&R Faculty


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