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dc.contributorVirginia Tech. Department of Chemistry
dc.contributor.authorMerola, Joseph S.en_US
dc.contributor.authorGrieb, Aarthur W.en_US
dc.coverage.spatialUnited Statesen_US
dc.identifier.citationMerola, J. S., A. W. Grieb (2014). Crystal structure of chlorido­(η2-phenyl iso­thio­cyanate-κ2C,S)-mer-tris­­(tri­methyl­phosphane-κP)iridium(I). Acta Crystallographica Section E, 70(11), 352-354. doi:doi:10.1107/S160053681402162X
dc.description.abstractThe molecule of the title compound, [IrCl(C7H5NS)(C3H9P)3], is a distorted octa-hedral iridium complex with three PMe3 ligands arranged in a meridional geometry, a chloride ion cis to all three PMe3 groups and the phenyl iso-thio-cyanate ligand bonded in an η(2)-fashion through the C and S atoms. The C atom is trans to the chloride ion and the S atom is responsible for a significant deviation from an ideal octa-hedral geometry. The geometric parameters for the metal-complexing phenyl isothiocyanate group are compared with other metal-complexed phenyl iso-thio-cyanates, as well as with examples of uncomplexed aryl iso-thio-cyanates.en_US
dc.description.sponsorshipVirginia Tech. Open Access Subvention Fund
dc.format.extent9 pagesen_US
dc.publisherInternational Union of Crystallography
dc.rightsCreative Commons Attribution 4.0 International (CC BY 4.0)*
dc.subjectcrystal structureen_US
dc.subjectiridium complexen_US
dc.subjectphenyl iso­thio­cyanateen_US
dc.titleCrystal structure of chlorido-(η(2)-phenyl iso-thio-cyanate-κ(2) C,S)-mer-tris-(tri-methyl-phosphane-κP)iridium(I).en_US
dc.typeArticle - Refereeden_US
dc.description.notesPublished online (Publication status)en_US
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen_US
dc.identifier.issuePt 11en_US
pubs.organisational-group/Virginia Tech
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pubs.organisational-group/Virginia Tech/Faculty of Health Sciences
pubs.organisational-group/Virginia Tech/Science
pubs.organisational-group/Virginia Tech/Science/Chemistry
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Creative Commons Attribution 4.0 International (CC BY 4.0)
License: Creative Commons Attribution 4.0 International (CC BY 4.0)