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dc.contributor.authorRyan, Madeline Fayeen_US
dc.date.accessioned2018-09-15T08:00:25Z
dc.date.available2018-09-15T08:00:25Z
dc.date.issued2018-09-14en_US
dc.identifier.othervt_gsexam:17000en_US
dc.identifier.urihttp://hdl.handle.net/10919/85021
dc.description.abstractRecent studies have focused on dissolved organic matter (DOM) cycling throughout river corridors or in reservoirs, but few have explored DOM cycling in commonplace but understudied run-of-river (ROR) reservoir systems. Impoundments disrupt river flow patterns, as they increase hydraulic residence time and alter the flow of DOM downstream. During storms when the majority of DOM loading occurs, impoundments become less likely to hold DOM and will increase export of DOM downstream. In this study, we quantified DOM bioavailability and composition, carbon flux, and carbon dioxide (CO2) gas evasion in a ROR reservoir system at baseflow conditions and during a 1.5-year storm event. This study used a combination of high frequency spatial sensor data geotagged to GPS coordinates along the river to reservoir transition, and grab samples of surface water taken at two U.S. Geological Survey stream gauges and three additional sites. The landscape and shallow flow paths to ROR reservoir systems resulted in the export of both aromatic carbon and labile organic matter present within these waters, as water was mixed and exported downstream. Additionally, the reservoir was a net sink of DOC and BDOC flux, while also a source of DIC flux. Finally, CO2 evasion was magnified by high flow, with the reservoir changing from a sink to a source of CO2 to the atmosphere. ROR reservoirs may undergo "short-circuiting" during high flow, which alters DOM transformations and transport of carbon downstream. Our results provide critical insight on carbon dynamics in ROR reservoir systems and highlight the need to incorporate riverine DOM into carbon budgets, especially under variable flow conditions.en_US
dc.format.mediumETDen_US
dc.publisherVirginia Techen_US
dc.rightsThis item is protected by copyright and/or related rights. Some uses of this item may be deemed fair and permitted by law even without permission from the rights holder(s), or the rights holder(s) may have licensed the work for use under certain conditions. For other uses you need to obtain permission from the rights holder(s).en_US
dc.subjectDOMen_US
dc.subjectDOCen_US
dc.subjectCO2en_US
dc.subjectimpoundmenten_US
dc.subjecthigh flowen_US
dc.subjectfluxen_US
dc.subjectevasionen_US
dc.subjectROR reservoiren_US
dc.titleSpatial and Temporal Transitions in the Composition and Transport of Carbon under Variable Flowen_US
dc.typeThesisen_US
dc.contributor.departmentBiological Systems Engineeringen_US
dc.description.degreeMaster of Scienceen_US
thesis.degree.nameMaster of Scienceen_US
thesis.degree.levelmastersen_US
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen_US
thesis.degree.disciplineBiological Systems Engineeringen_US
dc.contributor.committeechairScott, Durelle T.en_US
dc.contributor.committeememberHotchkiss, Erin R.en_US
dc.contributor.committeememberHession, William Cullyen_US


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