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dc.contributor.authorOyama, S. Ted
dc.contributor.authorAono, Haruki
dc.contributor.authorTakagaki, Atsushi
dc.contributor.authorSugawara, Takashi
dc.contributor.authorKikuchi, Ryuji
dc.date.accessioned2020-03-27T18:47:58Z
dc.date.available2020-03-27T18:47:58Z
dc.date.issued2020-03-22
dc.identifier.citationOyama, S.T.; Aono, H.; Takagaki, A.; Sugawara, T.; Kikuchi, R. Synthesis of Silica Membranes by Chemical Vapor Deposition Using a Dimethyldimethoxysilane Precursor. Membranes 2020, 10, 50.
dc.identifier.urihttp://hdl.handle.net/10919/97499
dc.description.abstractSilica-based membranes prepared by chemical vapor deposition of tetraethylorthosilicate (TEOS) on γ-alumina overlayers are known to be effective for hydrogen separation and are attractive for membrane reactor applications for hydrogen-producing reactions. In this study, the synthesis of the membranes was improved by simplifying the deposition of the intermediate γ-alumina layers and by using the precursor, dimethyldimethoxysilane (DMDMOS). In the placement of the γ-alumina layers, earlier work in our laboratory employed four to five dipping-calcining cycles of boehmite sol precursors to produce high H2 selectivities, but this took considerable time. In the present study, only two cycles were needed, even for a macro-porous support, through the use of finer boehmite precursor particle sizes. Using the simplified fabrication process, silica-alumina composite membranes with H2 permeance > 10−7 mol m−2 s−1 Pa−1 and H2/N2 selectivity >100 were successfully synthesized. In addition, the use of the silica precursor, DMDMOS, further improved the H2 permeance without compromising the H2/N2 selectivity. Pure DMDMOS membranes proved to be unstable against hydrothermal conditions, but the addition of aluminum tri-sec-butoxide (ATSB) improved the stability just like for conventional TEOS membranes.en
dc.format.mimetypeapplication/pdf
dc.language.isoenen_US
dc.publisherMDPI
dc.rightsCreative Commons Attribution 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.titleSynthesis of Silica Membranes by Chemical Vapor Deposition Using a Dimethyldimethoxysilane Precursoren
dc.typeArticle - Refereeden_US
dc.date.updated2020-03-27T13:24:04Z
dc.contributor.departmentChemical Engineeringen_US
dc.title.serialMembranes
dc.identifier.doihttps://doi.org/10.3390/membranes10030050
dc.type.dcmitypeText
dc.type.dcmitypeStillImage


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Creative Commons Attribution 4.0 International
License: Creative Commons Attribution 4.0 International