Zhou, RongweiManbeck, Gerald F.Wimer, Dexter G.Brewer, Karen J.2016-03-182016-03-182015-07-01Zhou, R., Manbeck, G. F., Wimer, D. G., & Brewer, K. J. (2015). A new Ru (II) Rh (III) bimetallic with a single Rh-Cl bond as a supramolecular photocatalyst for proton reduction. Chemical Communications, 51(65), 12966-12969. doi:10.1039/C5CC04123F1359-73452015_Zhou_A_new_RuII_RhIII_bimetallic.pdfNew_RuIIRhIII_bimetallic_supp_info.pdfDE FG02-05-ER15751http://hdl.handle.net/10919/64971A new RuIIRhIII structural motif [(bpy)2Ru(dpp)RhCl(tpy)]4+ with one halide on the RhIII center demonstrates light-driven proton reduction ability, establishing that two halide ligands are not mandatory despite all prior systems containing a cis-RhCl2 catalytic site. This new design provides a novel approach to modulate RhIII redox behavior and catalytic activity with insight into catalytic intermediates.4 p.application/pdfenCreative Commons Attribution-NonCommercial 3.0 UnportedArticle - Refereedhttps://doi.org/10.1039/C5CC04123F5165