Hobart, David B. Jr.Merola, Joseph S.2016-09-222016-09-222013-04-13Acta Cryst. (2013). E69, m261-m262 [doi:10.1107/S1600536813009525]http://hdl.handle.net/10919/73017The title complex salt, (C12H16NO2)[PdCl2(C12H14NO2)], is of inter-est with respect to organic and organometallic catalysis. The compound crystallizes as very small orange-red irregular prisms and the asymmetric unit contains three crystallographically distinct cation-anion pairs. The coordination geometry about the palladium atoms is square-planar with the chloride ligands cis to one another. The structure displays N-H⋯Cl and O-H⋯O hydrogen bonding such that the N-H⋯Cl hydrogen bonds align the cation-anion pairs in a linear fashion along [001], with the O-H⋯O hydrogen bonds connecting these linear strands along [100] and [010].m261 - m262 page(s)application/pdfenCreative Commons Attribution 4.0 Internationalcrystal structurex-raypalladiumamino acids(S)-α-Benzylprolinium cis-[(S)-α-benzyl-prolinato]dichloridopalladium(II)Article - RefereedActa Crystallographica Section E: Structure Reports Onlinehttps://doi.org/10.1107/S160053681300952569Pt 51600-5368