Merola, Joseph S.Roy, Christopher P.2016-09-212016-09-212014-02-01Merola, J.S., Roy, C.P. Acta Cryst. E70, m73-m74. doi:10.1107/S160053681300860Xhttp://hdl.handle.net/10919/72971The title complex, [Ir(C5H8NO2)H(C3H9P)3]PF6, has two independent anion-cation pairs in the asymmetric unit. The geometry about each Ir(III) atom is pseudo-octa-hedral with a meridional arrangement of the P(CH3)3 ligands, N,O-bidentate coordination of prolinate and a hydride ligand trans to the prolinate N atom. The independent Ir(III) moieties are joined by N-H⋯O hydrogen bonds and the N-H⋯O bonding motif continues throughout the structure, creating an extended chain parallel to the c-axis direction. The methyl groups of one P(CH3)3 ligand are rotationally disordered over two sets of sites in a 0.62 (2):0.38 (2) ratio.m73 - m74 page(s)application/pdfenCreative Commons Attribution 4.0 InternationalCrystal structureamino acidsprolinehydrogen-bondingiridium trimethylphosphineArticle - Refereedhttps://doi.org/10.1107/S160053681400183470Pt 21600-5368