Maffly, Robert L.Johnson, Paul L.Koch, Timothy R.Williams, Jack M.2022-08-172022-08-171977-02-010567-7408http://hdl.handle.net/10919/111542Na<sub>2</sub>[Pt(CN)<sub>4</sub>Br<sub>2</sub>]. 2H<sub>2</sub>O, orthorhombic, Pnma (D<sub>2h</sub><sup>16</sup>), a = 11.949(11), b = 15.124(14), c = 6.487 (6) Å, Z = 4, D<sub>m</sub> = 3.06, D<sub>x</sub> = 3.065 g cm<sup>-3</sup>. A room-temperature, single-crystal neutron diffraction study was performed. The structure was solved by direct methods and refined by full-matrix least-squares techniques to R(F<sub>0</sub><sup>2</sup>) = 0.068 for 1447 observed reflections > 1σ(F<sub>0</sub><sup>2</sup>). The structure consists of octahedrally coordinated platinum (IV) complex anions interacting with both the sodium cations and the waters of hydration.Pages 558-560application/pdfenPublic Domain (U.S.)Structural studies of precursor and partially oxidized conducting complexes. II. A neutron diffraction study of disodium dibromotetracyanoplatinate dihydrateArticle - Refereed2022-08-06Acta Crystallographica Section B Structural Crystallography and Crystal Chemistryhttps://doi.org/10.1107/s0567740877004075332Koch, Timothy [0000-0002-8026-9653]