Yoon, Tae-Ho2017-11-092017-11-091987http://hdl.handle.net/10919/80009Zinc phosphate conversion coating has been applied to improve the corrosion resistance and paint adhesion. However, zinc phosphate crystals dissolve in a highly alkaline environment, which reduces the corrosion resistance of base metal. To improve the phosphate stability in a highly alkaline environment, a post-rinse treatment has been applied to phosphate coating by rinsing with an aqueous solution which contains certain anions or cations. Chromatepost-rinse treatment is the most widely used method and has shown a great improvement in corrosion resistance. But, due to the environmental problems caused by chromate ions, non-chromate post-rinse treatment should be developed, which has equal or better corrosion resistance than does chromate post-rinse treatment. In this research, inorganic silicate with addition of Ca²⁺, Ba²⁺, Ni²⁺, Mg²⁺, has been extensively evaluated together with silane solution, γ -aminopropyltriethoxysilane ( γ -A.P.S., NH₂(CH₂)₃Si(OC₂H₅)₃), which was applied after the post-rinse treatment. The evaluation was carried out by the highly advanced surface analysis techniques such as SEM/EDX, AES, SIMS, and XRD and polarization measurements.x, 100 leavesapplication/pdfen-USIn CopyrightLD5655.V855 1987.Y666Phosphate coatingCorrosion and anti-corrosivesMetals -- FinishingThesis