Zadrozny, JosephPoquette, Ben2019-06-192019-06-192006-09-22Zadrozny, J.M., 2006. Tunable Three-Dimensional Magnetic Coordination Polymers. Journal of Undergraduate Materials Research, 2. DOI: http://doi.org/10.21061/jumr.v2i0.06061934-7677http://hdl.handle.net/10919/90323Four chlorinated phenyltricyanoethylenes were synthesized and reacted with vanadium hexacarbonyl to form ferrimagnetic coordination polymers.Species chlorinated at the 2, 3, or 4 position of the ring as well as a dichlorinated analogue with substitution at both the 2 and 6 positions were examined.The magnetic ordering temperatures of the polymers were reproducible and ranged from 140 to 288 K. All compounds displayed soft ferrimagnetic behavior, and their structure-property relationships are discussed.6 pages513.77 KBapplication/pdfapplication/zipenIn CopyrightMaterials ScienceMagnetic Coordination PolymersArticleVirginia Tech Department of Materials Science and Engineeringhttps://doi.org/10.21061/jumr.v2i0.0606212578-9570