Iskander, Syeed Md2019-04-262019-04-262019-04-25vt_gsexam:19677http://hdl.handle.net/10919/89218Landfill leachate contains valuable, recoverable organics, water, and nutrients. This project investigated leachate treatment and resource recovery from landfill leachates by innovative methods such as forward osmosis (FO), bioelectrochemical systems (BES), and advanced oxidation. In this study, a microbial fuel cell (MFC) removed 50-75% of the ammonia from a leachate through the electricity driven movement of ammonium to the cathode chamber followed by air stripping at high pH (> 9). During this process, the MFC system removed 53-64% of the COD, producing a net energy of 0.123 kWh m-3. Similarly, an integrated microbial desalination cell (MDC) in an FO system recovered 11-64% of the ammonia from a leachate; this was affected by current generation and hydraulic retention time in the desalination chamber. The MDC-FO system recovered 51.5% of the water from a raw leachate. This increased to 83.5% when the FO concentrate was desalinated in the MDC and then recirculated through the FO unit. In addition, the project investigated humic acid (HA) recovery from leachate during the synergistic incorporation of FO, HA recovery, and Fenton's oxidation to enhance leachate treatment and to reduce Fenton's reagent requirements. This led to the investigation of harmful disinfection byproducts (DBPs) formation during Fenton's oxidation of landfill leachate. The removal of leachate UV-quenching substances (humic, fulvic, and hydrophilic acids) using an MFC and a chemical oxidant (i.e., sodium percarbonate) with a focus on energy production and cost efficiency were also studied. BES treatment can reduce leachate organics concentrations; lower UV absorbance; recover ammonia; and, in combination with FO, recover water. Although BES is promising, significant work is needed before its use in landfill leachate becomes practical. FO application to leachate treatment must consider the choice of an appropriate draw solute, which should require minimal effort for regeneration. Resources like HA in leachate deserve more attention. Further efforts can focus on purification and application of the recovered products. The emerging issue of DBP formation in leachate treatment also requires attention due to the potential environmental and human health effects. The broader impact of this study is the societal benefit from more sustainable and cost-efficient leachate treatment.ETDIn CopyrightLandfill leachateResource recoveryBioelectrochemical systemsForward osmosisMicrobial fuel cellMicrobial desalination cellEnergy recoveryAmmonia recoveryWater recoveryFenton's oxidationSludge reductionCo-treatmentUV quenchersDissertation