Browsing by Author "Alfeeli, Bassam"

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    Behavior of Random Hole Optical Fibers under Gamma Ray Irradiation and Its Potential Use in Radiation Sensing Applications
    Alfeeli, Bassam; Pickrell, Gary R.; Garland, Marc; Wang, Anbo (MDPI, 2007-05-24)
    Effects of radiation on sensing and data transmission components are of greatinterest in many applications including homeland security, nuclear power generation, andmilitary. A new type of microstructured optical fiber (MOF) called the random hole opticalfiber (RHOF) has been recently developed. The RHOFs can be made in many differentforms by varying the core size and the size and extent of porosity in the cladding region.The fibers used in this study possessed an outer diameter of 110 _m and a core ofapproximately 20 _m. The fiber structure contains thousands of air holes surrounding thecore with sizes ranging from less than 100 nm to a few _m. We present the first study ofthe behavior of RHOF under gamma irradiation. We also propose, for the first time to ourknowledge, an ionizing radiation sensor system based on scintillation light from ascintillator phosphor embedded within a holey optical fiber structure. The RHOF radiationresponse was compared to normal single mode and multimode commercial fibers(germanium doped core, pure silica cladding) and to those of radiation resistant fibers (puresilica core with fluorine doped cladding fibers). The comparison was done by measuringradiation-induced absorption (RIA) in all fiber samples at the 1550 nm wavelength window(1545 25 nm). The study was carried out under a high-intensity gamma ray field from a 60Co source (with an exposure rate of 4x104 rad/hr) at an Oak Ridge National Laboratory gamma ray irradiation facility. Linear behavior, at dose values less than 106 rad, was observed in all fiber samples except in the pure silica core fluorine doped cladding fiber which showed RIA saturation at 0.01 dB. RHOF samples demonstrated low RIA (0.02 and 0.005 dB) compared to standard germanium doped core pure silica cladding (SMF and MMF) fibers. Results also showed the possibility of post-fabrication treatment to improve the radiation resistance of the RHOF fibers.
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    Chemical Micro Preconcentrators Development for Micro Gas Chromatography Systems
    Alfeeli, Bassam (Virginia Tech, 2010-10-06)
    Microelectromechanical systems (MEMS) technology allows the realization of mechanical parts, sensors, actuators and electronics on silicon substrate. An attractive utilization of MEMS is to develop micro instruments for chemical analysis. An example is gas chromatography (GC) which is widely used in food, environmental, pharmaceutical, petroleum/refining, forensic/security, and flavors and fragrances industries. A MEMS-based micro GC (µGC) provides capabilities for quantitative analysis of complex chemical mixtures in the field with very short analysis time and small amounts of consumables. The aim of this research effort is to enhance the sensitivity and selectivity of µGC instruments by implementing chemical amplification method known as preconcentration. A micro preconcentrator (µPC) extracts the target analytes from the sample matrix, concentrates them, and injects them into the separation column for analysis. This work resulted in the development of silicon-glass bonded chips consisting of 7 mm x 7 mm x 0.38 mm multiport cavity with thousands of embedded 3D microstructures (to achieve high surface-to-volume ratio) coated with polymeric thin film adsorbents. Deep reactive ion etching (DRIE) was the enabling technology for the realization of µPCs. Several coating methods, such as inkjet printing of polymers and polymer precipitation from solution have been utilized to coat complex geometrical structures. One major outcome was the development of cobweb adsorbent structure. Moreover, the porous polymeric adsorbent Tenax TA in the film form was characterized, for the first time, for μPC application and shown to have similar properties to that of the granular form. Several μPC designs were experimentally evaluated for their performance in concentrating volatile organic compounds, including cancer biomarkers, Propofol (anesthetic agent), environmental pollutants, and chemical warfare simulants. The possibility of utilizing the μPCs in practical applications such breath analysis was also demonstrated.
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    Ionizing Radiation Resistance of Random Hole Optical Fiber for Nuclear Instrumentation and Control Applications
    Alfeeli, Bassam (Virginia Tech, 2009-05-04)
    Random hole optical fibers (RHOF) offer advantages over other types of microstructured optical fibers (MOFs). They are inexpensive and easy-to-make when compared to the high cost of ordered hole MOFs. They also have unique characteristics since they contain open and closed holes. The open holes contain ambient air under normal conditions and the closed holes contain residual gases from the fabrication process at certain pressure. The objective of this research work was to investigate the radiation resistance of Random Hole Optical Fibers (RHOF) for possible use as both sensing element and data transmission medium in nuclear reactor instrumentation and control applications. This work is motivated by the demand for efficient, cost effective, and safe operation of nuclear power plants, which accounts for more than 14% of the world's electricity production. This work has studied the effect of gamma irradiation on RHOF fibers by comparing their performance to that of standard solid telecommunication fibers and commercially available specialty solid fiber designed to be radiations hardened fiber. The fibers were evaluated at different absorbed dose levels: 12 mGy(Si), 350 mGy(Si), and 7200 Gy(Si) by measuring their radiation induced absorption (RIA) on-line. In the low dose test, the maximum RIA measured in untreated RHOF was approximately 8 dB while the RIA in the untreated MMF fibers reached a maximum at about 28 dB. In the high dose test, the maximum RIA measured in untreated RHOF was 36 dB while RIA in the methanol washed RHOF was only 9 dB. RHOF also demonstrated superior radiation damage recovery time over all of the other fibers tested. Based on the experimental evaluations, it was deduced that RHOFs used in this work are resistant to gamma radiation. and recover from radiation damage at a faster rate compared to other fibers tested. The radiation induced absorption (RIA) at the 1550 nm window in the RHOF fibers could be attributed to the OH absorption band tail. However, the existence of other mechanisms responsible for RIA is also postulated. Some of these mechanisms include bulk and surface defects which are related to the fabrication process and the influence of the gases confined within the RHOF microstructure. Gamma radiation resistance of RHOFs can be attributed to the lack of dopants and also possibly the inherent OH and nitrogen content. The behavior of thermally annealed RHOF and their fast recovery is in favor of this hypothesis.
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    Miniature gas sensing device based on near-infrared spectroscopy
    Alfeeli, Bassam (Virginia Tech, 2005-12-01)
    The identification and quantification of atoms, molecules, or ions concentrations in gaseous samples are in great demand for medical, environmental, industrial, law enforcement and national security applications. These applications require in situ, high-resolution, non-destructive, sensitive, miniature, inexpensive, rapid detection, remotely accessed, real time and continuously operating chemical sensing devices. The aim of this work is to design a miniature optical sensing device that is capable of detecting and measuring chemical species, compatible with being integrated into a large variety of monitoring systems, and durable enough to be used under extreme conditions. The miniature optical sensor has been realized by employing technologies from the optical communication industry and spectroscopic methods and techniques. Fused silica capillary tubing along with standard communication optical fibers have been utilized to make miniature gas sensor based on near-infrared spectroscopy for acetylene gas detection. In this work, the basic principles of infrared spectroscopy are reviewed. Also, the principle of operation, fabrication, testing, and analysis of the proposed sensor are discussed in details.