Browsing by Author "Ashley, Kyle T."
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- Constraining Metamorphic and Tectonic Evolution in Convergent Terranes: How Trace Elements and Mineral Inclusions Shape Mechanical and Reconstructive ModelsAshley, Kyle T. (Virginia Tech, 2015-06-01)Conventional thermobarometry in metamorphic systems has been primarily limited to constraining peak temperature (or pressure) along a generalized P-T loop. This is largely attributed to the assumption that mineral assemblages and chemistries achieve a state closest to equilibrium with the maximum thermal (and therefore energetic) input at these peak conditions. However, this traditional approach is limited in providing much information about the evolution of a metamorphic terrane, which is modified by tectonic (kinematic) forces, fluid and component mobility, and heating duration. The ubiquity of quartz in the continental crust has driven much interest in using the phase for thermobarometric purposes. In this dissertation, I discss the application of elastic theory in reconstructing conditions of inclusion encapsulation through inclusion pressure estimation with Raman spectroscopy. In some instances, overpressuring of quartz inclusions in garnet give evidence for high-pressure formation conditions. When analyses are collected from garnet core to rim, pressure paths along garnet growth can be inferred (if temperature can be reasonably estimated). In high-T, low-P terranes, quartz may become dilated if the inclusion adheres to the host. If a quartz inclusion is sufficiently stretched, transformation to a low-density polymorph may occur. Trace element uptake, particularly Ti, have been characterized in quartz and understood to be the result of a temperature- (and to a lesser extent, pressure-) sensitive substitution for Si4+. However, the application of the Ti-in-quartz thermobarometer in quartz mylonites has led to mixed results due to the low-Ti resetting that occurs with dynamic recrystallization. We applied defect energy simulations and took a global assessment of deformed quartz trace element chemistries to infer that sweeping grain boundaries provide short pathways that allows localized re-equilibration with a Ti-undersaturated medium, resulting in Ti removal from the quartz lattice. In addition, thermodynamic pseudosection modeling has provided a method to assess Ti activity as a dynamic parameter – one that evolves as the phase stability changes through prograde and retrograde metamorphic reactions. With this understanding, better growth-composition models can be derived to infer complex pressure-temperature-time-deformation (P-T-t-D) histories of metamorphic rocks. These techniques and results are coupled with conventional thermobarometry techniques to provide a more comprehensive picture of the conditions experienced by a rock through the evolution, from burial to exhumation to the Earth's surface. The thermal evolution is used to provide conceptual thermal-kinematic models to explain tectonic evolution and heat advection in the continental lithosphere in ancient mountain belts.
- Multiple sediment incorporation events in a continental magmatic arc: Insight from the metasedimentary rocks of the northern North Cascades, Washington (USA)Hanson, Ann E. H.; Gordon, Stacie M.; Ashley, Kyle T.; Miller, Robert B.; Langdon-Lassagne, Elizabeth (Geological Society of America, 2022-02)The rheology and composition of arc crust and the overall evolution of continental magmatic arcs can be affected by sediment incorporation events. The exhumed Cretaceous-Eocene North Cascades arc exposes abundant meta-sedimentary rocks that were incorporated into the arc during multiple events. This study uses field relationships, detrital zircon geochronology, bulk rock geo-chemistry, geothermometry, and quartz-in-garnet geobarometry to distinguish approximate contacts and emplacement depths for different metasedimentary units to better understand their protolith incorporation history and impact on the arc. The Skagit Gneiss Complex is one of the main deep crustal units of the North Cascades arc. It includes metasedimentary rocks with distinct detrital zircon signatures: Proterozoic-Cretaceous (Group 1) or Triassic-Cretaceous (Group 2) zircon populations. Both metasedimentary groups achieved near-peak metamorphic conditions of 640-800 degrees C and 5.5-7.9 kbar; several Group 2 samples reveal the higher pressures. A third group of meta sedimentary rocks, which was previously interpreted as metamorphosed equivalents of backarc sediments (Group 3), exhibited unimodal Triassic or bimodal Late Jurassic- Early Cretaceous detrital zircon signatures and achieved near-peak conditions of 570-700 degrees C and 8.7-10.5 kbar. The combined field and analytical data indi-cate that protoliths of Group 1 and Group 2 metasedimentary rocks were successively deposited in a forearc basin and underthrusted into the arc as a relatively coherent body. Group 3 backarc sediments were incorporated into the arc along a transpressional step-over zone. The incorporation of both forearc and backarc sediments was likely facilitated by arc magmatism that weakened arc crust in combination with regional transpression.
- Tectonic Transport Directions, Shear Senses and Deformation Temperatures Indicated by Quartz c-Axis Fabrics and Microstructures in a NW-SE Transect across the Moine and Sgurr Beag Thrust Sheets, Caledonian Orogen of Northern ScotlandLaw, Richard D.; Thigpen, J. Ryan; Mazza, Sarah E.; Mako, Calvin A.; Krabbendam, Maarten; Spencer, Brandon M.; Ashley, Kyle T.; Strachan, Robin A.; Davis, Ella F. (MDPI, 2021-09-30)Moine metasedimentary rocks of northern Scotland are characterized by arcuate map patterns of mineral lineations that swing progressively clockwise from orogen-perpendicular E-trending lineations in greenschist facies mylonites above the Moine thrust on the foreland edge of the Caledonian Orogen, to S-trending lineations at higher structural levels and metamorphic grades in the hinterland. Quartz c-axis fabrics measured on a west to east coast transect demonstrate that the lineations developed parallel to the maximum principal extension direction and therefore track the local tectonic transport direction. Microstructures and c-axis fabrics document a progressive change from top to the N shearing in the hinterland to top to the W shearing on the foreland edge. Field relationships indicate that the domain of top to the N shearing was at least 55 km wide before later horizontal shortening on km-scale W-vergent folds that detach on the underlying Moine thrust. Previously published data from the Moine thrust mylonites demonstrate that top to the W shearing had largely ceased by 430 Ma, while preliminary isotopic age data suggest top to the N shearing occurred at ~470–450 Ma. In addition, data from the east coast end of our transect indicate normal-sense top down-SE shearing at close to peak temperatures at ~420 Ma that may be related to the closing stages of Scandian deformation, metamorphism and cooling/exhumation.
- Water loss during dynamic recrystallization of Moine thrust quartzites, northwest ScotlandKronenberg, Andreas K.; Ashley, Kyle T.; Francsis, Matthew K.; Holyoke, Caleb W.; Jezek, Lynna; Kronenberg, Johannes A.; Law, Richard D.; Thomas, Jay B. (2020-06)Infrared absorption measurements of molecular water in sheared Cambrian quartzites in the footwall to the Moine thrust reveal a decrease in water content from 4080 to 1570 ppm with increasing recrystallization traced toward the overlying thrust at the Stack of Glencoul in northwest Scotland. These results are contrary to the expected correlation between shear strain and water content for quartz deformed by dislocation creep and water-weakening processes. The observed inverse correlation indicates that fluid inclusions and hydrous defects within grains were lost by mobile grain boundary sweeping and grain boundary diffusion. Although reduced water contents might lead to hardening as chemical weakening is diminished, quartz mylonites in the immediate footwall (5 mm) to the thrust are characterized by intense strain localization and contain the least water, and there is little evidence of shear zone widening. Water weakening appears to have been important throughout the quartz mylonites, controlled by the presence of water, not by water concentration. Fluids present within relict inclusions and at grain boundaries may have governed the high water fugacities critical for water weakening.