Browsing by Author "Atekwana, Estella A."

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    Instantaneous 3D tomography-based convection beneath the Rungwe Volcanic Province, East Africa: implications for melt generation
    Njinju, Emmanuel A.; Stamps, D. Sarah; Atekwana, Estella A.; Rooney, Tyrone O.; Rajaonarison, Tahiry A. (Oxford University Press, 2023-10)
    Within the Western Branch of the East African Rift (EAR), volcanism is highly localized, which is distinct from the voluminous magmatism seen throughout the Eastern Branch of the EAR. A possible mechanism for the source of melt beneath the EAR is decompression melting in response to lithospheric stretching. However, the presence of pre-rift magmatism in both branches of the EAR suggest an important role of plume-lithosphere interactions, which validates the presence of voluminous magmatism in the Eastern Branch, but not the localized magmatism in the Western Branch. We hypothesize that the interaction of a thermally heterogeneous asthenosphere (plume material) with the base of the lithosphere enables localization of deep melt sources beneath the Western Branch where there are sharp variations in lithospheric thickness. To test our hypothesis, we investigate sublithospheric mantle flow beneath the Rungwe Volcanic Province (RVP), which is the southernmost volcanic center in the Western Branch. We use seismically constrained lithospheric thickness and sublithospheric mantle structure to develop an instantaneous 3D thermomechanical model of tomography-based convection (TBC) with melt generation beneath the RVP using ASPECT. Shear wave velocity anomalies suggest excess temperatures reach ∼250 K beneath the RVP. We use the excess temperatures to constrain parameters for melt generation beneath the RVP and find that melt generation occurs at a maximum depth of ∼140 km. The TBC models reveal mantle flow patterns not evident in lithospheric modulated convection (LMC) that do not incorporate upper mantle constraints. The LMC model indicates lateral mantle flow at the base of the lithosphere over a longer interval than the TBC model, which suggests that mantle tractions from LMC might be overestimated. The TBC model provides higher melt fractions with a slightly displaced melting region when compared to LMC models. Our results suggest that upwellings from a thermally heterogeneous asthenosphere distribute and localize deep melt sources beneath the Western Branch in locations where there are sharp variations in lithospheric thickness. Even in the presence of a uniform lithospheric thickness in our TBC models, we still find a characteristic upwelling and melt localization beneath the RVP, which suggest that sublithospheric heterogeneities exert a dominant control on upper mantle flow and melt localization than lithospheric thickness variations. Our TBC models demonstrate the need to incorporate upper mantle constraints in mantle convection models and have global implications in that small-scale convection models without upper mantle constraints should be interpreted with caution.
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    Microbially Induced Anaerobic Oxidation of Magnetite to Maghemite in a Hydrocarbon-Contaminated Aquifer
    Ohenhen, Leonard O.; Feinberg, Joshua M.; Slater, Lee D.; Ntarlagiannis, Dimitrios; Cozzarelli, Isabelle M.; Rios-Sanchez, Miriam; Isaacson, Carl W.; Stricker, Alexis; Atekwana, Estella A. (American Geophysical Union, 2022-04)
    Iron mineral transformations occurring in hydrocarbon-contaminated sites are linked to the biodegradation of the hydrocarbons. At a hydrocarbon-contaminated site near Bemidji, Minnesota, USA, measurements of magnetic susceptibility (MS) are useful for monitoring the natural attenuation of hydrocarbons related to iron cycling. However, a transient MS, previously observed at the site, remains poorly understood and the iron mineral phases acting as reactants and products associated with this MS perturbation remain largely unknown. To address these unknowns, we acquired mineral magnetism measurements, including hysteresis loops, backfield curves, and isothermal remanent magnetizations on sediment core samples retrieved from the site and magnetite-filled mineral packets installed within the aquifer. Our data show that the core samples and magnetite packs display decreasing magnetization with time and that this loss in magnetization is accompanied by increasing bulk coercivity consistent with decreased average grain size and/or partial oxidation. Low-temperature magnetometry on all samples displayed behavior consistent with magnetite, but samples within the plume also show evidence of maghemitization. This interpretation is supported by the occurrence of shrinkage cracks on the surface of the grains imaged via scanning electron microscopy. Magnetite transformation to maghemite typically occurs under oxic conditions, here, we propose that maghemitization occurs within the anoxic portions of the plume via microbially mediated anaerobic oxidation. Mineral dissolution also occurs within the plume. Microorganisms capable of such anaerobic oxidation have been identified within other areas at the Bemidji site, but additional microbiological studies are needed to link specific anaerobic iron oxidizers with this loss of magnetization.