Browsing by Author "Brown, Michael Carey"

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    Assessment of Commercial Corrosion Inhibiting Admixtures for Reinforced Concrete
    Brown, Michael Carey (Virginia Tech, 1999-11-11)
    Corrosion of reinforcing steel in concrete exposed to chloride-laden environments is a well-known and documented phenomenon. The need for cost effective systems for protection against corrosion has become increasingly clear since the first observations of severe corrosion damage to interstate bridges in the 1960's. As one potential solution to the mounting problem of corrosion deterioration of structures, corrosion-inhibiting admixtures have been researched and introduced into service. This report conveys the results of a three-part laboratory study of corrosion inhibiting admixtures in concrete. The commercial corrosion inhibiting admixtures for concrete have been analyzed by three evaluation methods, including: • Conventional concrete corrosion cell prisms under ponding, • Black steel reinforcing bars immersed in simulated concrete pore solutions, • Electrochemical screening tests of special carbon steel specimens in electrochemical corrosion cells containing filtered cement slurry solution. The purposes of the study include: • Determining the influence of a series of commercially available corrosion inhibiting admixtures on general concrete handling, performance and durability properties not related to corrosion. • Determining the effectiveness of corrosion inhibiting admixtures for reduction or prevention of corrosion of reinforcing steel in concrete, relative to untreated systems, under laboratory conditions. • Conducting a short-term pore solution immersion test for inhibitor performance and relating the results to those of the more conventional long-term corrosion monitoring techniques that employ admixtures in reinforced concrete prisms. • Determining whether instantaneous electrochemical techniques can be applied in screening potential inhibitor admixtures. Concrete properties under test included air content, slump, heat of hydration, compressive strength, and electrical indication of chloride permeability. Monitoring of concrete prism specimens included macro-cell corrosion current, mixed-cell corrosion activity as indicated by linear polarization, and ancillary temperature, relative humidity, and chloride concentration documentation. Simulated pore solution specimens were analyzed on the basis of weight loss and surface area corroded as a function of chloride exposure. Electrochemical screening involved polarization resistance of steel in solution. Results include corrosion potential, polarization resistance and corrosion current density.
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    Corrosion Protection Service Life of Epoxy Coated Reinforcing Steel in Virginia Bridge Decks
    Brown, Michael Carey (Virginia Tech, 2002-05-03)
    The corrosion protection service life extension provided by epoxy-coated reinforcement (ECR) was determined by comparing ECR and bare bar from 10 bridge decks built between 1981 and 1995. The objective was to determine the corrosion protection service life time extension provided by ECR field specimens with various degrees of coating adhesion: disbonded, partially disbonded, and wholly bonded coatings. The size and length distributions of cracks in Virginia bridge decks were investigated to assess the frequency and severity of cracks. Correlation of cracks with chloride penetration was used to characterize the influence of cracking on deck deterioration. Cracks influence the rate of chloride penetration, but the frequency and width distributions of cracks indicate that cracks are not likely to shorten the overall service life of most bridge decks in Virginia. Altogether, 141 drilled cores, 102 mm (4 inches) in diameter, were employed in this study. For each of the decks built with ECR, 10 to 12 cores were drilled through a top reinforcing bar adjacent to the previous study core locations. In addition, approximately 3 cores were drilled through a top reinforcing bar at a surface crack location. Laboratory testing involved nondestructive monitoring using advanced electrochemical techniques to periodically assess the corrosion state of the steel bars during cyclic exposure to chloride-rich solution over 22 months of treatment. Time of corrosion initiation and time of cracking (where applicable), as well as chloride content of the concrete before and after treatment, were used in the analysis. Less than 25 percent of all Virginia bridge decks built under specifications in place since 1981 is projected to corrode sufficiently to require rehabilitation within 100 years, regardless of bar type. The corrosion service life extension attributable to ECR in bridge decks was found to be approximately 5 years beyond that of bare steel.