Browsing by Author "Devine, Christina"

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    Evaluating Water Lead Levels During the Flint Water Crisis
    Pieper, Kelsey J.; Martin, Rebekah L.; Tang, Min; Walters, LeeAnne; Parks, Jeffrey L.; Roy, Siddhartha; Devine, Christina; Edwards, Marc A. (ACS, 2018-06-22)
    In April 2014, the drinking water source in Flint, Michigan was switched from Lake Huron water with phosphate inhibitors to Flint River water without corrosion inhibitors. The absence of corrosion control and use of a more corrosive source increased lead leaching from plumbing. Our city-wide citizen science water lead results contradicted official claims that there was no problem– our 90th percentile was 26.8 μg/L, which was almost double the Lead and Copper Rule action level of 15 μg/L. Back calculations of a LCR sampling pool with 50% lead pipes indicated an estimated 90th percentile lead value of 31.7 μg/L (±4.3 μg/L). Four subsequent sampling efforts were conducted to track reductions in water lead after the switch back to Lake Huron water and enhanced corrosion control. The incidence of water lead varied by service line material. Between August 2015 and November 2016, median water lead reduced from 3.0 to <1 μg/L for homes with copper service lines, 7.2–1.9 μg/L with galvanized service lines, and 9.9–2.3 μg/L with lead service lines. As of summer 2017, our 90th percentile of 7.9 μg/L no longer differed from official results, which indicated Flint’s water lead levels were below the action level.
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    A Standardized Test Protocol for Evaluation of Scale Reduction Technologies
    Devine, Christina; Wang, Fei; Edwards, Marc A. (2021-10-27)
    Precipitation of calcium carbonate (i.e., scaling) can occur in both traditional tank (electric and gas) and "green" tankless hot water systems that have implications for public health, water and energy sustainability, infrastructure damage, and consumer esthetics. There are many scale reduction devices and technologies that aim to reduce or eliminate such problems, and several standardized methods have been proposed to research their performance with scientific rigor. All of the existing approaches were inherently nonreproducible or could not quantify important aspects of scale deposition, including quantity, location, and deposit durability. Here we develop and vet a Standardized Scaling Test Protocol that overcomes many of these deficiencies, using a laboratory-scale model premise plumbing system and a synthesized synthetic scaling water that could be reproduced in any laboratory. This approach produced 25.1 g of calcium carbonate scaling (95% confidence interval of 20.3-29.8 g, n = 3) in similar to 5 days. Illustrative scale reduction for a range of representative technologies, including cation exchange, electrochemical deionization, magnetism, electric field generator, media-induced precipitation, phosphate sacrificial media, and citric acid sacrificial media, ranged from 0% to 100% using the standardized protocol. The general approach was also applied to suitable local natural water with high scaling potential, and similar capabilities were observed.