Browsing by Author "Ghosh, Suvojit"

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    Patterning the Stiffness of Elastomeric Nanocomposites by Magnetophoretic Control of Cross-linking Impeder Distribution
    Ghosh, Suvojit; Tehrani, Mehran; Al-Haik, Marwan S.; Puri, Ishwar K. (MDPI, 2015-01-30)
    We report a novel method to pattern the stiffness of an elastomeric nanocomposite by selectively impeding the cross-linking reactions at desired locations while curing. This is accomplished by using a magnetic field to enforce a desired concentration distribution of colloidal magnetite nanoparticles (MNPs) in the liquid precursor of polydimethysiloxane (PDMS) elastomer. MNPs impede the cross-linking of PDMS; when they are dispersed in liquid PDMS, the cured elastomer exhibits lower stiffness in portions containing a higher nanoparticle concentration. Consequently, a desired stiffness pattern is produced by selecting the required magnetic field distribution a priori. Up to 200% variation in the reduced modulus is observed over a 2 mm length, and gradients of up to 12.6 MPa·mm−1 are obtained. This is a significant improvement over conventional nanocomposite systems where only small unidirectional variations can be achieved by varying nanoparticle concentration. The method has promising prospects in additive manufacturing; it can be integrated with existing systems thereby adding the capability to produce microscale heterogeneities in mechanical properties.
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    Self-assembly of magnetic nanoparticles: A tool for building at the nanoscale
    Ghosh, Suvojit (Virginia Tech, 2014-01-15)
    Nanoparticles can be used as building blocks of materials. Properties of such materials depend on the organization of the constituent particles. Thus, control over particle organization enables control over material properties. However, robust and scalable methods for arranging nanoparticles are still lacking. This dissertation explores the use of an externally applied magnetic field to organize magnetic nanoparticles into microstructures of desired shape. It extends to proofs of concept towards applications in material design and tissue engineering. First, external control over dipolar self-assembly of magnetic nanoparticles (MNPs) in a liquid dispersion is investigated experimentally. Scaling laws are derived to explain experimental observations, correlating process control variables to microstructure morphology. Implications of morphology on magnetic properties of such structures are then explored computationally. Specifically, a method is proposed wherein superparamangetic nanoparticles, having no residual magnetization, can be organized into anisotropic structures with remanence. Another application explores the use of magnetic forces in organizing human cells into three-dimensional (3D) structures of desired shape and size. When magnetized cells are held in place for several days, they are seen to form inter-cellular contacts and organize themselves into tight clusters. This provides a method for 3D tissue culture without the use of artificial scaffolding materials. Finally, a method to pattern heterogeneities in the stiffness of an elastomer is developed. This makes use of selective inhibition of the catalyst of crosslinking reactions by magnetite nanoparticles. The last chapter discusses future possibilities.