Browsing by Author "Lerkkasemsan, Nuttapol"

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    Life Cycle Costs and Life Cycle Assessment for the Harvesting, Conversion, and the Use of Switchgrass to Produce Electricity
    Lerkkasemsan, Nuttapol; Achenie, Luke E. K. (Hindawi, 2013-09-23)
    This paper considers both LCA and LCC of the pyrolysis of switchgrass to use as an energy source in a conventional power plant. The process consists of cultivation, harvesting, transportation, storage, pyrolysis, transportation, and power generation. Here pyrolysis oil is converted to electric power through cocombustion in conventional fossil fuel power plants. Several scenarios are conducted to determine the effect of selected design variables on the production of pyrolysis oil and type of conventional power plants. The set of design variables consist of land fraction, land shape, the distance needed to transport switchgrass to the pyrolysis plant, the distance needed to transport pyrolysis oil to electric generation plant, and the pyrolysis plant capacity. Using an average agriculture land fraction of the United States at 0.4, the estimated cost of electricity from pyrolysis of 5000 tons of switchgrass is the lowest at $0.12 per kwh. Using natural gas turbine power plant for electricity generation, the price of electricity can go as low as 7.70 cent/kwh. The main advantage in using a pyrolysis plant is the negative GHG emission from the process which can define that the process is environmentally friendly.
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    Mechanistic Modeling of Biodiesel Production via Heterogeneous Catalysis
    Lerkkasemsan, Nuttapol (Virginia Tech, 2010-05-04)
    Biodiesel has emerged as a promising renewable and clean energy alternative to petrodiesel. While biodiesel has traditionally been prepared through homogeneous basic catalysis, heterogeneous acid catalysis has been investigated recently due to its ability to convert cheaper but high free fatty acid content oils such as waste vegetable oil while decreasing production cost. In this work, the esterification of free fatty acid over sulfated zirconia and activated acidic alumina in a batch reactor was considered. The models of the reaction over the catalysts were developed in two parts. First, a kinetic study was performed using a deterministic model to develop a suitable kinetic expression; the related parameters were subsequently estimated by numerical techniques. Second, a stochastic model was developed to further confirm the nature of the reaction at the molecular level. The esterification of palmitic acid obeyed the Eley-Rideal mechanism in which palmitic acid and methanol are adsorbed on the surface for SO?/ZrO?-550°C and AcAl?O? respectively. The coefficients of determination of the deterministic model were 0.98, 0.99 and 0.99 for SO?/ZrO?-550°C at 40, 60 and 80°C respectively and 0.99, 0.98 and 0.96 for AcAl?O? at the same temperature. The deterministic and stochastic models were in good agreement.
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    Modeling of Bioenergy Production
    Lerkkasemsan, Nuttapol (Virginia Tech, 2014-06-06)
    In this dissertation we address three different sustainability concepts: [1] modeling of biodiesel production via heterogeneous catalysis, [2] life cycle analysis for pyrolysis of switchgrass for using in power plant, and [3] modeling of pyrolysis of biomass. Thus we deal with Specific Aim 1, 2 and 3. In Specific Aim 1, the models for esterification in biodiesel production via heterogeneous catalysis were developed. The models of the reaction over the catalysts were developed in two parts. First, a kinetic study was performed using a deterministic model to develop a suitable kinetic expression; the related parameters were subsequently estimated by numerical techniques. Second, a stochastic model was developed to further confirm the nature of the reaction at the molecular level. The deterministic and stochastic models were in good agreement. In Specific Aim 2, life cycle analysis and life cycle cost for pyrolysis of switchgrass for using in power plant model were developed. The greenhouse gas (GHG) emission for power generation was investigated through life cycle assessment. The process consists of cultivation, harvesting, transportation, storage, pyrolysis, transportation and power generation. Here pyrolysis oil is converted to electric power through co- combustion in conventional fossil fuel power plants. The conventional power plants which are considered in this work are diesel engine power plant, natural gas turbine power plant, coal-fired steam-cycle power plant and oil-fired steam-cycle power plant. Several scenarios are conducted to determine the effect of selected design variables on the production of pyrolysis oil and type of conventional power plants. In Specific Aim 3, pyrolysis of biomass models were developed. Since modeling of pyrolysis of biomass is complex and challenging because of short reaction times, temperatures as high as a thousand degrees Celsius, and biomass of varying or unknown chemical compositions. As such a deterministic model is not capable of representing the pyrolysis reaction system. We propose a new kinetic reaction model, which would account for significant uncertainty. Specifically we have employed fuzzy modeling using the adaptive neuro-fuzzy inference system (ANFIS) in order to describe the pyrolysis of biomass. The resulting model is in better agreement with experimental data than known deterministic models.