Browsing by Author "Lin, Shihong"

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    Mitigation of bidirectional solute flux in forward osmosis via membrane surface coating of zwitterion functionalized carbon nanotubes
    Zou, Shiqiang; Smith, Ethan D.; Lin, Shihong; Martin, Stephen M.; He, Zhen (Elsevier, 2019-07-08)
    Forward osmosis (FO) has emerged as a promising membrane technology to yield high-quality reusable water from various water sources. A key challenge to be solved is the bidirectional solute flux (BSF), including reverse solute flux (RSF) and forward solute flux (FSF). Herein, zwitterion functionalized carbon nanotubes (Z-CNTs) have been coated onto a commercial thin film composite (TFC) membrane, resulting in BSF mitigation via both electrostatic repulsion forces induced by zwitterionic functional groups and steric interactions with CNTs. At a coating density of 0.97 gm⁻², a significantly reduced specific RSF was observed for multiple draw solutes, including NaCl (55.5% reduction), NH₄H₂PO₄(83.8%), (NH₄)₂HPO₄ (74.5%), NH₄Cl (70.8%), and NH₄HCO₃ (61.9%). When a synthetic wastewater was applied as the feed to investigate membrane rejection, FSF was notably reduced by using the coated membrane with fewer pollutants leaked to the draw solution, including NH₄⁺-N (46.3% reduction), NO₂⁻₋N (37.0%), NO₂⁻₋N (30.3%), K⁺ (56.1%), PO₄³⁻₋P (100%), and Mg²⁺ (100%). When fed with real wastewater, a consistent water flux was achieved during semi-continuous operation with enhanced fouling resistance. This study is among the earliest efforts to address BSF control via membrane modification, and the results will encourage further exploration of effective strategies to reduce BSF.
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    Numerical Analysis and Parameter Optimization of Portable Oscillating-Body Wave Energy Converters
    Capper, Joseph David (Virginia Tech, 2021-06-14)
    As a clean, abundant, and renewable source of energy with a strategic location in close proximity to global population regions, ocean wave energy shows major promise. Although much wave energy converter development has focused on large-scale power generation, there is also increasing interest in small-scale applications for powering the blue economy. In this thesis, the objective was to optimize the performance of small-sized, portable, oscillating-body wave energy converters (WECs). Two types of oscillating body WECs were studied: bottom hinged and two-body attenuator. For the bottom-hinged device, the goal was to show the feasibility of an oscillating surge WEC and desalination system using numerical modeling to estimate the system performance. For a 5-day test period, the model estimated 517 L of freshwater production with 711 ppm concentration and showed effective brine discharge, agreeing well with preliminary experimental results. The objective for the two-body attenuator was to develop a method of power maximization through resonance tuning and numerical simulation. Three different geometries of body cross sections were used for the study with four different drag coefficients for each geometry. Power generation was maximized by adjusting body dimensions to match the natural frequency with the wave frequency. Based on the time domain simulation results, there was not a significant difference in power between the geometries when variation in drag was not considered, but the elliptical geometry had the highest power when using approximate drag coefficients. Using the two degree-of-freedom (2DOF) model with approximate drag coefficients, the elliptical cross section had a max power of 27.1 W and 7.36% capture width ratio (CWR) for regular waves and a max power of 8.32 W and 2.26% CWR for irregular waves. Using the three degree-of-freedom (3DOF) model with approximate drag coefficients, the elliptical cross section had a max power of 22.5 W and 6.12% CWR for regular waves and 6.18 W and 1.68% CWR for irregular waves. A mooring stiffness study was performed with the 3DOF model, showing that mooring stiffness can be increased to increase relative motion and therefore increase power.