Browsing by Author "Rippy, Megan A."
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- Adaptive strategy biases in engineered ecosystems: Implications for plant community dynamics and the provisioning of ecosystem services to peopleKrauss, Lauren; Rippy, Megan A. (2022-11-22)1. Plant communities in green stormwater infrastructure (GSI) such as biofilters play an integral role in ecosystem services provisioning, such that many design manuals now feature plant lists that guide vegetation selection. 2. This study looks at the implications of those lists for biofilter plant communities and their services, focusing on (1) how plants are selected across US climate zones, (2) whether selected plants exhibit adaptive strategy biases (i.e. towards competitive, stress tolerant or ruderal strategies that might impact ecosystem services provisioning) and (3) whether human-induced selection or natural climatic processes underly any biases revealed. 3. Our results suggest that biofilter plant strategies are significantly biased towards stress tolerance or competitiveness (depending on the climate zone) and away from ruderalness relative to the broader pool of native and wetland-adapted native species. 4. Competitive bias was evident in humid-continental climates and stress-tolerant bias in hot coastal/arid climates, with some degree of anti-ruderal bias present across all zones. 5. These biases are correlated with human concerns related to water availability and climate (water conservation; p < 0.05, irrigation; p < 0.1, climate extremes; p < 0.1). They do not appear to reflect strict climatological limits (i.e. limits that are independent of preferences or design constraints imposed by people) because they are not also evident for native plants. 6. The benefits and costs of relaxing these biases are discussed, focusing on the implications for water quality, hydrologic, and cultural services provisioning and the dynamicity of GSI ecosystems, particularly their capacity to self-repair, a prerequisite for the development of self-sustaining GSI.
- Addressing the Contribution of Indirect Potable Reuse to Inland Freshwater SalinizationBhide, Shantanu V.; Grant, Stanley B.; Parker, Emily A.; Rippy, Megan A.; Godrej, Adil N.; Kaushal, Sujay S.; Prelewicz, Gregory; Saji, Niffy; Curtis, Shannon; Vikesland, Peter J.; Maile-Moskowitz, Ayella; Edwards, Marc A.; Lopez, Kathryn; Birkland, Thomas A.; Schenk, Todd (2021-02-02)Inland freshwater salinity is rising worldwide, a phenomenon called the freshwater salinization syndrome (FSS). We investigate a potential conflict between managing the FSS and indirect potable reuse, the practice of augmenting water supplies through the addition of reclaimed wastewater to surface waters and groundwaters. From time-series data collected over 25 years, we quantify the contributions of three salinity sources—a wastewater reclamation facility and two rapidly urbanizing watersheds—to the rising concentration of sodium (a major ion associated with the FSS) in a regionally important drinking water reservoir in the Mid-Atlantic United States. Sodium mass loading to the reservoir is primarily from watershed runoff during wet weather and reclaimed wastewater during dry weather. Across all timescales evaluated, sodium concentration in the reclaimed wastewater is higher than in outflow from the two watersheds. Sodium in reclaimed wastewater originates from chemicals added during wastewater treatment, industrial and commercial discharges, human excretion, and down-drain disposal of drinking water and sodium-rich household products. Thus, numerous opportunities exist to reduce the contribution of indirect potable reuse to sodium pollution at this site, and the FSS more generally. These efforts will require deliberative engagement with a diverse community of watershed stakeholders and careful consideration of the local political, social, and environmental context.
- The anthropogenic salt cycleKaushal, Sujay S.; Likens, Gene E.; Mayer, Paul M.; Shatkay, Ruth R.; Shelton, Sydney A.; Grant, Stanley B.; Utz, Ryan M.; Yaculak, Alexis M.; Maas, Carly M.; Reimer, Jenna E.; Bhide, Shantanu V.; Malin, Joseph T.; Rippy, Megan A. (SpringerNature, 2023-10-31)Increasing salt production and use is shifting the natural balances of salt ions across Earth systems, causing interrelated effects across biophysical systems collectively known as freshwater salinization syndrome. In this Review, we conceptualize the natural salt cycle and synthesize increasing global trends of salt production and riverine salt concentrations and fluxes. The natural salt cycle is primarily driven by relatively slow geologic and hydrologic processes that bring different salts to the surface of the Earth. Anthropogenic activities have accelerated the processes, timescales and magnitudes of salt fluxes and altered their directionality, creating an anthropogenic salt cycle. Global salt production has increased rapidly over the past century for different salts, with approximately 300 Mt of NaCl produced per year. A salt budget for the USA suggests that salt fluxes in rivers can be within similar orders of magnitude as anthropogenic salt fluxes, and there can be substantial accumulation of salt in watersheds. Excess salt propagates along the anthropogenic salt cycle, causing freshwater salinization syndrome to extend beyond freshwater supplies and affect food and energy production, air quality, human health and infrastructure. There is a need to identify environmental limits and thresholds for salt ions and reduce salinization before planetary boundaries are exceeded, causing serious or irreversible damage across Earth systems.
- Balancing the Water Budget: the effect of plant functional type on infiltration to harvest ratios in stormwater bioretention cellsKrauss, Lauren Marie (Virginia Tech, 2021-01-19)Stormwater bioretention cells (BRCs) are a variety of green stormwater infrastructure with the potential to restore pre-urban water balance, provided they can be tailored to infiltrate and evapotranspire (i.e., harvest) urban runoff in proportions consistent with pre-urban hydrologic conditions. This paper evaluates their capacity to do so, focusing on evapotranspirative harvest, which is relatively understudied, and the capacity of CSR (Competitve, Stress-tolerant, and Ruderal) functional type to serve as an overarching framework characterizing the water use strategy of BRC plants. The goal is to determine if harvest (and therefore the ratio of urban runoff infiltrated to harvested; the I:H ratio) might be fine-tuned to meet pre-urban values in BRCs through informed manipulation of plant community composition. This study focuses on 3 critical plant water use traits, the turgor loss point, the point of incipient water stress, and maximum stomatal conductance. A global plant traits meta-analysis identified degree of plant competitiveness and stress tolerance as significant determinants of all three water use traits, with stem type (woody vs herbaceous) also being significant, but only for turgor loss point. Based on these results, six water use scenarios appropriate for plants with different CSR type/stem type combinations were developed. BRC plants spanning the range of CSR types necessary to actionize these scenarios were determined to be available in eight major climate zones of the coterminous US, suggesting that regulating plant water use in BRCs using CSR is likely feasible. Hydraulic simulations (Hydrus 1D) were conducted for each scenario in all eight climate zones and revealed significant differences in evapotranspirative harvest and I:H ratios in simulated BRCs. Competitive woody plants had the highest evapotranspiration and lowest I:H ratios; 1.5-1.8 times more evapotranspiration and a 1.6-2 times lower I:H ratio than stress tolerant herbaceous plants, on average, across climate zones. Despite these significant differences, no simulated BRC in any climate zone was capable of reproducing pre-urban I:H ratios, regardless of plant type. More water was infiltrated than harvested in all scenarios and climates with the inverse being true for all pre-urban conditions. This suggests that absent additional sources of harvest (e.g., use of BRC water for nonpotable purposes such as toilet flushing and outdoor irrigation, or adoption of novel BRC designs that promote lateral exfiltration, stimulating "extra" evapotranspiration from nearby landscapes), BRCs will be unable to restore pre-urban water balance on their own. If true, then using BRCs in combination with other green technologies (particularly those biased towards harvest), may be the best path forward for balancing urban water budgets.
- Can Common Pool Resource Theory Catalyze Stakeholder-Driven Solutions to the Freshwater Salinization Syndrome?Grant, Stanley B.; Rippy, Megan A.; Birkland, Thomas A.; Schenk, Todd; Rowles, Kristin; Misra, Shalini; Aminpour, Payam; Kaushal, Sujay; Vikesland, Peter J.; Berglund, Emily; Gomez-Velez, Jesus D.; Hotchkiss, Erin R.; Perez, Gabriel; Zhang, Harry X.; Armstrong, Kingston; Bhide, Shantanu V.; Krauss, Lauren; Maas, Carly; Mendoza, Kent; Shipman, Caitlin; Zhang, Yadong; Zhong, Yinman (American Chemical Society, 2022-09-14)Freshwater salinity is rising across many regions of the United States as well as globally, a phenomenon called the freshwater salinization syndrome (FSS). The FSS mobilizes organic carbon, nutrients, heavy metals, and other contaminants sequestered in soils and freshwater sediments, alters the structures and functions of soils, streams, and riparian ecosystems, threatens drinking water supplies, and undermines progress toward many of the United Nations Sustainable Development Goals. There is an urgent need to leverage the current understanding of salinization's causes and consequences?in partnership with engineers, social scientists, policymakers, and other stakeholders?into locally tailored approaches for balancing our nation's salt budget. In this feature, we propose that the FSS can be understood as a common pool resource problem and explore Nobel Laureate Elinor Ostrom's social-ecological systems framework as an approach for identifying the conditions under which local actors may work collectively to manage the FSS in the absence of top-down regulatory controls. We adopt as a case study rising sodium concentrations in the Occoquan Reservoir, a critical water supply for up to one million residents in Northern Virginia (USA), to illustrate emerging impacts, underlying causes, possible solutions, and critical research needs.
- Characterizing the Impact of Freshwater Salinization on Engineered Ecosystems: Implications for Performance, Resilience, and Self-Repair Through PhytoremediationLong, Samuel Bowen (Virginia Tech, 2023-06-15)Stormwater detention basins are commonly used in the Eastern United States to temporarily store and attenuate stormwater runoff, and also serve as habitats for native and exotic plants. However, during winter, these basins receive saline runoff from road salt application, which contributes to Freshwater Salinization Syndrome (FSS). Since limited research has connected direct measurement of soil and stormwater salinities to biodiversity and phytoremediation potential of salt-tolerant plant species, this thesis aimed to fill this gap. We selected a set of detention basins draining mostly pervious areas, parking lots, or roads in Northern Virginia and measured temporal variations in stormwater and soil salinities, depth profiles of soil salinities, plant community composition, and plant tissue ion concentration. The results indicated elevated levels of sodium, chloride, electrical conductivity (EC), and exchangeable sodium percentage (ESP)/sodium adsorption ratio (SAR) in soil and stormwater after road salt application during winter, followed by a decrease during the growing season for basins draining parking lots and roads. A subsequent increase at the end of the season was observed for all site types. While some stormwater samples exceeded toxicity thresholds, most soil samples did not exceed their respective thresholds nor reach saline or sodic conditions, and native and exotic plant species of both salt-sensitive and salt-tolerant classifications were observed at almost all sites, although proportions of each varied by site type. Tissue analysis of select plants revealed ionic concentrations that generally coincided with observed soil and stormwater concentrations at each major site type. These findings have implications for future detention basin planting regimes to mitigate FSS, and the thesis discusses native plants found to provide the most benefit for phytoremediation.
- Community Ecosystem Services Values Support Conservation and Sustainable Landscape Development: Perspectives From Four University of California CampusesFausey, Kaitlin (Virginia Tech, 2022-12-20)Urban landscapes homogenize our world at global scales. This sameness contributes to "extinction of experience", where people feel increasingly disconnected from native ecosystems and the services they provide. Numerous approaches have been proposed for combatting extinction of experience, all of which require community support to be successful. Because comparative assessments are relatively rare, however, it is difficult to say which options are most supported. We addresses this knowledge gap using human subject surveys and multi-criteria decision analysis to evaluate landscape preferences and their implications for three approaches recommended to combat extinction of experience: ecosystem conservation, turf replacement and nature-based solutions. Our study focuses on universities in Southern California, where native ecosystem remnants, nature-based solutions, lawns, and ornamental gardens co-exist, which is necessary to compare community support for transitions among them. Our results suggest that conservation of native ecosystems, particularly sage scrub (top ranked landscape overall), is well supported by campus communities, as are turf replacement programs (lawns ranked lowest overall). Support for nature-based solutions was more intermediate (and variable), which may reflect their relative newness, both on university campuses and in urban spaces more generally. Not all university populations preferred the same landscapes; preferences differed with degree of pro-environmentalism and university status (undergrad, graduate student, staff). Even so, all groups exhibited landscape preferences consistent with at least one approach for combatting extinction of experience. This suggests we have a viable set of tools for increasing native ecosystem exposure on university campuses, and ultimately, in the next generation of urban homeowners.
- Designing Smarter Stormwater Systems at Multiple Scales with Transit Time Distribution Theory and Real-Time ControlParker, Emily Ann (Virginia Tech, 2021-06-17)Urban stormwater runoff is both an environmental threat and a valuable water resource. This dissertation explores the use of two stormwater management strategies, namely green stormwater infrastructure and stormwater real-time control (RTC), for capturing and treating urban stormwater runoff. Chapter 2 focuses on clean bed filtration theory and its application to fecal indicator bacteria removal in experimental laboratory-scale biofilters. This analysis is a significant step forward in our understanding of how physicochemical theories can be melded with hydrology, engineering design, and ecology to improve the water quality benefits of green infrastructure. Chapter 3 focuses on the novel application of unsteady transit time distribution (TTD) theory to solute transport in a field-scale biofilter. TTD theory closely reproduces experimental bromide breakthrough concentrations, provided that lateral exchange with the surrounding soil is accounted for. TTD theory also provides insight into how changing distributions of water age in biofilter storage and outflow affect key stormwater management endpoints, such as biofilter pollutant treatment credit. Chapter 4 focuses on stormwater RTC and its potential for improving runoff capture and water supply in areas with Mediterranean climates. We find that the addition of RTC increases the percent of runoff captured, but does not increase the percent of water demand satisfied. Our results suggest that stormwater RTC systems need to be implemented in conjunction with context-specific solutions (such as spreading basins for groundwater recharge) to reliably augment urban water supply in areas with uneven precipitation. Through a combination of modeling and experimental studies at a range of scales, this dissertation lays the foundation for future integration of TTD theory with RTC to improve regional stormwater management.
- Evaluation of Digital PCR (dPCR) for the Quantification of Soil Nitrogen Turnover Bacteria in Wetland Mesocosms in Response to Season, Fertilization, and Plant Species RichnessShah, Parita Raj (Virginia Tech, 2019-02-11)Excess nutrients from nonpoint sources are an ongoing problem that is expected to worsen as population and fertilizer usage rise. Conventional centralized treatment systems are not well suited to address nonpoint source pollution. More distributed best management practices (BMPs) like constructed wetlands are a promising alternative and have been widely implemented in the US since the 1970's. Constructed wetlands are multi-functional systems that can effectively store and transform harmful contaminants using primarily natural processes. However, the removal of pollutants like nitrogen by wetlands is highly variable, likely due to a combination of factors such as plant species-specific assimilation behavior, the effects of plant communities on microbial diversity and function, and variable nitrogen inputs. In this study, the effect of plant species richness (i.e., number of plant species in a system) and seasonal nutrient loading (i.e., nitrogen fertilization) on the microbial community responsible for regulating nitrogen turnover in wetland mesocosm soils was investigated. The chip-based QuantStudio 3D digital PCR (QS3D dPCR) system was used to quantify ammonia-oxidizing bacteria (AOB), nitrite-oxidizing bacteria (NOB), comammox, anammox, and denitrifiers. Principal component analysis (PCA) was used to identify dominant patterns in the microbial community and nitrogen species. Resampling-based analysis of variance (ANOVA) was used to assess statistical significance of any observed differences caused by nitrogen fertilization or plant species richness. Results indicated that fertilization or season, which was convolved with fertilization, was the dominant factor influencing the microbial community in the study environment (27% variance explained), as indicated by the disparate clustering of fall (fertilized) and spring (unfertilized) samples about principal component 1 (fall: negative PC1, spring: positive PC1). Because unplanted unfertilized controls sampled in November clustered within the season in which they were collected rather than with other unfertilized samples collected in May, season may have influenced microbial community shifts more than fertilization for unplanted systems. This finding should be interpreted cautiously, however, given the small number of unplanted unfertilized controls (N = 2) and the absence of similar controls in the planted systems. The most abundant bacterial groups detected in May (November) were AOB, nirK, anammox, and Nitrospira spp. NOB (AOB, anammox, Nitrospira spp. NOB, and nosZ). The effects of plant species richness were more nuanced, with greater richness significantly impacting the abundance of only a subset of bacterial groups (i.e., the nitrifying bacteria AOB, Nitrospira spp. NOB, and comammox, but not the denitrifying bacteria). Different relationships between richness and microbial abundance were observed in different seasonal nutrient loadings (i.e., interaction effects between richness and fertilization were detected for some bacterial groups).
- Five state factors control progressive stages of freshwater salinization syndromeKaushal, Sujay S.; Mayer, Paul M.; Likens, Gene E.; Reimer, Jenna E.; Maas, Carly M.; Rippy, Megan A.; Grant, Stanley B.; Hart, Ian; Utz, Ryan M.; Shatkay, Ruth R.; Wessel, Barret M.; Maietta, Christine E.; Pace, Michael L.; Duan, Shuiwang; Boger, Walter L.; Yaculak, Alexis M.; Galella, Joseph G.; Wood, Kelsey L.; Morel, Carol J.; Nguyen, William; Querubin, Shane Elizabeth C.; Sukert, Rebecca A.; Lowien, Anna; Houde, Alyssa Wellman; Roussel, Anais; Houston, Andrew J.; Cacopardo, Ari; Ho, Cristy; Talbot-Wendlandt, Haley; Widmer, Jacob M.; Slagle, Jairus; Bader, James A.; Chong, Jeng Hann; Wollney, Jenna; Kim, Jordan; Shepherd, Lauren; Wilfong, Matthew T.; Houlihan, Megan; Sedghi, Nathan; Butcher, Rebecca; Chaudhary, Sona; Becker, William D. (Wiley, 2022-03-16)Factors driving freshwater salinization syndrome (FSS) influence the severity of impacts and chances for recovery. We hypothesize that spread of FSS across ecosystems is a function of interactions among five state factors: human activities, geology, flowpaths, climate, and time. (1) Human activities drive pulsed or chronic inputs of salt ions and mobilization of chemical contaminants. (2) Geology drives rates of erosion, weathering, ion exchange, and acidification-alkalinization. (3) Flowpaths drive salinization and contaminant mobilization along hydrologic cycles. (4) Climate drives rising water temperatures, salt stress, and evaporative concentration of ions and saltwater intrusion. (5) Time influences consequences, thresholds, and potentials for ecosystem recovery. We hypothesize that state factors advance FSS in distinct stages, which eventually contribute to failures in systems-level functions (supporting drinking water, crops, biodiversity, infrastructure, etc.). We present future research directions for protecting freshwaters at risk based on five state factors and stages from diagnosis to prognosis to cure.
- Freshwater salinization syndrome limits management efforts to improve water qualityMaas, Carly M.; Kaushal, Sujay S.; Rippy, Megan A.; Mayer, Paul M.; Grant, Stanley B.; Shatkay, Ruth R.; Malin, Joseph T.; Bhide, Shantanu V.; Vikesland, Peter J.; Krauss, Lauren; Reimer, Jenna E.; Yaculak, Alexis M. (Frontiers, 2023-09-22)Freshwater Salinization Syndrome (FSS) refers to groups of biological, physical, and chemical impacts which commonly occur together in response to salinization. FSS can be assessed by the mobilization of chemical mixtures, termed “chemical cocktails”, in watersheds. Currently, we do not know if salinization and mobilization of chemical cocktails along streams can be mitigated or reversed using restoration and conservation strategies. We investigated 1) the formation of chemical cocktails temporally and spatially along streams experiencing different levels of restoration and riparian forest conservation and 2) the potential for attenuation of chemical cocktails and salt ions along flowpaths through conservation and restoration areas. We monitored high-frequency temporal and longitudinal changes in streamwater chemistry in response to different pollution events (i.e., road salt, stormwater runoff, wastewater effluent, and baseflow conditions) and several types of watershed management or conservation efforts in six urban watersheds in the Chesapeake Bay watershed. Principal component analysis (PCA) indicates that chemical cocktails which formed along flowpaths (i.e., permanent reaches of a stream) varied due to pollution events. In response to winter road salt applications, the chemical cocktails were enriched in salts and metals (e.g., Na+, Mn, and Cu). During most baseflow and stormflow conditions, chemical cocktails were less enriched in salt ions and trace metals. Downstream attenuation of salt ions occurred during baseflow and stormflow conditions along flowpaths through regional parks, stream-floodplain restorations, and a national park. Conversely, chemical mixtures of salt ions and metals, which formed in response to multiple road salt applications or prolonged road salt exposure, did not show patterns of rapid attenuation downstream. Multiple linear regression was used to investigate variables that influence changes in chemical cocktails along flowpaths. Attenuation and dilution of salt ions and chemical cocktails along stream flowpaths was significantly related to riparian forest buffer width, types of salt pollution, and distance downstream. Although salt ions and chemical cocktails can be attenuated and diluted in response to conservation and restoration efforts at lower concentration ranges, there can be limitations in attenuation during road salt events, particularly if storm drains bypass riparian buffers.
- From yards to cities: a simple and generalizable probabilistic framework for upscaling outdoor water conservation behaviorGrant, Stanley B.; Duong, Kimberly; Rippy, Megan A.; Pierce, Gregory; Feldman, David; Zanetti, Enrique; McNulty, Amy (2020-05)Outdoor watering of lawns accounts for about half of single-family residential potable water demand in the arid southwest United States. Consequently, many water utilities in the region offer customers cash rebates to replace lawns with drought tolerant landscaping. Here we present a parcel-scale analysis of water savings achieved by a 'cash-for-grass' program offered to 60 000 homes in Southern California. The probability a resident will participate in the program, and the lawn area they replace with drought tolerant landscaping, both increase with a home's outdoor area. The participation probability is also higher if a home is occupied by its owner. From these results we derive and test a simple and generalizable probabilistic framework for upscaling water conservation behavior at the parcel-scale to overall water savings at the city- or water provider-scale, accounting for the probability distribution of parcel outdoor areas across a utility's service area, climate, cultural drivers of landscape choices, conservation behavior, equity concerns, and financial incentives.
- Groundwater Modeling of Managed Aquifer Recharge at the Regional and Local ScaleFrazier, Andrew Dane (Virginia Tech, 2022-06-09)The Hampton Roads Sanitation District is heading a Managed Aquifer Recharge project designed to build water resiliency for the district as well as meet recent regulations concerning effluent released into the Chesapeake Bay. The Sustainable Water Initiative for Tomorrow (SWIFT) project will include five injection well fields across the Virginian Coast. The first of these fields to be implemented is the James River site, scheduled to begin in 2025. A model of the Virginia Coastal Plain region was created in 2009 and has been used to simulate the combined impact of the full-scale SWIFT project. This study estimated the change in hydraulic head in the Potomac Aquifer System caused by the proposed James River recharge well field at a regional and local level. That estimation required the use of a widely accepted model of the Virginia Coastal Plain developed in 2009 which was subjected to a limited validation using USGS monitoring well data for comparison. That model was then used to establish boundary conditions for a local scale model surrounding the James River site, after which each model was used to run four pumping scenarios with varying rates of recharge. The validation of the Virginia Coastal Plain model found it to be satisfactory for the scope of this work, and it was therefore used to interpolate boundary conditions for the developed local model. The regional and local model both showed an increase in the simulated head values of the Potomac Aquifer System. The regional model simulated a sharper initial increase than the local model, however, long term the local model simulated a greater impact to the groundwater levels from the proposed recharge.
- Impact of Indirect Potable Reuse on Endocrine Disrupting Compounds in the Potomac River BasinFlanery, Amelia Lynn (Virginia Tech, 2020-06-17)The Potomac River Basin is significant for both public and ecological health as it flows directly into the ecologically-sensitive Chesapeake Bay. It is a drinking water source for about 5 million people living in Maryland, Virginia, and Washington D.C. The discovery of intersex fish, an indicator of poor ecological health, in the Chesapeake Bay occurred in the 2000s, and has led to a series of studies in the watershed to determine the sources and magnitude of endocrine disruption. Endocrine disrupting compounds (EDCs) are exogenous chemicals that interfere with the endocrine system and can cause detrimental health effects at low concentrations. This study aims to understand a best management practice referred to as planned indirect potable reuse (IPR) and its impacts on EDCs. The Occoquan Watershed is a planned IPR subwatershed of the Potomac River Basin. Water samples were collected at the water reclamation plant discharge (Upper Occoquan Service Authority), up- and downstream of that location along Bull Run, and at the water treatment plant intake (Frederick P. Griffith WTP) in the Occoquan Watershed to assess planned IPR. Samples were also collected at a water treatment plant (James J. Corbalis WTP) along the Potomac River for comparison as an unplanned IPR location. These two groups of samples were analyzed for EDCs (categorized into two groups: estrogen hormones and other synthetic organic compounds (SOCs)), nutrients, and other water quality parameters. The infrequency of estrogen hormones and SOC patterns indicate planned and unplanned IPR are both viable approaches to provide safe drinking water
- Ionic Characterization of Laundry Detergents: Implications for Consumer Choice and Inland Freshwater SalinizationMendoza, Kent Gregory (Virginia Tech, 2024-04-11)Increased salinity in freshwater systems – also called the Freshwater Salinization Syndrome (FSS) – can have far-ranging implications for the natural and built environment, agriculture, and public health at large. Such risks are clearly on display in the Occoquan Reservoir – a drinking water source for roughly one million people in the northern Virginia/ National Capital Region. Sodium concentrations in the Occoquan Reservoir are approaching levels that can affect taste and health. The Reservoir is also noteworthy as a flagship example of indirect potable reuse, which further adds complexity to understanding the sources of rising levels of sodium and other types of salinity. To help understand the role residential discharges might play in salinization of the Occoquan Reservoir, a suite of laundry detergent products was identified based upon survey data collected in the northern Virginia region. The ionic compositions of these products were then characterized using ion chromatography and inductively coupled plasma-mass spectrometry to quantify select ionic and elemental analytes. Sodium, chloride, and sulfate were consistently found in appreciable amounts. To comparatively characterize the laundry detergents, principal component analysis was employed to identify clusters of similar products. The physical formulation of the products was identified as a marker for their content, with dry formulations (free-flowing and encapsulated powders) being more enriched in sodium and sulfate. This result was corroborated by comparing nonparametric bootstrap intervals for individual analytes. The study's findings suggest an opportunity wherein consumer choice can play a role in mediating residential salt inputs in receiving bodies such as the Occoquan Reservoir.
- Longitudinal stream synoptic monitoring tracks chemicals along watershed continuums: a typology of trendsKaushal, Sujay S.; Maas, Carly M.; Mayer, Paul M.; Newcomer-Johnson, Tammy A.; Grant, Stanley B.; Rippy, Megan A.; Shatkay, Ruth R.; Leathers, Jonathan; Gold, Arthur J.; Smith, Cassandra; McMullen, Evan C.; Haq, Shahan; Smith, Rose; Duan, Shuiwang; Malin, Joseph; Yaculak, Alexis; Reimer, Jenna E.; Newcomb, Katie Delaney; Raley, Ashley Sides; Collison, Daniel C.; Galella, Joseph G.; Grese, Melissa; Sivirichi, Gwendolyn; Doody, Thomas R.; Vikesland, Peter J.; Bhide, Shantanu V.; Krauss, Lauren; Daugherty, Madeline; Stavrou, Christina; Etheredge, MaKayla; Ziegler, Jillian; Kirschnick, Andrew; England, William; Belt, Kenneth T. (Frontiers, 2023-06-09)There are challenges in monitoring and managing water quality due to spatial and temporal heterogeneity in contaminant sources, transport, and transformations. We demonstrate the importance of longitudinal stream synoptic (LSS) monitoring, which can track combinations of water quality parameters along flowpaths across space and time. Specifically, we analyze longitudinal patterns of chemical mixtures of carbon, nutrients, greenhouse gasses, salts, and metals concentrations along 10 flowpaths draining 1,765 km2 of the Chesapeake Bay region. These 10 longitudinal stream flowpaths are drained by watersheds experiencing either urban degradation, forest and wetland conservation, or stream and floodplain restoration. Along the 10 longitudinal stream flowpaths, we monitored over 300 total sampling sites along a combined stream length of 337 km. Synoptic monitoring along longitudinal flowpaths revealed: (1) increasing, decreasing, piecewise, or no trends and transitions in water quality with increasing distance downstream, which provide insights into water quality processes along flowpaths; (2) longitudinal trends and transitions in water quality along flowpaths can be quantified and compared using simple linear and non-linear statistical relationships with distance downstream and/or land use/land cover attributes, (3) attenuation and transformation of chemical cocktails along flowpaths depend on: spatial scales, pollution sources, and transitions in land use and management, hydrology, and restoration. We compared our LSS patterns with others from the global literature to synthesize a typology of longitudinal water quality trends and transitions in streams and rivers based on hydrological, biological, and geochemical processes. Applications of LSS monitoring along flowpaths from our results and the literature reveal: (1) if there are shifts in pollution sources, trends, and transitions along flowpaths, (2) which pollution sources can spread further downstream to sensitive receiving waters such as drinking water supplies and coastal zones, and (3) if transitions in land use, conservation, management, or restoration can attenuate downstream transport of pollution sources. Our typology of longitudinal water quality responses along flowpaths combines many observations across suites of chemicals that can follow predictable patterns based on watershed characteristics. Our typology of longitudinal water quality responses also provides a foundation for future studies, watershed assessments, evaluating watershed management and stream restoration, and comparing watershed responses to non-point and point pollution sources along streams and rivers. LSS monitoring, which integrates both spatial and temporal dimensions and considers multiple contaminants together (a chemical cocktail approach), can be a comprehensive strategy for tracking sources, fate, and transport of pollutants along stream flowpaths and making comparisons of water quality patterns across different watersheds and regions.
- Perceived services and disservices of natural treatment systems for urban stormwater: Insight from the next generation of designersRippy, Megan A.; Pierce, Gregory; Feldman, David; Winfrey, Brandon; Mehring, Andrew S.; Holden, Patricia A.; Ambrose, Richard; Levin, Lisa A. (Wiley, 2022)1. Natural treatment systems (NTS) for stormwater have the potential to provide a myriad of ecosystem services to society. Realizing this potential requires active collaboration among engineers, ecologists and landscape planners and begins with a paradigm shift in communication whereby these groups are made aware of each other's perceptions about NTS and the presence of knowledge gaps that their respective disciplines can bridge. 2. Here we participate in the first part of what we hope will be a reciprocal exchange: presenting results from a landscape perceptions survey to urban planners, ecologists and landscape architects that illustrates how the next generation of engineers perceives NTS relative to other landscape features, and the implications of those perceptions for future infrastructure development. 3. Our results suggest that although lawns, gardens and native ecosystems were perceived as multifunctional, providing characteristic bundles of services/disservices, perceptions of NTS were more variable (i.e. there was no social norm for their perception). 4. Environmental worldviews, knowledge, attitudes about ecosystem services and demographics were all significant drivers of perceived services. However, students had difficulty identifying NTS correctly, and factual knowledge about NTS did not help students associate NTS with typical design services like flood reduction more than features not designed for those purposes, such as lawns. This suggests that engineering students lack familiarity with the outward appearance of NTS and have difficulty placing NTS services into a broader landscape context. 5. Expertise from urban planning and ecology could help bridge these knowledge gaps, improving the capacity of tomorrow's engineers to co-design NTS to meet diverse community needs.
- Predicting Solute Transport Through Green Stormwater Infrastructure With Unsteady Transit Time Distribution TheoryParker, E. A.; Grant, Stanley B.; Cao, Y.; Rippy, Megan A.; McGuire, Kevin J.; Holden, P. A.; Feraud, M.; Avasarala, S.; Liu, H.; Hung, W. C.; Rugh, M.; Jay, J.; Peng, J.; Shao, S.; Li, D. (2021-02)In this study, we explore the use of unsteady transit time distribution (TTD) theory to model solute transport in biofilters, a popular form of nature-based or "green" storm water infrastructure (GSI). TTD theory has the potential to address many unresolved challenges associated with predicting pollutant fate and transport through these systems, including unsteadiness in the water balance (time-varying inflows, outflows, and storage), unsteadiness in pollutant loading, time-dependent reactions, and scale-up to GSI networks and urban catchments. From a solution to the unsteady age conservation equation under uniform sampling, we derive an explicit expression for solute breakthrough during and after one or more storm events. The solution is calibrated and validated with breakthrough data from 17 simulated storms at a field-scale biofilter test facility in Southern California, using bromide as a conservative tracer. TTD theory closely reproduces bromide breakthrough concentrations, provided that lateral exchange with the surrounding soil is accounted for. At any given time, according to theory, more than half of the water in storage is from the most recent storm, while the rest is a mixture of penultimate and earlier storms. Thus, key management endpoints, such as the pollutant treatment credit attributable to GSI, are likely to depend on the evolving age distribution of water stored and released by these systems.
- Probabilistic Tropical Cyclone Surge Hazard Under Future Sea-Level Rise Scenarios: A Case Study in The Chesapeake Bay Region, USAKim, Kyutae (Virginia Tech, 2023-07-11)Storm surge flooding caused by tropical cyclones is a devastating threat to coastal regions, and this threat is growing due to sea-level rise (SLR). Therefore, accurate and rapid projection of the storm surge hazard is critical for coastal communities. This study focuses on developing a new framework that can rapidly predict storm surges under SLR scenarios for any random synthetic storms of interest and assign a probability to its likelihood. The framework leverages the Joint Probability Method with Response Surfaces (JPM-RS) for probabilistic hazard characterization, a storm surge machine learning model, and a SLR model. The JPM probabilities are based on historical tropical cyclone track observations. The storm surge machine learning model was trained based on high-fidelity storm surge simulations provided by the U.S. Army Corps of Engineers (USACE). The SLR was considered by adding the product of the normalized nonlinearity, arising from surge-SLR interaction, and the sea-level change from 1992 to the target year, where nonlinearities are based on high-fidelity storm surge simulations and subsequent analysis by USACE. In this study, this framework was applied to the Chesapeake Bay region of the U.S. and used to estimate the SLR-adjusted probabilistic tropical cyclone flood hazard in two areas: one is an urban Virginia site, and the other is a rural Maryland site. This new framework has the potential to aid in reducing future coastal storm risks in coastal communities by providing robust and rapid hazard assessment that accounts for future sea-level rise.
- Understanding the Limits of Residential Water Conservation through Generalized, Basin-Scale System DynamicsWinter, Benjamin Frederick (Virginia Tech, 2023-07-03)Population growth and climate change have strained existing water supplies requiring municipalities to shift towards demand management strategies to ensure reliable water provisions. Particularly in the residential sector, water conservation measures and incentives have been utilized to reduce demand during short-term shortages. As water conservation programs are now being commonly utilized as a way to ensure enough water will be available for continued growth, the impacts on a basin-wide scale have yet to be established. By changing the relative water demand for indoor and outdoor uses within a municipality, the amount of water being consumed can thereby reduce the effluent available for downstream communities. This research investigates how the timing of water conservation, water conservation strategy, and population growth impact water availability in a shared basin. A generalized system dynamics model reflecting typical residential water use and availability patterns similar to the southwest United States was utilized. We found that when upstream municipalities focus their initial reductions on non-consumptive demands, downstream municipalities reliant on upstream return flow have to increase their conservation rate to meet demands and maintain population growth. When most of the basin's population is in upstream municipalities, the more influence their change in water use has on downstream water availability. Therefore, consumptive conservation should be the priority of basin-wide conservation programs to ensure return flow is sufficient to satisfy the demands of downstream municipalities.