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Browsing by Author "Stokes, David"

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    High-Efficiency Skutterudite Modules at a Low Temperature Gradient
    Li, Wenjie; Stokes, David; Poudel, Bed; Saparamadu, Udara; Nozariasbmarz, Amin; Kang, Han Byul; Priya, Shashank (MDPI, 2019-11-11)
    Thermoelectric skutterudite materials have been widely investigated for their potential application in mid-temperature waste heat recovery that has not been efficiently utilized A large amount of research has focused on developing materials with a high thermoelectric figure of merit (zT). However, the translation of material properties to device performance has limited success. Here, we demonstrate single-filling n-type Yb0.25Fe0.25Co3.75Sb12 and multi-filling La0.7Ti0.1Ga0.1Fe2.7Co1.3Sb12 skutterudites with a maximum zT of ~1.3 at 740 K and ~0.97 at 760 K. The peak zT of skutterudites usually occurs above 800 K, but, as shown here, the shift in peak zT to lower temperatures is beneficial for enhancing conversion efficiency at a lower hot-side temperature. In this work, we have demonstrated that the Fe-substitution significantly reduces the thermal conductivity of n-type skutterudite, closer to p-type skutterudite thermal conductivity, resulting in a module that is more compatible to operate at elevated temperatures. A uni-couple skutterudite module was fabricated using a molybdenum electrode and Ga–Sn liquid metal as the thermal interface material. A conversion efficiency of 7.27% at a low temperature gradient of 366 K was achieved, which is among the highest efficiencies reported in the literature at this temperature gradient. These results highlight that peak zT shift and optimized module design can improve conversion efficiency of thermoelectric modules at a low temperature gradient.
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    Low-grade Thermal Energy Harvesting and Waste Heat Recovery
    Kishore, Ravi Anant (Virginia Tech, 2018-12-14)
    Low-grade heat, either in the form of waste heat or natural heat, represents an extremely promising source of renewable energy. A cost-effective method for recovering the low-grade heat will have a transformative impact on the overall energy scenario. Efficiency of heat engines deteriorates with decrease in hot-side temperature, making low-grade heat recovery complex and economically unviable using the current state-of-the-art technologies, such as Organic Rankine cycle, Kalina cycle and Stirling engine. In this thesis, a fundamental breakthrough is achieved in low-grade thermal energy harvesting using thermomagnetic and thermoelectric effects. This thesis systematically investigates two different mechanisms: thermomagnetic effect and thermoelectric effect to generate electricity from the low-grade heat sources available near ambient temperature to 200°C. Using thermomagnetic effect, we demonstrate a novel ultra-low thermal gradient energy recovery mechanism, termed as PoWER (Power from Waste Energy Recovery), with ambient acting as the heat sink. PoWER devices do not require an external heat sink, bulky fins or thermal fluid circulation and generate electricity on the order of 100s μW/cm3 from heat sources at temperatures as low as 24°C (i.e. just 2°C above the ambient) to 50°C. For the high temperature range of 50-200°C, we developed the unique low fill fraction thermoelectric generators that exhibit a much better performance than the commercial modules when operated under realistic conditions such as constant heat flux boundary condition and high thermally resistive environment. These advancements in thermal energy harvesting and waste heat recovery technology will have a transformative impact on renewable energy generation and in reducing global warming.