Browsing by Author "Stratakes, Bethany"
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- Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin filmUsov, Pavel M.; Ahrenholtz, Spencer Rae; Maza, William A.; Stratakes, Bethany; Epley, Charity Cherie; Kessinger, Matthew C.; Zhu, Jie; Morris, Amanda J. (Royal Society of Chemistry, 2016-10-06)Here, we demonstrate a new strategy for cooperative catalysis and proton abstraction via the incorporation of independent species competent in the desired reactivity into a metal–organic framework (MOF) thin film. The highly porous MOF, designated as PCN-224-Ni, is constructed by Zr–oxo nodes and nickel(II) porphyrin linkers. Films of PCN-224-Ni were grown in situ on FTO and were found to electrochemically facilitate the water oxidation reaction at near neutral pH.