Browsing by Author "Wang, Yajian"
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- The Effect of Cross-Linking Type on EPDM Elastomer Dynamics and Mechanical Properties: A Molecular Dynamics Simulation StudyWang, Yajian; Liu, Huifang; Li, Pengpeng; Wang, Linbing (MDPI, 2022-03-24)The cross-linking structure of the Ethylene-propylene-diene monomer (EPDM) is made up of a number of cross-linking types, including carbon atoms from the main chain or monomer and ether crosslinks formed during degradation. Through molecular dynamic simulations, the contribution of each type of cross-linked structure to the dynamics and mechanical properties of EPDM, the study’s focus, were investigated. Cross-linking between the tertiary carbons of two main chains, cross-linking at the monomer’s unsaturated position, ether cross-linking after oxidation, and other combinations of target cross-linked carbon atoms from different positions, totaling eight types of cross-linked types, were mixed with EPDM free chains in a 1:1 ratio to form eight types of cross-linked EPDMs. These varieties of cross-linked EPDMs were then compared to an uncross-linked EPDM in terms of density, radius of gyration, free volume, mean square displacement, and uniaxial tensile stress-strain curves. It was found that the cross-linking was always proven to have a favorable influence on mechanical characteristics; however, the relaxation inhibition effect varied. The cross-linking between the diene monomer at the C9 position resulted in a more flexible molecular shape and was more than double the free volume of the uncross-linked EPDM, resulting in an improved diffusion ability. The ether cross-linking produced by the oxidation of the side chain cross-linking improved the positive contribution to stiffness and enhanced the inhibitory impact on diffusion properties, whereas the main chain cross-linking had the opposite effect. The research presented in this study leads to a better knowledge of the microscopic aspects underlying EPDM performance.
- Multiscale Analytical Method and Its Parametric Study for Lining Joint Leakage of Shield TunnelWang, Yajian; Yang, Yuyou; Su, Fei; Wang, Linbing (MDPI, 2020-11-28)Understanding the underlying processes of lining joint leakage is essential for predicting its waterproofing performance, improving the design, and assessing its operational health in shield tunnels. There is little literature reported on a leakage model that can reflect various influencing factors. This article introduced an analytical method for predicting joint leakage based on recently developed multi-scale contact mechanics: the Persson model. In addition, the critical leakage state and the self-sealing effect were defined, and an approach to calculate the critical leakage pressure, as well as self-sealing stress, were deduced. Then, taking the second Dapu Road Tunnel in Shanghai as a case study, the influence of various factors, including the gap and offset of joints, the roughness of sealing materials, the service time, and groundwater pressure on the lining joint leakage, was calculated. The applicability of the model was verified by comparing the calculated results with the experimental data and monitoring data in the literature. This research could contribute to understanding the development process of seepage in sealing engineering and provide a reference for waterproof design and the performance assessment of shield tunnels’ lining joints.