Browsing by Author "Zhang, Dian"

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    Effect of Process Intensification Techniques on Biosolids Management
    Zhang, Dian (Virginia Tech, 2020-04-10)
    This study is aimed to provide comprehensive evaluation and mechanistic understanding of the impact of process intensification techniques applied in main and side stream wastewater treatment on biosolids management in terms of anaerobic digestion enhancement, dewaterability improvement, odor mitigation, as well as phosphorus and nitrogen removal. The first part of this study was conducted to understand the effect of anaerobic digester solids retention time (SRT) on odor emission from biosolids. A kinetic model and inhibitory studies showed the emission of methanethiol (MT), a representative odor compound, was primarily determined by the dynamic concurrence of MT production from amino acid and utilization by methanogens in the course of anaerobic digestion. MT emission pattern follows a bell-shape curve with SRT in anaerobic digesters. However, for digested and dewatered biosolids, SRT ranging from 15 to 50 days in anaerobic digesters demonstrated insignificant effect on the odor emission from biosolids. In contrast, the peak odor emission was found to exponentially increase with both shear intensity and polymer dose applied during dewatering. The second part of this study investigated the impact of process intensification practices on sludge dewatering performance. The integration of high-rate activated sludge process and anaerobic digestion elevated the sludge orthophosphate level, leading to struvite scaling and dewaterability deterioration. Superior orthophosphate removal, significant improvement of sludge dewaterability, and favorable economics were achieved through sludge conditioning by cerium chloride. Continuous flow aerobic granulation technology offered significant process intensification of mainstream treatment trains. However, its impact on biosolids management was not studied. This study showed that there was little dewaterability difference between aerobic granular sludge and activated sludge when polymer was not added. However, about 75% polymer saving and improved dewatering performance were observed with polymer addition. When subjected to high shear, a greater dewaterability deterioration was observed for granular sludge than activated sludge. The last part of this study is focused on the impact of anaerobic digestion process intensification through thermal treatment including pre-pasteurization, thermophilic anaerobic digestion, temperature phased anaerobic digestion, and thermal hydrolysis pretreatment. Improved methane production, pathogen reduction, dewatering performance, and odor mitigation were observed with the involvement of these high-temperature processes. However, special cautions and measure should be taken during the start-up of these high rate processes as they are more liable to digester souring. In addition, the in-depth understanding of the mechanism of recalcitrant dissolved organic nitrogen formation during sludge thermal pretreatment was provided.
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    Recalcitrant dissolved organic nitrogen formation in thermal hydrolysis pretreatment of municipal sludge
    Zhang, Dian; Feng, Yiming; Huang, Haibo; Khunjar, Wendell; Wang, Zhi-Wu (2020-05)
    Thermal hydrolysis pretreatment (THP) has been considered as an advanced approach to enhance the performance of anaerobic digestion treating municipal sludge. However, several drawbacks were also identified with THP including the formation of brown and ultraviolet-quenching compounds that contain recalcitrant dissolved organic nitrogen (rDON). Melanoidins produced from the Maillard reaction between reducing sugar and amino group have been regarded as a representative of such compounds. This review presented the state-of-the-art understanding of the mechanism of melanoidin formation derived from the research of sludge THP, food processing, and model Maillard reaction systems. Special attentions were paid to factors affecting melanoidin formation and their implications to the control of rDON in the sludge THP process. These factors include reactant availability, heating temperature and time, pH, and the presence of metallic ions. It was concluded that efforts need to be focused on elucidating the extent of the Maillard reaction in sludge THP. This paper aims to provide a mechanistic recommendation on the research and control of the THP-resulted rDON in municipal wastewater treatment plants.
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    Unblocking the rate-limiting step of the municipal sludge anaerobic digestion
    Wang, Jiefu; Sun, Yuepeng; Zhang, Dian; Broderick, Tom; Strawn, Mary; Santha, Hari; Pallansch, Karen; Deines, Allison; Wang, Zhi-Wu (Wiley, 2022-10)
    Anaerobic digestion stabilizes municipal sludge through total solids reduction and biogas production. It is generally accepted that hydrolysis accounts for the rate-limiting step of municipal sludge anaerobic digestion, impacting the overall rates of solids reduction and methane production. Technically, the sludge hydrolysis rate can be enhanced by the application of thermal hydrolysis pretreatment (THP) and is also affected by the total solids concentration, temperature, and solids retention time used in the anaerobic digestion. This study systematically analyzed and compared ways to take these four factors into the consideration of modern anaerobic digestion system for achieving the maximum solid reduction. Results showed that thermophilic anaerobic digestion was superior to mesophilic anaerobic digestion in terms of solids reduction but vice versa in terms of the methane production when integrated with THP. This difference has to do with the intermediate product accumulation and inhibition when hydrolysis outpaced methanogenesis in THP-enhanced thermophilic anaerobic digestion, which can be mitigated by adjusting the solids retention time. Practitioner points THP followed by TAD offers the greatest solids reduction rate. THP followed by MAD offered the greatest methane production rate. FAN inhibition appears to be an ultimate limiting factor constraining the methane production rate. In situ ammonia removal technique should be developed to further unblock the rate-limiting step.