Browsing Faculty Works, Department of Chemistry by Title
Now showing items 1-20 of 109
-
(2S,4R)-4-Fluoro-pyrrolidinium-2-carboxyl-ate.
(International Union of Crystallography, 2012-08-01)The crystal structure of the title compound, C(5)H(8)FNO(2), at 100 K, displays inter-molecular N-H⋯O hydrogen bonding between the ammonium and carboxyl-ate groups as a result of its zwitterionic nature in the solid state. ... -
Acetylcholinesterase of the sand fly, Phlebotomus papatasi (Scopoli): construction, expression and biochemical properties of the G119S orthologous mutant
(2014-12-10)Background Phlebotomus papatasi vectors zoonotic cutaneous leishmaniasis. Previous expression of recombinant P. papatasi acetylcholinesterase (PpAChE1) revealed 85% amino acid sequence identity to mosquito AChE and identified ... -
Antimalarial 5,6-Dihydro-alpha-pyrones from Cryptocarya rigidifolia: Related Bicyclic Tetrahydro-alpha-Pyrones Are Artifacts
(Amer Chemical Soc, 2015-06-01) -
Antiproliferative Compounds from Cleistanthus boivinianus from the Madagascar Dry Forest
(Amer Chemical Soc, 2015-07-01) -
Antiproliferative Trihydroxyalkylcyclohexenones from Pleiogynium timoriense
(Amer Chemical Soc, 2015-07-01) -
Antiproliferative triterpenoid saponins from Leptaulus citroides Baill. from the Madagascar rain forest
(Springer, 2016)Bioassay-guided fractionation of EtOH extracts obtained from the roots and wood of the Madagascan plant Leptaulus citroides Baill. (Cardiopteridaceae) led to the isolation of ethyl esters of three new triterpenoid saponins ... -
Aqua-bis-(4-methyl-benzene-sulfonato-κO)(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III) monohydrate.
(International Union of Crystallography, 2013-05-01)The title half-sandwich rhodium(III) complex, [Rh(C10H15)(C7H7O3S)2(H2O)]·H2O, consists of a π-bonded penta-methyl-cyclo-penta-dienyl group, two σ-bonded tosyl-ate groups and an aqua ligand. The structure displays both ... -
Assembly of Bio-Nanoparticles for Double Controlled Drug Release
(PLOS, 2013-09-06)A critical limiting factor of chemotherapy is the unacceptably high toxicity. The use of nanoparticle based drug carriers has significantly reduced the side effects and facilitated the delivery of drugs. Source of the ... -
An atomic force microscope tip as a light source
(AIP Publishing, 2005-12-01)We present a simple method for causing the end of a silicon nitride atomic force microscope (AFM) tip to emit light, and we use this emitted light to perform scanning near-field optical microscopy. Illumination of a silicon ... -
Atomic-Level Structural Dynamics of Polyoxoniobates during DMMP Decomposition
(Springer Nature, 2017-04-10)Ambient pressure in situ synchrotron-based spectroscopic techniques have been correlated to illuminate atomic-level details of bond breaking and formation during the hydrolysis of a chemical warfare nerve agent simulant ... -
Bis-(η(2)-ethyl-ene)(η(5)-inden-yl)iridium(I).
(2013)The asymmetric unit of the title compound, [Ir(C9H7)(C2H4)2], consists of two independent mol-ecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with ... -
Bis[bis-(penta-methyl-cyclo-penta-dien-yl)cobalt(III)] tetra-chlorido-cobaltate(II) di-chloro-methane disolvate.
(International Union of Crystallography, 2013)The title compound, [Co(C10H15)2]2[CoCl4]·2CH2Cl2, was isolated as a dichloromethane solvate and was formed in the reaction between lithium pentamethylcyclopentadienide and anyhydrous cobalt(II) chloride in tetrahydrofuran. ... -
Block copolymer derived uniform mesopores enable ultrafast electron and ion transport at highmass loadings
(Nature Research, 2019)High mass loading and fast charge transport are two crucial but often mutually exclusive characteristics of pseudocapacitors. On conventional carbon supports, high mass loadings inevitably lead to sluggish electron conduction ... -
Block copolymer–based porous carbon fibers
(American Association for the Advancement of Science, 2019-02-01)Carbon fibers have high surface areas and rich functionalities for interacting with ions, molecules, and particles. However, the control over their porosity remains challenging. Conventional syntheses rely on blending ... -
Boosting the Power-Generation Performance of Micro-Sized Al-H2O2 Fuel Cells by Using Silver Nanowires as the Cathode
(MDPI, 2018-09-03)Micro-sized fuel cells represent one of the pollution-free devices available to power portable electronics. However, the insufficient power output limits the possibility of micro-sized fuel cells competing with other power ... -
Branched Peptide Boronic Acids (BPBAs): A Novel Mode of Binding Towards RNA
(The Royal Society of Chemistry, 2013-02-07)We report branched peptideboronic acids (BPBAs) that bind to RRE IIB from an on-bead high-throughput screening of a 3.3.4-library (46 656 compounds). We demonstrate that boronic acids are tunable moieties that afford a ... -
Cationic Polythiophenes as Responsive DNA-Binding Polymers
(The Royal Society of Chemistry, 2013-09-23)A new water soluble cationic polythiophene derivative, poly(N,N,N-trimethyl-3-(2-(thiophen-3-yl)acetamido)propan-1-aminium iodide), was synthesized via two consecutive post-polymerization functionalizations of poly(methyl ... -
Controlling Morphological Parameters of Anodized Titania Nanotubes for Optimized Solar Energy Applications
(MDPI, 2012-10-19)Anodized TiO2 nanotubes have received much attention for their use in solar energy applications including water oxidation cells and hybrid solar cells [dye-sensitized solar cells (DSSCs) and bulk heterojuntion solar cells ... -
Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film
(Royal Society of Chemistry, 2016-10-06)Here, we demonstrate a new strategy for cooperative catalysis and proton abstraction via the incorporation of independent species competent in the desired reactivity into a metal–organic framework (MOF) thin film. The ... -
Crystal structure of chlorido-(η(2)-phenyl iso-thio-cyanate-κ(2) C,S)-mer-tris-(tri-methyl-phosphane-κP)iridium(I).
(International Union of Crystallography, 2014-11-01)The molecule of the title compound, [IrCl(C7H5NS)(C3H9P)3], is a distorted octa-hedral iridium complex with three PMe3 ligands arranged in a meridional geometry, a chloride ion cis to all three PMe3 groups and the phenyl ...
