Browsing Scholarly Works, Department of Chemistry by Title
Now showing items 1-20 of 152
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(2S,4R)-4-Fluoro-pyrrolidinium-2-carboxyl-ate.
(International Union of Crystallography, 2012-08-01)The crystal structure of the title compound, C(5)H(8)FNO(2), at 100 K, displays inter-molecular N-H⋯O hydrogen bonding between the ammonium and carboxyl-ate groups as a result of its zwitterionic nature in the solid state. ... -
Acetylcholinesterase of the sand fly, Phlebotomus papatasi (Scopoli): construction, expression and biochemical properties of the G119S orthologous mutant
(2014-12-10)Background Phlebotomus papatasi vectors zoonotic cutaneous leishmaniasis. Previous expression of recombinant P. papatasi acetylcholinesterase (PpAChE1) revealed 85% amino acid sequence identity to mosquito AChE and identified ... -
An adaptive variational algorithm for exact molecular simulations on a quantum computer
(Springer Nature, 2019-07-08)Quantum simulation of chemical systems is one of the most promising near-term applications of quantum computers. The variational quantum eigensolver, a leading algorithm for molecular simulations on quantum hardware, has ... -
Ammonium Bisphosphonate Polymeric Magnetic Nanocomplexes for Platinum Anticancer Drug Delivery and Imaging with Potential Hyperthermia and Temperature-Dependent Drug Release
(Hindawi, 2018-08-05)Novel magnetite-ammonium bisphosphonate graft ionic copolymer nanocomplexes (MGICs) have been developed for potential drug delivery, magnetic resonance imaging, and hyperthermia applications. The complexes displayed ... -
An improved laser-schlieren system for measurement of shock-wave velocity
(AIP Publishing, 1974-07)An improved laser_schlieren system for the measurement of shock_wave velocities has been developed which employs a single detector.Calibration of multiple detectors has been obviated. The system has been shown to yield, ... -
Antimalarial 5,6-Dihydro-alpha-pyrones from Cryptocarya rigidifolia: Related Bicyclic Tetrahydro-alpha-Pyrones Are Artifacts
(Amer Chemical Soc, 2015-06-01) -
Antiproliferative Compounds from Cleistanthus boivinianus from the Madagascar Dry Forest
(Amer Chemical Soc, 2015-07-01) -
Antiproliferative Trihydroxyalkylcyclohexenones from Pleiogynium timoriense
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Antiproliferative triterpenoid saponins from Leptaulus citroides Baill. from the Madagascar rain forest
(Springer, 2016)Bioassay-guided fractionation of EtOH extracts obtained from the roots and wood of the Madagascan plant Leptaulus citroides Baill. (Cardiopteridaceae) led to the isolation of ethyl esters of three new triterpenoid saponins ... -
Aqua-bis-(4-methyl-benzene-sulfonato-κO)(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III) monohydrate.
(International Union of Crystallography, 2013-05-01)The title half-sandwich rhodium(III) complex, [Rh(C10H15)(C7H7O3S)2(H2O)]·H2O, consists of a π-bonded penta-methyl-cyclo-penta-dienyl group, two σ-bonded tosyl-ate groups and an aqua ligand. The structure displays both ... -
Aryl ethynyl phthalic anhydrides and polymers with terminal or pendant amines prepared with aryl ethynyl phthalic anhydrides
(United States Patent and Trademark Office, 1996-02-20)Arylethynyl phthalic anhydrides have been synthesized and shown to have particular application as endcappers or pendant groups in high performance/high temperature thermosets which include amine terminal or amine pendant groups. -
Assembly of Bio-Nanoparticles for Double Controlled Drug Release
(PLOS, 2013-09-06)A critical limiting factor of chemotherapy is the unacceptably high toxicity. The use of nanoparticle based drug carriers has significantly reduced the side effects and facilitated the delivery of drugs. Source of the ... -
An atomic force microscope tip as a light source
(AIP Publishing, 2005-12-01)We present a simple method for causing the end of a silicon nitride atomic force microscope (AFM) tip to emit light, and we use this emitted light to perform scanning near-field optical microscopy. Illumination of a silicon ... -
Atomic-Level Structural Dynamics of Polyoxoniobates during DMMP Decomposition
(Springer Nature, 2017-04-10)Ambient pressure in situ synchrotron-based spectroscopic techniques have been correlated to illuminate atomic-level details of bond breaking and formation during the hydrolysis of a chemical warfare nerve agent simulant ... -
Between the Scylla of hidebound conservatism and the Charybdis of mindless speculation
(Inter-Research, 2004)The ‘quality’ of a scientific publication is not an absolute but must be assessed in relation to a journal’s mission. It should be judged primarily by its disciplined intellectual rigor, bearing in mind what course the ... -
Biochar Surface Oxygenation by Ozonization for Super High Cation Exchange Capacity
(2019-10-07)Biochar cation exchange capacity (CEC) is a key property central to better retention of soil nutrients and reduction of fertilizer runoff. This paper reports a breakthrough process to improve biochar CEC value by a factor ... -
Bis-(η(2)-ethyl-ene)(η(5)-inden-yl)iridium(I).
(2013)The asymmetric unit of the title compound, [Ir(C9H7)(C2H4)2], consists of two independent mol-ecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with ... -
Bis[bis-(penta-methyl-cyclo-penta-dien-yl)cobalt(III)] tetra-chlorido-cobaltate(II) di-chloro-methane disolvate.
(International Union of Crystallography, 2013)The title compound, [Co(C10H15)2]2[CoCl4]·2CH2Cl2, was isolated as a dichloromethane solvate and was formed in the reaction between lithium pentamethylcyclopentadienide and anyhydrous cobalt(II) chloride in tetrahydrofuran. ... -
Block copolymer derived uniform mesopores enable ultrafast electron and ion transport at highmass loadings
(Nature Research, 2019)High mass loading and fast charge transport are two crucial but often mutually exclusive characteristics of pseudocapacitors. On conventional carbon supports, high mass loadings inevitably lead to sluggish electron conduction ... -
Block copolymer–based porous carbon fibers
(American Association for the Advancement of Science, 2019-02-01)Carbon fibers have high surface areas and rich functionalities for interacting with ions, molecules, and particles. However, the control over their porosity remains challenging. Conventional syntheses rely on blending ...
