Effect of polyoxymethylene (POM-H Delrin) off-gassing within the Pandora head sensor on direct-sun and multi-axis formaldehyde column measurements in 2016-2019

Analysis of formaldehyde measurements by the Pandora spectrometer systems between 2016 and 2019 suggested that there was a temperature-dependent process inside the Pandora head sensor that emitted formaldehyde. Some parts in the head sensor were manufactured from the thermal plastic polyoxymethylene homopolymer (E.I. Du Pont de Nemour & Co., USA; POM-H Delrin (R)) and were responsible for formaldehyde production. Laboratory analysis of the four Pandora head sensors showed that internal formaldehyde production had exponential temperature dependence with a damping coefficient of 0.0911 +/- 0.0024 degrees C-1 and the exponential function amplitude ranging from 0.0041 to 0.049 DU. No apparent dependency on the head sensor age and heating and cooling rates was detected. The total amount of formaldehyde internally generated by the POM-H Delrin components and contributing to the direct-sun measurements were estimated based on the head sensor temperature and solar zenith angle of the measurements. Measurements in winter, during colder (< 10 degrees C) days in general, and at high solar zenith angles (> 75 degrees) were minimally impacted. Measurements during hot days (> 28 degrees C) and small solar zenith angles had up to 1 DU (2.69 x 10(16 )molec. cm(-2)) contribution from POM-H Delrin parts. Multi-axis differential slant column densities were minimally impacted (< 0.01 DU) due to the reference spectrum being collected within a short time period with a small difference in head sensor temperature. Three new POM-H Delrin free Pandora head sensors (manufactured in summer 2019) were evaluated for temperature-dependent attenuation across the entire spectral range (300 to 530 nm). No formaldehyde absorption or any other absorption above the instrumental noise was observed across the entire spectral range.