Dynamic Mechanical And Thermal Behavior Of Novel Liquid-Crystalline Polybutadiene-Diols with Azobenzene Groups in Side Chains

dc.contributorVirginia Techen
dc.contributor.authorPoláková, Lenkaen
dc.contributor.authorSedlakova, Zdenkaen
dc.contributor.authorBenes, Hyneken
dc.contributor.authorValentova, Helenaen
dc.contributor.authorKrakovsky, Ivanen
dc.contributor.authorRabie, Ferasen
dc.contributor.departmentChemical Engineeringen
dc.date.accessed2014-03-11en
dc.date.accessioned2014-03-26T17:35:13Zen
dc.date.available2014-03-26T17:35:13Zen
dc.date.issued2013-09-01en
dc.description.abstractLiquid-crystalline (LC) polymers containing methoxy-or butoxy-substituted azobenzene in side chains have been prepared via radical addition of the in advance synthesized nematic thiols onto double bonds of poly(butadiene) diol [Polakova et al., Pol. Bull. 54, 315-326 (2010)]. In the present work, thermal behavior of these comblike polymers has been characterized by differential scanning calorimetry and polarizing optical microscopy. LC transitions have been also determined by rheological measurement. Time-temperature superposition of mechanical functions has been successfully applied to samples undergoing direct nematic/glassy state transition. (C) 2013 The Society of Rheology.en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationJ. Rheol. 57, 1297 (2013); http://dx.doi.org/10.1122/1.4815980en
dc.identifier.doihttps://doi.org/10.1122/1.4815980en
dc.identifier.issn0148-6055en
dc.identifier.urihttp://hdl.handle.net/10919/46790en
dc.identifier.urlhttp://scitation.aip.org/content/sor/journal/jor2/57/5/10.1122/1.4815980en
dc.language.isoen_USen
dc.publisherAIP Publishingen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjectElastomersen
dc.subjectRheologyen
dc.subjectPolymersen
dc.subjectOrderen
dc.titleDynamic Mechanical And Thermal Behavior Of Novel Liquid-Crystalline Polybutadiene-Diols with Azobenzene Groups in Side Chainsen
dc.title.serialJournal of Rheologyen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten

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