Browsing by Author "Read, James Fredrick"
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- Architectural Models for Lower Pennsylvanian Strata in Dickenson/Wise County, Southwest Virginia: A Reservior Case StudyDenning, Samuel Fenton (Virginia Tech, 2008-08-29)The lower Pennsylvanian, coal-bearing, siliciclastic strata in Dickenson/Wise counties of southwest Virginia were deposited in continental to marginal marine environments influenced by high-amplitude relative sea level fluctuations. Coal-bearing siliciclastics of the eastern facies belt are fluvio-deltaic in origin, with sediment derived from the erosion of low-grade metamorphic and Grenvillian-Avalonian terranes of the Alleghanian orogen to the southeast. Elongate NNE trending quartzarenite belts in the northwestern region of the basin are braided-fluvial deposits and were sourced by the cratonic Archean Superior Province to the north. This orthogonal relationship between the southeastern coal-bearing siliciclastics and the northwestern quartzarenites reflect a trunk-tributary drainage system operating during the lower Pennsylvanian in the central Appalachian basin. Analysis of core, gamma ray and density logs, and six cross-sections within an approximately 20 km² study area reveals a hierarchy of bounding discontinuities and architectural elements. Discontinuities are both erosional (unconformable) and depositional (condensed) and are 3rd-order (~ 2.5 Ma) and 4th-order (~ 400 k.y.) in origin. Architectural elements are bound by 4th-order discontinuities and consist of upward-fining lowstand and transgressive incised valley fill, alluvial, and estuarine deposits, and upward-coarsening highstand deltaic deposits and represent 4th-order sequences. Lowstand and transgressive deposits are separated from the highstand deposits by marine flooding zones (condensed sections). 4th-order sequences are stacked into composite 3rd-order sequences. Sequence development can be attributed to 4th-order Milankovitch orbital eccentricity cycles superimposed on a lower-frequency eccentricity cycle. Extensive coals occur in both transgressive and highstand systems tracts. Coals within the transgressive systems tract are associated with 4th-order flooding surfaces, while coals within the highstand systems tract occur within high-frequency deltaic autocycles. Therefore, coals formation in the central Appalachian basin can be attributed to be of both allocyclic (glacio-eustacy) and autocyclic (deltaic processes) mechanisms.
- Beekmantown Formation-Middle Ordovician limestone unconformity on the northwest limb of the Green Ridge anticline near Fincastle, VirginiaCampbell, Joseph Kent (Virginia Tech, 1975-08-05)The depositional and erosional history can be summarized as follows: 1) Subtidal carbonate shelf sedimentation through Early Ordovician (and including early Middle Ordovician White Rock?) time represented by the Beekmantown Formation. 2) Emergence of a Beekmantown terrain due to eustatic lowering of sea level and inception of gentle folding in late Early Ordovician (or early Middle Ordovician White Rock?) time. Subsequent erosion of the Beekmantown Formation and development of drainage and topographic relief. Development and filling of the paleodolinen on the topographic high. 3) Transgression of the sea. Previously developed drainage was drowned, evidenced by fining upward of the Cahoon Conglomerate Member into dolomite. Continued development and filling of the paleodolinen on the still exposed topographic high. 4) Development of tidal flats with numerous shoaling episodes as evidenced by fenestral fabrics and crystal silt in the New Market Limestone. Fresh meteoric waters available for crystal silt to fill voids throughout much of New Market time. Continued development and filling of the paleodolinen on the still exposed topographic high. Topographic high exposed until end of New Market time. 5) Beginning of Lincolnshire sedimentation marks complete submergence of topographic high. Deeper water, lower energy environment with abundant argillaceous material being brought into the basin and abundance of mud producing organisms. 6) Development of offshore biostromes as represented by Effna Limestone. Lack of mud may reflect high energy or the absence of mud-producing organisms.
- Calcification by amorphous carbonate precursors: Towards a new paradigm for sedimentary and skeletal mineralizationWang, Dongbo (Virginia Tech, 2010-11-29)A new paradigm for the formation of calcified skeletons suggests mineralization proceeds through amorphous calcium carbonate (ACC) precursors. The implications of this strategy in carbonate crystallization are widespread, particularly for understanding factors controlling impurity and isotopic signatures in calcium carbonates. The first chapter is a literature review of the biomineralization processes used by two important model organisms: the sea urchin larva and the foraminifera. Sea urchin larvae provide a thoroughly studied example of mineralization by an ACC pathway that is under biological control through regulation of protein chemistry and the local mineralization environment. A review of how foraminifera produce their test structures is also examined to explore the question of how organisms regulate the Mg content in proportion to the temperature their environments of formation. The second chapter demonstrates that acidic biomolecules regulate the composition of ACC for a suite of model carboxylated molecules. The physical basis for the systematic trend in Mg content is related to the ability of the affinity of the biomolecule for binding Ca versus Mg. The third chapter builds on these findings to explore the transformation of Mg-rich ACC precursors to calcites of exceptionally high Mg-contents that could not be produced by classical step-dominated growth processes. The data indicate that these materials are likely a result of a nucleation-dominated pathway. The final, fourth chapter develops Raman spectroscopy-based calibrations for determining Mg contents in ACC. The calibrations are based upon peak position or peak width of the carbonate υ₁ stretch.
- Chemostratigraphy of the Early Paleoproterozoic carbonate successions (Kaapvaal and Wyoming cratons)Bekker, Andrey (Virginia Tech, 2001-08-24)Evidence of three glaciations in Paleoproterozoic successions of North America and at least one on three other continents, suggests that these glaciations were of global extent. In common with the Neoproterozoic record, carbonates cap the glacials. However, the relationship between biogeochemical cycling of carbon and ice ages has not been fully appreciated. This research involved the sedimentology and isotope stratigraphy of carbonates and shales in Paleoproterozoic glacially-influenced successions of Wyoming and South Africa. Carbonates of the Vagner Formation cap the middle of three diamictites in the Snowy Pass Supergroup, Medicine Bow Mountains, WY. The Duitschland Formation occurs between two glacial horizons in South Africa. Limestones retain negative d13C values for over 60 m in the Vagner Formation, and for over 100 m in the lower part of the Duitschland Formation. Isotope compositions of TOC from the lower part of the Duitschland Formation reveal pronounced enrichment resulting in significantly lower fractionation between organic and inorganic carbon. This is similar to enrichment noted in Neoproterozoic cap carbonates. Combined with strongly positive carbon isotope compositions in upper Duitschland carbonates, the data from the Vagner Formation underscores strongly positive-to-negative carbon isotope trends bracketing Paleoproterozoic glaciations. These trends mimic those noted in Neoproterozoic glacial successions and possibly indicate a recurrence of global glaciations. The Slaughterhouse and Nash Fork formations significantly postdate the glacial epoch. Both the lower part of the Nash Fork Formation, Medicine Bow Mountains and the Slaughterhouse Formation, Sierra Madre contains carbonates with 13C-enrichment >+6â ° and locally up to +28%, whereas carbonates higher in the Nash Fork Formation have d13C values between 0 and 2.5%. This dramatic change in the composition of the Paleoproterozoic ocean is constrained at ca. 2.1 Ga (Karhu, 1993). Carbonates in the Rawhide Canyon section of the Whalen Group in the Hartville Uplift (the easternmost exposure of the Wyoming Craton) display δ13C values up to +8.2% suggesting correlation with the Slaughterhouse and Nash Fork formations and their deposition on continuous carbonate platform along the margin of the Wyoming Craton. These data support an open-marine, and therefore a global origin for the ca. 2.2-2.1 Ga carbon isotope excursion.
- Chuaria, Vendotaenia, and the taphonomy of the Carbonaceous CompressionAnderson, Evan Pelzner (Virginia Tech, 2010-05-03)Carbonaceous Compressions are a widespread preservational style for fossils, yet their taphonomy remains poorly understood. Previous studies focusing on the taphonomy of carbonaceous compressions have primarily looked at exceptionally preserved faunas in plane view. The precious nature of these fossils leaves destructive techniques of analysis out of the question, but these techniques are necessary if the taphonomy of carbonaceous compressions is to be deciphered. This study analyzes Neoproterozoic carbonaceous compressions from the Yangtze Gorges area in order to address this issue. Chuaria fossils from the Jiulongwan, Sixi, and Sifangtan sections of the Doushantuo Formation and Vendotaenia fossils from the Wuhe and Miaohe sections of the Denying Formation are microchemically analyzed in both plane view and cross section in order to gain a greater understanding of the makeup of carbonaceous compressions. Results confirm and elaborate on previous studies. Likely clay coats are detected on some Chuaria specimens, while they are absent on less thermally mature specimens. Evidence for sulfate reduction in association with carbonaceous compressions is found. Sulfur enrichment, rather than clay coats, is found in association with Vendotaenia fossils. These observations lead to the hypothesis that while organic remains require a very precise set of taphonomic conditions in order to be preserved as carbonaceous compressions, there may be more than one set of conditions that allow for preservation. More studies of a greater taxonomic and taphonomic range of carbonaceous compressions are needed, however, if the mechanisms which control this preservational pathway are to be fully understood.
- Community persistence and the pattern of community variability over time: a test using fossil assemblages from four marine transgressions in the Breathitt Formation (Middle Pennsylvanian) of Eastern KentuckyBennington, J. Bret (Virginia Tech, 1995-11-06)Four intervals of Middle Pennsylvanian marine strata in the Breathitt Formation of eastern Kentucky, the Elkins Fork, Kendrick, Magoffin, and Stoney Fork, were measured, sampled for fossils, and described. Each marine interval was shown to be the product of a single episode of transgression and regression that led to the establishment of a variety of marine habitats in the central Appalachian basin. These habitats included marginal marine, nearshore normal marine, nearshore stressed, offshore normal marine, and offshore dysaerobic environments. Fossil collections were made and species abundance distributions were obtained for each paleontological sample. Multivariate statistical analyses such as cluster analysis and principle components analysis were used to classify fossil assemblages sampled into a variety of paleocommunity types, each associated with a particular lithological facies. Paleocommunity types that were found to occur in more than one of the four marine intervals were resampled at selected localities, with replicate samples taken at each locality. These additional samples were used to test for the presence of the same statistically defmed paleocommunity at different localities within the same marine units and to test for the recurrence of statistically defmed paleocommunities between marine units. Results of the analyses suggest that recurrence of similar fossil assemblages (paleocommunity types) is common in the Breathitt marine units whenever there is recurrence of comparable marine facies. However, recurrence of the same statistically defined paleocommunity is rare, with significant variation in the abundances of member species appearing each time a particular paleocommunity type recurs. This suggests that the recurrence of distinct fossil assemblages over intervals of geologic time can be explained by the repeated reinvasion of suitable habitats by the individual members of a persistent species pool, without recourse to ecological mechanisms needed for preserving or perpetuating particular community structures.
- A comparison of the seismicity and regional geology of the southeastern United States and southeastern AustraliaHunter, Stephen Allen (Virginia Tech, 1981-05-14)The southeastern United States and southeastern Australia are both intraplate regions. They are characterized topographically and geologically by low relief, Paleozoic mountain belts that parallel continental margins formed by rifting. Interestingly, there are also remarkable similarities in the seismicity of the two areas. To characterize the temporal aspects of seismicity, the recurrence relationship, log N (number of earthquakes per year) versus Io (maximum intensity), for southeastern Australia was determined to be: log N = 3.28 - 0.61 Io; III ≤ Io ≤ VII Comparison with a similar relationship for the southeastern United States, log N = 3.01 - 0.59 Io; V ≤ Io ≤ VIII. (Bollinger, G. A., 1973) indicates that both the level of seismic activity and the distribution of earthquakes by size are comparable in the two regions. Additionally, strain release studies for the two regions, while subject to considerable uncertainty, do support that similarity. Note that the intensity X, 1886 Charleston, South Carolina, earthquake was not included in either the recurrence or strain studies. Comparison of the spatial patterns of earthquake epicenters in both regions reveals only weak correlations of the seismicity with topography or with regional geology. There is, however, no apparent correlation with major igneous outcrops or with most major through-going faults. Both regions have seismic zones that are transverse or parallel to the regional geologic trends or tectonic fabrics. The parallel zones are usually associated spatially with severely-faulted regions, suggesting a possible causal relationship. For southeastern Australia, such zones exhibit northeast-trending normal faults of Jurassic age while for the southeastern United States, there are northeast-trending Pennsylvanian-Permian thrust faults. However, no such fault concentrations are found in the transverse seismic zones. Thus, the severely-faulted Source region hypothesis does apply uniformly. Indeed, it may be that, in portions of both of these widely separated geographic regions, the seismic activity is associated with deep crustal features that have no obvious surface expression.
- Contributions to the Neoproterozoic GeobiologyShen, Bing (Virginia Tech, 2007-11-29)This thesis makes several contributions to improve our understanding of the Neoproterozoic Paleobiology. In chapter 1, a comprehensive quantitative analysis of the Ediacara fossils indicates that the oldest Ediacara assemblage "the Avalon assemblage" already encompassed the full range of Ediacara morphospace. A comparable morphospace range was occupied by the subsequent White Sea and Nama assemblages, although it was populated differently. In contrast, taxonomic richness increased in the White Sea assemblage and declined in the Nama assemblage. The Avalon morphospace expansion mirrors the Cambrian explosion, and both may reflect similar underlying mechanisms. Chapter 2 describes problematic macrofossils collected from the Neoproterozoic slate of the upper Zhengmuguan Formation in North China and sandstone of the Zhoujieshan Formation in Chaidam. Some of these fossils were previously interpreted as animal traces. Our study of these fossils recognizes four genera and five species. None of these taxa can be interpreted as animal traces. Instead, they are problematic body fossils of unresolved phylogenetic affinities. Chapter 3 reports stable isotopes of the Zhamoketi cap dolostone atop the Tereeken diamictite in the Quruqtagh area, eastern Chinese Tianshan. Our new data indicate that carbonate associated sulfate (CAS) abundance decreases rapidly in the basal cap dolostone and δ34SCAS composition varies between +9â ° and +15â ° in the lower 2.5 m. In the overlying interval, CAS abundance remains low while δ34SCAS rises ~5â ° and varies more widely between +10â ° and +21â °. δ34Spy is typically greater than δ34SCAS measured from the same samples. We propose that CAS and pyrite were derived from two isotopically distinct reservoirs in a chemically stratified basin. Chapter 4 studies δ13C, δ18O, δ34SCAS, and δ34Spy of the Zhoujieshan cap carbonate that overlies the Ediacaran Hongtiegou glaciation. The Zhoujieshan cap dolostone shows positive δ13C values (0 â 1.7â °). δ34SCAS shows rapid stratigraphic variations from +13.9 to +24.1â °, probably due to relatively low oceanic sulfate concentrations. δ34Spy shows a steady stratigraphic trend. Thus, the δ34SCAS and δ34Spy trends are decoupled from each other. The decoupling of δ34SCAS and δ34Spy trends suggests that CAS and pyrite were derived from different sulfur pools, which were probably due to the postglacial basin stratification.
- Contributions to the Proterozoic and Cambrian Evolution of EukaryotesDong, Lin (Virginia Tech, 2007-03-27)This thesis makes several contributions to improve our understanding of Proterozoic-Cambrian evolution of eukaryote life. Chapter 1 provides, for the first time, a quantitative characterization of the evolutionary trends of Proterozoic macroalgae. The analysis reveals that morphological disparity of Paleoproterozoic macroalgae was low but increased in the Mesoproterozoic and Ediacaran, with a plateau in between. There was also a significant increase in thallus surface/volume ratio and maximum canopy height of the Ediacaran macroalgal communities. The prolonged plateau between the Mesoproterozoic and Ediacaran may be related to either nutrient stress or the absence of animal grazing pressure. The Ediacaran increase in surface/volume ratio and morphological complexity may have been driven by decreasing pCO₂ levels and increasing animal grazing pressure. Chapter 2 presents a systematic re-examination of the carbonaceous compression fossils Protoarenicola baiguashanensis Wang, 1982, Pararenicola huaiyuanensis Wang, 1982, and Sinosabellidites huainanensis Zheng, 1980, from the early Neoproterozoic Liulaobei and Jiuliqiao formations in northern Anhui, North China. These fossils were previously interpreted as worm-like metazoans. Our study reveals new morphological features that weaken the metazoan interpretation. Instead, the new data indicate that these fossils can be alternatively interpreted as erect epibenthic organisms, possibly coenocytic algae. Chapter 3 examines two important eukaryote fossils: Horodyskia Yochelson and Fedonkin, 2000, and Palaeopascichnus Palij, 1976, from the upper Ediacaran chert of the Liuchapo Formation in central Guizhou, South China. These exceptionally preserved fossils offer us a unique opportunity to investigate their body constructions and affinities. The morphologies of Horodyskia and Palaeopascichnus support a phylogenetic relationship with agglutinated foraminifers, shedding new light on the divergence of bikont eukaryotes, the rise of rhizarians, and the ecological importance of heterotrophic eukaryotes in Proterozoic ecosystems. Chapter 4 focuses on Cambrian microfossils that represent the primary producers' cyanobacteria and eukaryotic phytoplankton (acritarchs). Careful investigation of the basal Cambrian Yanjiahe Formation in the Yangtze Gorges area and the Yurtus Formation in the Aksu area revealed abundant acanthomorphic acritarchs, clustered coccoidal microfossils, filamentous cyanobacteria, and tubular microfossils. This study confirms previous stratigraphic correlation between the Yanjiahe and Yurtus formations and suggests that animals and phytoplankton radiated in tandem during the Cambrian explosion.
- Crustal Structure in a Mesozoic Extensional Terrane: The South Georgia Rift and the Epicentral Area of the 1886 Charleston, South Carolina, EarthquakeBuckner, Jesse Conard (Virginia Tech, 2011-01-28)On August 31, 1886 a large scale earthquake occurred in Summerville, S.C. causing severe damage in the coastal city of Charleston. Although intensive geological and geophysical studies have been conducted in the area, uncertainty remains about the details of the event. Recently evidence from seismic reflection profiles have shed light on the tectonic environment of the area. The epicentral area of the 1886 event lies within the South Georgia Rift, a Mesozoic rift terrane. Previous studies have revealed clues to the geologic structure and evolution of this feature. SEISDATA4 is the largest seismic reflection profile recorded in the area. By re-processing the line, information about the tectonic structure of the area was revealed. The early Mesozoic extensional basin that hosted the 1886 earthquake and is host to the modern seismicity recorded in the area, extends several kilometers to the south and west of Charleston, along SEISDATA4. Cenozoic and Mesozoic faults were resolved within the basin and along its northwestern boundary that is distinguished by a strong gradient in the magnetic field. However, the question as to which fault was responsible for the rupture of 1886 still remains. The refraction analysis provides better resolution of the lithology in Lower Mesozoic section. The termination of the strong reflection at the base of the Atlantic Coastal Plain occurs in a section of the profile that shows major disruption of the underlying reflections, and suggests that the termination of a lower Mesozoic basalt flow responsible for the reflection may be related to tectonic deformation.
- Cyclostratigraphy of Late Cambrian cyclic carbonates: An interbasinal field and modelling study, U.S.A.Osleger, David Allen (Virginia Tech, 1990)An interbasinal study of Late Cambrian cyclic carbonate successions in the Appalachian and Cordilleran passive margins, the Texas cratonic embayment and the southern Oklahoma aulacogen has provided controls on the simultaneous development of peritidal to subtidal meter-scale cycles and the larger scale depositional sequences on which they are superimposed. Fining-upward peritidal cycles grade seaward into coarsening-upward, shallow to deep subtidal cycles that form a continuum across the carbonate platforms and are genetically linked to one another by shared lithofacies. Eustacy appears to exert the dominant control on the simultaneous development of peritidal and subtidal cycles on different carbonate platforms. Based on the recognition of dominant periodicities on power spectra derived from time series of subtidal cycles, high frequency eustatic oscillations may be controlled by Milankovitch astronomical rhythms. Interbasinal correlation of Late Cambrian depositional sequences was performed by graphic correlation and the time-equivalent intervals were correlated lithostratigraphically using isochronous biomere boundaries as time datums. Fischer plots of meter-scale cycles define changes in relative sea level based on the amount of extra accommodation space produced by eustacy beyond that provided by subsidence. Residual eustatic curves derived from subsidence analysis are useful for correlating the longer-term Late Cambrian sea level events and changes in the rate of sea level rise and fall can be used to define shorter-term events. Combining the sea level curves defined by Fischer plots and subsidence analysis with paleobathymetric curves of Late Cambrian cyclic strata suggests that the curves may approximate the form of the eustatic sea level curve. A composite "eustatic” sea level curve for the Late Cambrian was created by qualitatively combining the sea level curves defined by the different techniques for each of the four localities. “Eustatic" sea level curves defined by Fischer plots and subsidence analysis may be used to apply sequence stratigraphic concepts to onedimensional outcrop sections. Combined with systematic changes in the stacking patterns of meter-scale cycles, they can be used to define the internal composition of systems tracts, sequence boundaries, and flooding surfaces of third-order depositional sequences. One- and two-dimensional models of peritidal and subtidal cycle development indicate that peritidal cycle thickness is primarily controlled by accommodation space and deeper subtidal cycle thickness is primarily controlled by sedimentation rate. Whereas lithofacies within peritidal cycles alternate in response to fluctuations in sea level, subtidal cycle development may be related to fluctuations in fairweather and storm wave base that oscillate in harmony with sea level fluctuations.
- Depositional Environments and Sequence Stratigraphy of Upper Mississippian Strata in the Central Appalachian BasinMiller, Daniel James (Virginia Tech, 1998-04-30)The Upper Mississippian Hinton, Princeton, and Bluestone formations of southern West Virginia constitute a wedge of strata that filled the Appalachian basin over a ~7 million year time interval. Seventeen transgressive-regressive sequences comprise the study interval in the basin depocenter. Five sequence types defined by the degree of incision and the thickness/ character of dominant facies include: 1) major incised valley-fill to coastal plain, 2) major incised valley-fill to deltaic, 3) minor incised valley-fill, 4) coastal plain, and 5) marine-dominated sequences. Transgressive and highstand deposits within several sequences contain tidal rhythmites. The prodeltaic Pride Shale member (Bluestone Formation) preserves a hierarchy of submillimeter-to meter-scale cycles that reflect a spectrum of tidal periodicities. The abbreviated character of these microlaminated rhythmites is suggestive of a distal, subtidal setting wherein neap tides were of insufficient strength to transport sand/ silt. Decimeter-scale bundling of semimonthly cycles is ascribed to seasonal fluvial discharge. Meter-scale, multi-year cycles may reflect the 18.6-year lunar nodal cycle. Sequence development likely reflects fourth-order (~400 k.y.), Gondwanan glacioeustatic cycles. The character and relative stratigraphic position of paleoclimatic indicators within the sequences suggests a link between eustasy and patterns of global-scale atmospheric circulation. Calcic vertisols and lacustrine carbonates in coastal plain successions are suggestive of seasonal, semiarid climatic conditions during highstand progradation. Leached paleosols and coals that underlie sequence boundaries and occur within estuarine fills are suggestive of humid conditions during late highstand through early transgression. This pattern may reflect fluctuations in monsoonal circulation whereby the latitudinal shift of seasonal moisture was restricted to the equatorial zone during glaciations. The fourth-order sequences stack into two (2-4 Ma) composite sequences that consist of: 1) a basal retrogradational interval comprised of a major paleovalley-fill sequence overlain by a thick aggradational sequence set made up of fluvial/ coastal plain sequences (TST); 2) a marine interval that demarcates maximum flooding; and 3)(where preserved) a progradational sequence set consisting of minor incised valley-fill sequences (HST). These composite sequences document accommodation change that may reflect global tectono-eustasy.
- Development of cyclic ramp-to-basin carbonate deposits, lower Mississippian, Wyoming and MontanaElrick, Maya (Virginia Tech, 1990-07-01)The Lower Mississippian Lodgepole/lower Madison Formations (20-225 m thick) developed along a broad (>700 km) stormdominated cratonic ramp. Three types of shallowing-upward cycles (5th order) are recognized across the ramp-to-basin transition. Peritidal cycles consist of very shallow subtidal facies overlain by algal-laminated tidal flat deposits, which are rarely capped by paleosol/breccia layers. Shallow subtidal cycles consist of stacked ooid grainstone shoal deposits or deeper subtidal facies overlain by ooid-skeletal grainstone caps. Deep subtidal cycles occur along the outer ramp and ramp-slope and consist of sub-storm wave base limestone-argillite, overlain by graded limestone, and are capped by storm-deposited skeletal-ooid grainstone. They pass downslope into rhythmically interbedded limestone and argillite with local deepwater mud mounds; no shallowing-upward cycles occur within the ramp-slope facies. Average cycle periods calculated along the outer ramp range from 30-110 k.y. The cycles likely formed in response to 5th order (20-100 k.y.) sea level oscillations. The cycles are stacked to form three 3rd to 4th order depositional sequences which are defined by regional transgressive-regressive facies trends. The ramp margin wedge (RMW) developed during long-term sea level fall lowstand conditions and consists of cyclic crinoidal bank and oolitic shoal facies which pass downdip into deep subtidal cycles. The transgressive systems tract (TST),which onlapped the ramp during long-term sea level rise, includes thick deep and shallow subtidal cycles; peritidal cycles are restricted to the inner ramp. The highstand systems tract (HST) developed during long-term sea level highstand and fall, and along the ramp is composed of early HST shallow subtidal cycles which are overlain by late HST peritidal cycles; shallow through deep subtidal cycles composed the HST along the ramp-slope.
- Ecological, Evolutionary, and Taphonomic Comparisons of Brachiopods and Bivalves at Multiple Spatial and Temporal ScalesKrause, Richard Alan (Virginia Tech, 2006-04-14)The fossil record is the primary source of information on the history of life. As such, it is important to understand the limitations of this record. One critical area in which there is still much work to be done is in understanding how the fossil record, and our interpretation of it, may be biased. Herein, the fidelity between the life and death assemblage of an extant brachiopod with respect to morphological variability is studied using geometric morphometrics. The results from several analyses confirm a high degree of morphological variability with little change in mean shape between the living and sub-fossil assemblage. Additionally, there is no evidence of distinct morphogroups in either assemblage. These trends persist at all depths and size classes indicating that this species could be recognized as a single, rather than multiple, species if only fossil data were available. The second chapter involves the recognition and quantification of a worker bias in monographs of brachiopods and bivalves. Most specimens studied came from the 65th to 69th percentile of their species' bulk-collected size-frequency distribution. This indicates a significant bias toward monograph specimens that are larger than the mean size of the bulk sample. When compared at the species level, this bias was found to be highly consistent among the 86 species included in the study. Thus, size measurements of monographed specimens reliably and consistently record a similar size class for any given species, and this bias is easily corrected during meta-analyses. Chapter three focuses on bivalves and brachiopods from a modern tropical shelf and quantifies the magnitude of time averaging (temporal mixing) for these two different organisms. This is accomplished by dating a suite of shells from each site using amino acid racemization calibrated with several radiocarbon dates. By studying the age distributions for each species it is determined that, despite some site to site differences, both bivalve and brachiopod species exhibit a similar time averaging magnitude when collected from the same region or depositional system. This indicates that fossil assemblages of these species may have very similar resolution.
- Establishing a Baseline for Kinetic and Thermodynamic Origins of Vital Effects: Toward an Understanding of Factors Controlling Mg Signatures in CalciteStephenson, Allison Elaine (Virginia Tech, 2009-05-06)Elemental proxy models for temperature and seawater chemistry begin by assuming compositional signatures reflect environmental conditions of formation. The Mg/Ca ratio in marine cements and calcified skeletal structures is a widely used proxy for reconstructing past earth environments. Many studies have positively correlated Mg content in biogenic carbonates with temperature, but it is difficult to differentiate the effect of temperature from other environmental factors. Supersaturation, precipitation rate, salinity, pH, and ion concentration have also been proposed as drivers of Mg/Ca. Furthermore, it is difficult to distinguish environmental signatures from the “vital effect,” or the influences superimposed by the growth needs and metabolic activities of the organism. To construct viable paleoenvironmental proxies from biomineral compositions, we must resolve the effects of environmental conditions from the vital effects of the organism by first understanding the underlying thermodynamic and kinetic mechanisms for incorporating minor and trace elements. Using in situ Atomic Force Microscopy, controlled solution chemistries, and different ion microprobe techniques, this dissertation investigates the kinetics and thermodynamics of calcite growth to establish an inorganic baseline for uptake of Mg. I use this information to quantify the enhancement in Mg/Ca due to the presence of hydrophilic 27-mer peptides, demonstrating a possible origin of vital effects. Likewise I measure the effect of ionic strength on signatures and find that growth rate and background electrolyte proved more important than salinity in determining Mg contents. The findings contribute to the ongoing discussion regarding the relative importance of unique seawater parameters in determining Mg/Ca in calcite. Mg contents are significantly enhanced by biomolecules relative to the amounts attributed to temperature differences, while Mg content is less influenced by salinity variation than by changing supersaturation or driving force. In addition to sorting out the relative importance of environmental factors, our results begin to address the interplay of these different parameters in concert, and at different scales. At sites of calcification, the local biochemistry within an organism may shift in response to more saline waters. At a geological scale, interpreting past temperatures and particularly those of the Last Glacial Maximum depends on our ability to sort out and account for this interplay of salinity and temperature on Mg/Ca. Processes underlying inorganic and biogenic carbonate mineralization and interpretations of their formation environments are better understood by examining the influence of environmental parameters and biomolecular chemistry on kinetics and thermodynamics of calcite growth and stability.
- Evolution of early Proterozoic passive-margin carbonate platform, Rocknest Formation, Wopmay Orogen, N.W.T., CanadaGrotzinger, John P. (Virginia Polytechnic Institute and State University, 1985)The superbly exposed Rocknest Formation, Wopmay Oroqen, N.W.T., Canada, is an early Proterozoic (l.B9 Ga) passivemargin carbonate platform. It is an eastward-thinning prism, 0 to 1,100 m thick, extending for over 220 km parallel to strike, and over 200 k.m perpendicular to strike. It contains from west to east, slope, outer-shelf, shoaloomplex, and inner-shelf facies. Slope facies are rhythmites, megabreccias and rhythmite breccias. Outershelf faciea include stromatolitic reefal boundstone and backreef ooid/intraclast grainstore. Shoal-complex facies are shallowing-upward cycles of tufa, cryptalgalaminite, laminated dolosiltite/lutite, overlain by tepees, breccias and pisolite; these formed a paleotopographic high, restricting an eastern "lagoon" from western ocean. Innershelf facies are dominantly asymmetric, shallowing-upward cycles of "lagoonal" mixed carbonates and siliciclastics, that grade up into intertidal stromatolitic dolomites; cyclic facies pass eastward into non—cyclic siliclastics of central and eastern "lagoon". The shelf was terminally drovmed during attempted subduction of the margin. Individual cycles are correlatable for over 200 km parallel to strike and over 120 Ion perpendicular to strike. Cycles formed in response to small, asymmetric (rapid rise/slow fall) eustatic oscillaticns in sea-level (= 10 m). An alpine glacio-eustatic model accounts for the origin of cycles best. During sea-level rise, rapid transgression and submergence of tidal flats occurred along eastern margin of the shoal-complex, followed by eastward expansion of the shoal—complex, and slow progradation of tidal flats over lagoonal facies during sea-level fall. Computer modelling of Rocknest cycle types across the platform provides important information on absolute l sedimentation rates and lag times.
- Experimental Study of the PVTX Properties of the System H₂O-CH₄Lin, Fang (Virginia Tech, 2005-09-23)The system H₂O-CH₄ is found in a variety of geological environments in the earth’s crust, from sedimentary basins to low grade metamorphic terrains. Knowledge of the PressureVolume-Temperature-Composition (PVTX) properties of the H₂O-CH₄ system is necessary to understand the role that these fluids play in different geological environments. In this study the properties of the H₂O-CH₄ fluid system at elevated temperatures and pressures has been investigated experimentally to determine the PVTX properties of H₂O-CH₄ fluids in the P-T range equivalent to late diagenetic to low grade metamorphic environments, and XCH₄≤4mol%. A study has also been conducted to determine methane hydrate stability over the temperature range of -40~20°C. Synthetic fluid inclusions were employed in both studies as miniature autoclaves. Experimental data for the PVTX properties of H₂O-CH₄ fluids under late diagenetic to low grade metamorphic conditions was used to calculate the slopes of isoTh lines (the line connecting the P-T conditions of the inclusions at formation and at homogenization) at different PTX conditions. An empirical equation to describe the slope of iso-Th line as a function of homogenization temperature and fluid composition was developed. The equation is applicable to natural H₂O-CH₄ fluid inclusions up to 500°C and 3 kilobars, for fluid compositions ≤4 mol% CH₄. The Raman peak position of CH₄ gas is a function of the pressure and temperature. This relationship was used to determine the pressure along the methane hydrate stability curve in the H₂O-CH₄ system. The combined synthetic fluid inclusion, microthermometry and Raman spectroscopy method is a novel experimental approach to determine the P-T stability conditions of methane hydrates. The method is fast compared to conventional methods, and has the potential to be applied to study other gas hydrate systems.
- Facies, Sequence Framework, and Evolution of Rudist Buildups, Shu'aiba Formation, Saudi ArabiaAl-Ghamdi, Nasser Mohammad (Virginia Tech, 2006-05-19)The Cretaceous (Early Aptian) Shu'aiba Formation, Shaybah field, Saudi Arabia, is 60 km long by 12 km wide and 150 m thick, and is a giant carbonate reservoir. It formed on a regional carbonate ramp bordering an intrashelf basin. The succession consists of a composite sequence of seven high frequency sequences. Sequences 1 and 2 formed a deeper open platform of Palorbitolina-Lithocodium wackestone, with maximum flooding marked by planktic foram mudstone. Sequence 2 built relief over northern and southern blocks, separated by an intraplatform depression. They form the composite sequence TST. The remaining sequences developed a platform rimmed by rudist rudstone backed by rudist floatstone back-bank and lagoonal fine skeletal peloidal packstone; slope facies are fine skeletal fragmented packstone. Aggradational sequences 3 to 5 make up the composite sequence early highstand. Progradational sequences 6 and 7 are the composite sequence late highstand marking the deterioration of the Offneria rudist barrier and deposition of widespread lagoonal deposits, where accommodation may have been created by syn-depositional growth faulting that moved the northern block down. Shu'aiba deposition on the platform was terminated by long-term sea-level fall and karsting. The succession is dominated by approximately 400 k.y., 4th order sequences and 100 k.y. parasequences driven by long term eccentricity and short term eccentricity respectively, similar to the Pacific guyots of this age. This suggests that early Cretaceous climate may have been cooler and had small ice sheets and was not an ice-free greenhouse world.
- Geologic evolution of the Archean Buhwa Greenstone Belt and surrounding granite-gneiss terrane, southcentral ZimbabweFedo, Christopher M. (Virginia Tech, 1994-09-05)The Archean (~3.0 Ga) Buhwa Greenstone Belt, and surrounding granite-gneiss terrane, is the least understood major greenstone belt in the Archean Zimbabwe Craton, despite occupying a critical position between an early Archean continental nucleus and the Limpopo Belt. The cover succession in the Buhwa Greenstone Belt, which was probably deposited on the margin of this nucleus, is divisible into shelfal and basinal facies associations separated by a transitional facies association. The shelfal association consists mostly of quartzarenite and shale, but also contains a thick succession of iron-formation. Geochemical characteristics of the shales indicate that the source terrane consisted of several lithologies including tonalite, mafic-ultramafic volcanic rocks, and granite that underwent intense chemical weathering. Basinal deposits consist dominantly of greenstones, with less abundant chert and ironformation. The cover succession, which was deposited on a stable shelf transitional to deep water, has no stratigraphic equivalents elsewhere on the Archean Zimbabwe Craton. However, time and lithologic correlatives in the central zone of the Limpopo The Archean (-3.0 Ga) Buhwa Greenstone Belt, and surrounding granite-gneiss terrane, is the least understood major greenstone belt in the Archean Zimbabwe Craton, despite occupying a critical position between an early Archean continental nucleus and the Limpopo Belt. The cover succession in the Buhwa Greenstone Belt, which was probably deposited on the margin of this nucleus, is divisible into shelfal and basinal facies associations separated by a transitional facies association. The shelfal association consists mostly of quartzarenite and shale, but also contains a thick succession of iron-formation. Geochemical characteristics of the shales indicate that the source terrane consisted of several lithologies including tonalite, mafic-ultramafic volcanic rocks, and granite that underwent intense chemical weathering. Basinal deposits consist dominantly of greenstones, with less abundant chert and ironformation. The cover succession, which was deposited on a stable shelf transitional to deep water, has no stratigraphic equivalents elsewhere on the Archean Zimbabwe Craton. However, time and lithologic correlatives in the central zone of the Limpopo ~2.9 Ga in southern Africa. At ~2.9 Ga, the northern margin of the greenstone belt experienced kilometerscale, oblique-slip dextral shearing. This shear zone and the surrounding margins of the greenstone belt were later intruded by the ~2.9 Ga Chipinda batholith, which ranges from granitic to tonalitic in composition. A number of events occurred during the time period spanning 2.9-2.5 Ga and current geochronology cannot separate their order; some are known to be coeval. Crustal shortening to the northwest, which resulted in map-scale folding of the cover succession (and surrounding batholith) and greenschist-facies metamorphism, occurred along a set of discrete high-angle reverse-sense shear zones in response to uplift the Northern Marginal Zone of the Limpopo Belt over the Zimbabwe Craton. Two suites of potassic granites were intruded into the area near the end of reverse shearing. Analysis of a conjugate fault pair that is developed within one of the potassic granite suites, yields a principal compressive stress consistent with continued northwest-directed crustal shortening. The region was stabilized by ~2.5 Ga, with intrusion of the Great Dyke of Zimbabwe. It is possible that the last events to affect the area, which include sinistral shearing, transecting cleavage development, and northwest-striking open folding, took place during the 2.9-2.5 Ga time intervaL These structures post-date regional folding and metamorphism, but because of limited magnitude and extent, do not show obvious cross-cutting relationships with other rocks or structures. A tenable alternative is that these late structures formed at ~2.0 Ga. an age that is proving to be of great significance in the evolution of the Limpopo Belt and along parts of the southern margin of the Zimbabwe Craton.
- The Global Detrital Zircon Database: Quantifying the Timing and Rate of Crustal GrowthVoice, Peter James (Virginia Tech, 2010-05-04)Published detrital zircon geochronological data was compiled to form the Global Detrital Zircon Database (GDZDb). This database provides a reference block for provenance analysis by future detrital zircon geochronological studies. This project entailed three subprojects: 1. crustal growth/crustal recycling patterns, 2. a provenance study of the Triassic Dry Fork Formation of the Danville-Dan River Rift basin of Virginia and North Carolina, and 3. sample size issues in detrital zircon studies. The global detrital zircon age frequency distribution exhibits six prominent, statistically significant peaks: 3.2-3.0, 2.7-2.5, 2.0-1.7, 1.2-1.0, 0.7-0.5, and 0.3-0.1 Ga. These peaks are also observed when the data is sorted for continent of origin, the tectonic setting of the host sediment and for modern river sediments. Hf isotope model ages were also incorporated into the database where grains were dated with both U-Pb and Hf isotopes. The Hf isotope model ages suggest that the majority of detrital zircons U-Pb ages reflect crustal recycling events that generated granitic magmatism, as most grains exhibited Hf isotope ages that are much older than the corresponding U-Pb age. The Triassic Dry Fork Formation was sampled from a site in southern Virginia in the Danville-Dan River Basin. The detrital zircon age frequency distribution for this formation was strongly unimodal with a peak at 400-450 Ma and a paucity of Grenville-age zircons. Comparison of the Dry Fork sample to published east coast data and to the North American record (from the GDZDb) illustrate the unusual nature of the Dry Fork Formation sample. It is probable that older Grenville zircons were blocked from the rift valley by the rift shoulder. Using the GDZDb a study of sample size was conducted in order to estimate the best sample size to use when trying to constrain the maximum age of sedimentation of the host sediment. Rift basins and active margins exhibited smaller offsets from the youngest zircon grain age to host sediment maximum age than observed in samples from passive margins. This study recommends that at least 50 grains need to be age dated on average in order to best constrain the age of the host sediment.
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