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Browsing by Author "Sarver, Emily Allyn"

Now showing 1 - 5 of 5
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    Effects of Dust Controls and Dust Sources on Respirable Coal Mine Dust Characteristics
    Animah, Festus Ayinimi (Virginia Tech, 2024-10-14)
    Respirable coal mine dust (RCMD) continues to pose serious health hazards to workers. Over the past few decades, new regulations, monitoring technologies, and improved dust controls have emerged, and all are based on the presumption that limiting RCMD on the basis of mass will effectively mitigate the exposure hazards. Given the latency of exposure outcomes, it will be some time before the full impact of these strategies can be evaluated. In the meantime, there is increasing awareness that RCMD particle characteristics, in addition to mass, might be important. This dissertation comprises four separate studies which explore the effects of primary RCMD sources and/or engineering controls on particle size and constituents. To enable a direct comparison of dust generation from primary dust sources, a field study was conducted to investigate the dust generation and particle characteristics between coal and the rock strata. Results indicated that finer and more dust was generated when mining predominantly into the rock strata versus the coal strata, while the operation of a flooded bed scrubber and an increase in water sprays pressure and volume generally suppressed dust. Prior government research, conducted within the Mining Research Division of the National Institute of Occupational Safety and Health (NIOSH) evaluated the dust mass concentrations removal efficiency of different dust controls (i.e., a dry and wet scrubber, canopy air curtain, and a wet versus dry dust collection boxes). In the second and third studies, preserved samples from these prior NIOSH dust control studies were re-analyzed and evaluated to understand their effects on dust characteristics. Results indicated that the efficiency of dust controls was particle size dependent, as these controls mostly showed no appreciable effects on dust constituents. Generally, the cleaning of dust from a novel wet dust collection box versus a traditional dry dust box led to a reduction in operator exposure to hazardous dust. In the final study, a laboratory prototype flooded bed scrubber was evaluated to understand its efficiency on dust between different particle size bins (i.e., by particle count) ranging from 0.3-10 µm. From the results, removal efficiencies were generally low – and sometimes negative, for dust particles mostly in each of the size bins less than 2 µm. The results presented here highlight the need to holistically evaluate dust controls to understand their efficiency on dust of different particle sizes and constituents, so that informed decisions can be made on the best controls to adopt in mine operations.
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    Investigating the Effects of Particle Loading and Agglomeration on Respirable Coal Mine Dust Particle Classification by SEM-EDX
    Sweeney, Daniel Joseph (Virginia Tech, 2024-06-03)
    Respirable coal mine dust (RCMD) still poses serious occupational health hazards to coal miners and can lead to incurable lung diseases such as coal workers' pneumoconiosis (CWP, also referred to as "black lung"). Further, CWP can develop into a more severe form known as progressive massive fibrosis (PMF). There has been a resurgence of PMF since the late 1990s. Coal miners are also exposed to crystalline silica, which can lead to a lung disease known as silicosis. While coal mining related disease is on the rise, the historic dust monitoring data does not indicate such a striking resurgence. As a result, there has been an increased interest in research surrounding RCMD to understand exposure as well as prevent health effects. Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX) is a powerful tool that can analyze RCMD on a particle-level. The images produced by the SEM can size and characterize morphology of micron and submicron-sized particles. In addition, the EDX can determine elemental content, which can be used to infer mineralogy. However, particle classification can be impacted by interferences due to particle loading density (PLD) and agglomeration. PLD refers to the number of particles per unit area of substrate, while agglomeration describes clustered or overlapping particles. This thesis includes two studies aimed at exploring the effects of both PLD and agglomeration on SEM-EDX analysis. Study 1 includes an investigation into the effect of PLD on RCMD classification by SEM-EDX analysis. Dust recovered from the sample parent filters under low and high PLD conditions were used to isolate the effect of PLD. The comparison between the low and high PLD filters was then used to establish modified classification criteria to correct for high PLD. When the modified criteria were then applied to RCMD particles analyzed direct-on-filter, minimal change was observed in the apparent mineralogy distributions for most samples. These results suggest that particle agglomeration may have substantial effects on the particle classification of respirable dust analyzed direct-on-filter. Study 2 includes an investigation into the effect of particle agglomeration on RCMD by SEM-EDX analysis. Automated and manual SEM-EDX analysis was performed on paired filters collected from a parent filter. The manual analysis targeted respirable silica containing agglomerates. Each pair consisted of a filter analyzed directly and a filter that underwent a recovery process to deposit dust particles onto a new filter. The mineralogy distributions from the automated analysis suggest that agglomeration affects sizing and particle classification. Based on the manual analysis, there was an apparent increase in independent silica and a decrease in respirable silica-containing agglomerates after the recovery process. A limited collection of passive samples revealed more agglomerates than on the filters that were collected using a pump and size-selector cyclone. The work in this thesis is relevant to the research efforts aimed at the resurgence of coal mining related lung diseases, as the use of SEM-EDX can characterize RCMD by geographic region, geology, and location within a mine. Future work in this area of study might look at methods to estimate PLD in the field, other dust recovery methods, and a comparison of sampling methods.
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    Rapid FTIR analysis for respirable crystalline silica monitoring in coal mines using readily available sampling equipment
    Elie, Garek Christopher (Virginia Tech, 2024-07-01)
    In coal mines, workers can be exposed to respirable coal mine dust (RCMD) in conjunction with respirable crystalline silica (RCS). Overexposure can pose serious health risks, including development of coal workers' pneumoconiosis (CWP) (also known as "black lung"). CWP has the potential to progress to a more consequential form known as progressive massive fibrosis (PMF), for which a dramatic resurgence has been observed among US miners since the early 2000's. Recent rules promulgated by the Mine Safety and Health Administration (MSHA) have lowered the permissible exposure limit (PEL) of RCMD and RCS, but the nuances of dust monitoring are complicated. For RCMD, frequent monitoring is required using the continuous personal dust monitor (CPDM), which enables real time data—but the physical sample collected by the CPDM cannot currently be used for RCS analysis. For RCS monitoring, filter samples are still collected with the traditional coal mine dust personal sampling unit (CMDPSU)—but the standard RCS analysis must be done in a centralized lab and there is considerable lag time between sampling and data availability. To enable rapid RCS analysis of filter samples, NIOSH has developed a direct-on-filter (DOF) Fourier transform infrared (FTIR) spectroscopy method for use with CMDPSU filter samples. It can be performed in the field with a portable instrument. NIOSH has also developed a compatible software called the Field Analysis of Silica Tool (FAST), which simplifies processing of the FTIR spectral data to yield RCS mass results. While not allowed to demonstrate regulatory compliance with the RCS PEL, this method could be quite useful for routine non-regulatory monitoring (e.g., to support research or engineering studies). However, adoption of the method may hinge on a variety of factors such as costs, ease-of-use, and the usability and reliability of generated data. This thesis reports a field study designed to demonstrate how the DOF FTIR method (with FAST) might be used by mines with relatively low-cost, off-the-shelf sampling components for the CMDPSU. The field study also demonstrates how the percentage of RCS in RCMD (in addition to RCS mass) can be estimated by simply pairing a CPDM with the CMDPSU during sampling. Understanding RCS percentage may be important for a variety of research or engineering applications. While the DOF FTIR method can work well for CMDPSU samples, it is recognized that RCS analysis of CPDM samples would be ideal. However, the materials and construction of the filter assembly used by the CPDM is not conducive to DOF analysis. As part of an effort to develop a simple method for CPDM sample recovery, redeposition, and analysis by FTIR, the second study in this thesis focused on establishing the recovery procedure—and corrections to account for sample mass and RCS content attributed to any residue sourced from the CPDM filter assembly itself. Using blank CPDM filters and blank CPDM filters spiked with well characterized respirable dust, results show that the mass and RCS content of the CPDM residue may be quite small. Moreover, using field CPDM samples, results show that dust recovery can be quite high. Taken together, these are promising findings and suggest that a method for RCS analysis of CPDM samples is possible.
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    Toward Rapid Silica Analysis of CPDM Samples using Portable Fourier Transform Infrared Spectrometry
    Greth, August Vidal (Virginia Tech, 2024-10-21)
    Continuous personal dust monitors (CPDMs) are widely used to monitor respirable coal mine dust (RCMD) to reduce miners' exposures, but they are unable to directly assess respirable crystalline silica (RCS) concentrations, which are linked to the recent rise of respiratory diseases among coal miners. This incompatibility is due to the composition of the CPDM's internal filter stub. The stub consists of a fibrous borosilicate filter attached to a polypropylene (PP) backing and a polytetrafluoroethylene (PTFE) binder, which interferes with standard analytical techniques. This study developed a method for indirect analysis of dust collected on the CPDM filter stub using portable direct-on-filter Fourier Transform infrared spectroscopy (DOF-FTIR) to rapidly quantify quartz, the primary analyte of silica in coal mines. The research consisted of four studies that developed and evaluated a three-step process for dust recovery, deposition, and analysis. These studies investigated techniques for separating dust from the CPDM filter media, compared mechanisms for dust deposition onto various substrates, and assessed the ability of FTIR and scanning electron microscopy with energy dispersive X-ray (SEM-EDX) to analyze the mineral characteristics of recovered dust. The resulting method involves submerging CPDM filter stubs in 5 mL of isopropyl alcohol (IPA) and shaking them for 1 minute, followed by deposition of the dust onto a 25-mm polyvinyl chloride (PVC) filter using a syringe-based system. The PVC filter was then scanned at four 8-mm offset locations at 90° intervals from the center. Evaluating this method using field and lab-generated CPDM filter stubs revealed low dust recovery from the stubs. It was also observed that results tended to underpredict the quartz mass as the total sample mass increased. Though adjustments for recovery can be made using a scale and the method can be limited to lower mass samples, more efforts can be made to investigate better dust recovery and improve quartz determination of the samples to increase confidence in the method.
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    Understanding Mechanisms of Water Lead Contamination by Nitrate Spallation Corrosion and Lead Removal by Point-of-Use (POU) Filters
    Villalona, Chantaly (Virginia Tech, 2024-06-25)
    Lead enters drinking water by a process of corrosion, dissolution or particle detachment from lead bearing plumbing materials. Preventing contamination of water from lead-tin solder corrosion and achieving effective removal of particulate lead by point-of-use (POU) filters are important public health goals. These topics are especially timely given forthcoming revisions to the Lead and Copper Rule and ongoing efforts to reduce lead levels at the tap. Recently a switch from non-corrosive groundwater to a surface water source at a utility in Illinois caused unusual drinking water contamination from the release of large lead solder chunks from plumbing to water. Point-of-use (POU) filters distributed to remove the lead at this utility and elsewhere were not always completely effective. Here, we elucidate the mechanism of lead solder release in two chapters, followed by two more chapters examining lead removal by POU filters. The lead solder contamination arose after the water utility switched sources from high sulfate and low nitrate groundwater to a surface water with lower sulfate and high nitrate during runoff events. Such problems were unexpected because the surface water with high nitrate was not considered corrosive according to current theory. A chapter entitled A Novel Mechanism of Lead-Tin Solder Spallation in the Presence of Nitrate describes how 1) nitrate is extremely corrosive to lead:tin solder galvanically connected to copper, 2) nitrate corrosion can sometimes cause detachment of solder chunks to water, and 3) nitrate corroded the metal by reduction to ammonia and other reaction products. Another Chapter reports a follow up study, that reproduced the essence of nitrate induced spallation corrosion as observed in homes, using copper pipe with beads of lead-tin solder attached. During a 4-month experiment, the non-corrosive groundwater with high sulfate caused no solder beads to detach and only about 1% of the total lead was released to water. But in the surface water with high nitrate believed to cause the lead problem, 100% of the solder beads detached after just two months, and 80% of the total lead in the solder was released to water after 4 months. In the same surface water that had lower nitrate, with or without zinc orthophosphate or polyphosphate inhibitors, only 8 to 17% of the solder beads detached. Electrochemical studies also found that equimolar concentrations of chloride did not cause the disintegration of tin solder or as much weight loss as nitrate. Moreover, sulfate concentrations as low as 0.75 mM could effectively inhibit tin corrosion caused by 10 mg/L NO3-N. Studies focused on efficacy of POU filters have indicated that soluble lead in water is reliably removed, but sometimes particulate lead can escape capture and contaminate the treated water. To better understand this issue and practical limitations of filter use, field studies were performed in occupied and unoccupied homes in Enterprise, LA and New Orleans under both normal and extreme conditions of water lead contamination. For severe lead contamination present after lead pipes were disturbed or when a very long lead service line was present, and filters were tested to 200% of their rated capacity, the treated water occasionally had more than 15 ppb lead even when a very high percentage of the lead was removed. In Enterprise and New Orleans water with more typical levels of influent lead, the treated water was always below 1 ppb lead. But in Enterprise water with high iron and manganese the filters clogged quickly, causing higher costs for filtered water and consumer dissatisfaction. The occasional problems in removing particulate lead observed in this and prior research gave impetus to a series of bench-scale experiments elucidating particulate lead removal mechanisms by conventional ion-exchange media in sodium (Na+), strong acid (H+), chloride (Cl-) or strong base (OH-) form. Suspensions of lead phosphate particles of varying sizes and age revealed marked differences in dissolution rates under acidic, circa neutral and basic pHs that are caused by treatment with H+, Na +, OH -, Cl- form resin. Fresh nanoparticle lead phosphate particles were very labile, and immediately dissolved at pH 4 to form soluble Pb+2 ions which were quickly removed by strong acid media. High pHs > 10 and phosphate removal by OH– form resin could also dissolve the particles, and then remove the anionic soluble lead formed at high pHs. Na+ and Cl- resin caused little or no dissolution at the circa neutral pHs associated with their use and had lower rates of lead removal from water as a result. Older lead phosphate particles acquired from a New York City harvested lead pipe loop rig or purposefully synthesized in the laboratory, did not dissolve as readily as fresh nanoparticles which profoundly affected their relative removal efficiency by the different media. Overall, dissolution of lead phosphate particles in the ion-exchange media can sometimes have a range of important effects that can enhance or hinder lead removal dependent on circumstance. This thesis enhances our understanding of water lead contamination mechanisms by spallation of lead-tin solder and factors affecting lead removal by some POU filters. These novel insights can be helpful in preventing and mitigating future water lead contamination events.