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Browsing by Author "Sendula, Eszter"

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    Metasomatism-induced wehrlite formation in the upper mantle beneath the Nograd-Gomor Volcanic Field (Northern Pannonian Basin): Evidence from xenoliths
    Patko, Levente; Liptai, Nora; Aradi, Laszlo Elod; Klébesz, Rita; Sendula, Eszter; Bodnar, Robert J.; Kovacs, Istvan Janos; Hidas, Karoly; Cesare, Bernardo; Novak, Attila; Trasy, Balazs; Szabo, Csaba (2020-05)
    Clinopyroxene-enriched upper mantle xenoliths classified as wehrlites are common (similar to 20% of all xenoliths) in the central part of the Nograd-Gomor Volcanic Field (NGVF), situated in the northern margin of the Pannonian Basin in northern Hungary and southern Slovakia. In this study, we thoroughly investigated 12 wehrlite xenoliths, two from each wehrlite-bearing occurrence, to determine the conditions of their formation. Specific textural features, including clinopyroxene-rich patches in an olivine-rich lithology, orthopyroxene remnants in the cores of newly-formed clinopyroxenes and vermicular spinel forms all suggest that wehrlites were formed as a result of intensive interaction between a metasomatic agent and the peridotite wall rock. Based on the major and trace element geochemistry of the rock-forming minerals, significant enrichment in basaltic (Fe, Mn, Ti) and high field strength elements (Nb, Ta, Hf, Zr) was observed, compared to compositions of common lherzolite xenoliths. The presence of orthopyroxene remnants and geochemical trends in rock-forming minerals suggest that the metasomatic process ceased before complete wehrlitization was achieved. The composition of the metasomatic agent is interpreted to be a mafic silicate melt, which was further confirmed by numerical modelling of trace elements using the plate model. The model results also show that the melt/rock ratio played a key role in the degree of petrographic and geochemical transformation. The lack of equilibrium and the conclusions drawn by using variable lherzolitic precursors in the model both suggest that wehrlitization was the last event that occurred shortly before xenolith entrainment in the host mafic melt. We suggest that the wehrlitization and the Plio-Pleistocene basaltic volcanism are related to the same magmatic event.
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    Role of fluids in geological processes
    Sendula, Eszter (Virginia Tech, 2021-01-12)
    Water and other volatiles (e.g. CO2, H2, CH4, etc.) are crucial components on Earth that ensure the habitability of the planet and play an important role in many geological processes. Small aliquots of these fluids can be preserved in the geological record as fluid inclusions and can provide valuable information about the physical and chemical environment in which they formed. The ocean is the largest water reservoir on the Earth's surface, and seawater participates in important water-rock reactions such as hydrothermal alteration of the ocean floor, a process that is currently in the spotlight for hypotheses on the origin of life, as it is an environment where generation of abiotic carbohydrates occur. The ocean chemistry varied in the geologic past to reflect major changes in the intensity of weathering, rates of midocean ridge hydrothermal discharge, changes in the climate and atmospheric CO2 concentration, and also played an important part in mass extinction events. Understanding the history of Earth's ancient oceans may hold the key to answer some of the important questions about the future of the Earth. Today, oceans hold valuable resources, such as offshore basalt formations which have been considered for submarine CO2 sequestration to mitigate greenhouse gas emissions associated with global warming. In the chapters of this dissertation, the reader will be presented with studies using fluid inclusions to advance our knowledge about the chemical evolution of seawater and reaction kinetics involving CO2, seawater and olivine – an abundant mineral in the oceanic lithosphere. Chapter I "Redox conditions in Late Permian seawater based on trace element ratios in fluid inclusions in halite from the Polish Zechstein Basin" describes application of a new redox proxy for paleo-seawater that involves analysis of redox-sensitive trace elements (e.g., Fe, Mn, U, V, Mo) in ancient seawater trapped as fluid inclusions in halite. Chapter II "Partitioning behavior of trace elements during evaporation of seawater" investigates the behavior of trace elements during the evaporation of seawater. This information is required to interpret trace element data from fluid inclusions in halite. In Chapter III "In situ monitoring of the carbonation of olivine under conditions relevant to carbon capture and storage using synthetic fluid inclusion micro-reactors: Determination of reaction rates", fluid inclusions are used as micro-reactors to monitor the reaction progress of olivine carbonation in situ and in real time at elevated temperatures (50-200 °C) and pressures using non-destructive analytical techniques such as Raman spectroscopy.
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    Shift in the Raman symmetric stretching band of N-2, CO2, and CH4 as a function of temperature, pressure, and density
    Sublett, D. Matthew, Jr.; Sendula, Eszter; Lamadrid, Hector M.; Steele-MacInnis, Matthew; Spiekermann, Georg; Burruss, Robert C.; Bodnar, Robert J. (2020-03)
    The Raman spectra of pure N-2, CO2, and CH4 were analyzed over the range 10 to 500 bars and from -160 degrees C to 200 degrees C (N-2), 22 degrees C to 350 degrees C (CO2), and -100 degrees C to 450 degrees C (CH4). At constant temperature, Raman peak position, including the more intense CO2 peak (nu+), decreases (shifts to lower wave number) with increasing pressure for all three gases over the entire pressure and temperature (PT) range studied. At constant pressure, the peak position for CO2 and CH4 increases (shifts to higher wave number) with increasing temperature over the entire PT range studied. In contrast, N-2 first shows an increase in peak position with increasing temperature at constant pressure, followed by a decrease in peak position with increasing temperature. The inflection temperature at which the trend reverses for N-2 is located between 0 degrees C and 50 degrees C at pressures above similar to 50 bars and is pressure dependent. Below similar to 50 bars, the inflection temperature was observed as low as -120 degrees C. The shifts in Raman peak positions with PT are related to relative density changes, which reflect changes in intermolecular attraction and repulsion. A conceptual model relating the Raman spectral properties of N-2, CO2, and CH4 to relative density (volume) changes and attractive and repulsive forces is presented here. Additionally, reduced temperature-dependent densimeters and barometers are presented for each pure component over the respective PT ranges. The Raman spectral behavior of the pure gases as a function of temperature and pressure is assessed to provide a framework for understanding the behavior of each component in multicomponent N-2-CO2-CH4 gas systems in a future study.