Browsing by Author "Whitehill, Andrew"

Now showing 1 - 2 of 2
  • Thumbnail Image
    Can Column Formaldehyde Observations Inform Air Quality Monitoring Strategies for Ozone and Related Photochemical Oxidants?
    Travis, K. R.; Judd, L. M.; Crawford, J. H.; Chen, Gao; Szykman, James; Whitehill, Andrew; Valin, Lukas C.; Spinei, Elena; Janz, Scott; Nowlan, Caroline R.; Kwon, Hyeong-Ahn; Fried, Alan; Walega, James (American Geophysical Union, 2022-07-16)
    Formaldehyde column density (omega HCHO) showed a potentially useful correlation with surface ozone during the LISTOS campaign on Long Island Sound and the KORUS-AQ campaign in Seoul, South Korea. This builds on previous work that identified this relationship from in situ aircraft observations with similar findings for ground-based and airborne remote sensing of omega HCHO. In the Long Island Sound region, omega HCHO and surface ozone exhibited strong temporal (r(2) = 0.66) and spatial (r(2) = 0.73) correlation. The temporal variability in omega HCHO (similar to 1 Dobson units [DU]) was larger than the range in the spatial average (similar to 0.1 DU). The spatial average is most useful for informing ozone monitoring strategies, demonstrating the challenge in using omega HCHO satellite data sets for this purpose. In Seoul, high levels of NO2 resulted in O-x better correlating with omega HCHO than surface ozone due to titration effects. The omega HCHO-O-x relationship may therefore reflect the sum of surface ozone and related photochemical oxidants, relevant to air quality standards set to regulate this quantity such as the U.S. EPA National Ambient Air Quality Standard (NAAQS). The relationship of omega HCHO to O-x shifted in Seoul during the campaign demonstrating the need to evaluate this relationship over longer time periods. With sufficient precision in future satellite retrievals, omega HCHO observations could be useful for evaluating the adequacy of surface air quality monitoring strategies.
  • Thumbnail Image
    Effect of polyoxymethylene (POM-H Delrin) off-gassing within the Pandora head sensor on direct-sun and multi-axis formaldehyde column measurements in 2016-2019
    Spinei, Elena; Tiefengraber, Martin; Mueller, Moritz; Gebetsberger, Manuel; Cede, Alexander; Valin, Luke; Szykman, James; Whitehill, Andrew; Kotsakis, Alexander; Santos, Fernando; Abbuhasan, Nader; Zhao, Xiaoyi; Fioletov, Vitali; Lee, Sum Chi; Swap, Robert (2021-01-28)
    Analysis of formaldehyde measurements by the Pandora spectrometer systems between 2016 and 2019 suggested that there was a temperature-dependent process inside the Pandora head sensor that emitted formaldehyde. Some parts in the head sensor were manufactured from the thermal plastic polyoxymethylene homopolymer (E.I. Du Pont de Nemour & Co., USA; POM-H Delrin (R)) and were responsible for formaldehyde production. Laboratory analysis of the four Pandora head sensors showed that internal formaldehyde production had exponential temperature dependence with a damping coefficient of 0.0911 +/- 0.0024 degrees C-1 and the exponential function amplitude ranging from 0.0041 to 0.049 DU. No apparent dependency on the head sensor age and heating and cooling rates was detected. The total amount of formaldehyde internally generated by the POM-H Delrin components and contributing to the direct-sun measurements were estimated based on the head sensor temperature and solar zenith angle of the measurements. Measurements in winter, during colder (< 10 degrees C) days in general, and at high solar zenith angles (> 75 degrees) were minimally impacted. Measurements during hot days (> 28 degrees C) and small solar zenith angles had up to 1 DU (2.69 x 10(16 )molec. cm(-2)) contribution from POM-H Delrin parts. Multi-axis differential slant column densities were minimally impacted (< 0.01 DU) due to the reference spectrum being collected within a short time period with a small difference in head sensor temperature. Three new POM-H Delrin free Pandora head sensors (manufactured in summer 2019) were evaluated for temperature-dependent attenuation across the entire spectral range (300 to 530 nm). No formaldehyde absorption or any other absorption above the instrumental noise was observed across the entire spectral range.