Scholarly Works, Mining and Minerals Engineering
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Browsing Scholarly Works, Mining and Minerals Engineering by Subject "0914 Resources Engineering and Extractive Metallurgy"
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- Acid Leaching of Rare Earth Elements from Coal and Coal Ash: Implications for Using Fluidized Bed Combustion To Assist in the Recovery of Critical MaterialsHonaker, Rick; Zhang, Wencai; Werner, Joshua (American Chemical Society, 2019-07-18)High temperature pretreatment of coal-based mineral matter in an oxidizing environment significantly enhances the leaching characteristics of rare earth elements (REEs). A research study has found that the temperatures used in fluidized-bed combustion (FBC) of coal to produce electricity are near optimum for pre-treating the associated mineral matter prior to leaching to maximize the recovery of critical materials. Tests were performed on representative samples collected from preparation plants treating West Kentucky No. 13, Illinois No. 6, and Fire Clay coal seam sources as well as fly ash and bed ash samples from two FBC power plants. Acid leaching tests using 1.2M HCl at 75℃ were performed on both the coal and the FBC ash samples. Prior to leaching, the coal samples were pretreated at temperatures of 600℃, 750℃, and 900℃ in an oxidizing environment to study the effect on leaching characteristics. The results showed that pretreatment at 600℃ for 2 hours resulted in a significant increase in REE recovery from a range of 20-40% to about 80% for all coal sources. The leaching kinetics are characterized by a quick release of rare earth elements within the first few minutes of the process. For the West Kentucky No. 13 coal source, about 75% of REEs were leached in the first 15 min from the 1.4-1.8 specific gravity (SG) fraction that was calcined at 600℃. Additionally, the leaching kinetics of the major contaminant, i.e., Fe, were much lower than the REEs, which significantly benefits the efficiency of leaching and the downstream upgrading processes. REE leaching characteristics of the FBC ash samples were similar to that of the calcined coals. Mineralogy characterization showed that the degree of crystallinity for both the calcined coal and FBC samples were similar to the original associated mineral matter, which provided evidence for the advantage of using the FBC by- products as REE feedstocks over pulverized coal boilers that utilize temperatures greater than 1200℃. These findings were used to develop a conceptual flowsheet that incorporates FBC technology and its typical combustion environment to enhance the feasibility of recovering critical materials from coal-based sources.
- The Effect of Conditioning on the Flotation of Pyrrhotite in the Presence of ChloriteChen, Yanfei; Shi, Qing; Feng, Qiming; Lu, Yiping; Zhang, Wencai (MDPI, 2017-07-20)The influence of conditioning on the flotation of pyrrhotite in the presence of chlorite was investigated through flotation tests, sedimentation tests, and X-ray photoelectron spectroscopy (XPS) analysis. The flotation results show that chlorite slimes dramatically impair the flotation of pyrrhotite. Sedimentation and flotation tests reveal that conditioning can effectively remove chlorite slimes from pyrrhotite surfaces, resulting in an enhanced flotation recovery of pyrrhotite. When mixed minerals were conditioned under the natural atmosphere, a faster conditioning speed and longer conditioning time decreased the flotation recovery of pyrrhotite. However, when mixed minerals were conditioned under a nitrogen atmosphere, a more intensive conditioning process provided better flotation results. XPS analyses illustrate that a faster conditioning speed and longer conditioning time under the natural atmosphere accelerates the oxidation of pyrrhotite, leading to a decrease in the flotation recovery of pyrrhotite.
- Effects of contaminant metal ions on precipitation recovery of rare earth elements using oxalic acidZhang, Wencai; Noble, Aaron; Ji, Bin; Li, Qi (2022-01-01)Solution equilibrium calculations were performed in this study to understand the impact of contaminant metal ions on the precipitation efficiency of selected rare earth elements (Ce3+, Nd3+, and Y3+) using oxalic acid as a precipitant. Trivalent metal ions, Al3+ and Fe3+, were found to considerably affect the precipitation efficiency of REEs. When Al3+ and Fe3+ concentrations were increased by 1 × 10−4 mol/L, in order to achieve an acceptable cerium recovery of 93% from solutions containing 1 × 10−4 mol/L Ce3+, oxalate dosage needed to increase by 1.2 × 10−4 and 1.68 × 10−4 mol/L, respectively. Such great impacts on the required oxalate dosage were also observed for Nd3+ and Y3+, which indicates that oxalic acid consumption and cost will be largely increased when the trivalent metal ions exist in REE-concentrated solutions. Effects of the divalent metal ions on the oxalate dosage is minimal. Furthermore, solution equilibrium calculation results showed that the precipitation of Fe3+ and Ca2+ (e.g., hematite and Ca(C2O4)∙H2O(s)) likely occurs during the oxalate precipitation of REEs at relatively high pH (e.g., pH 2.5), which will reduce rare earth oxalate product purity. In addition to the metal ions, anionic species, especially SO42−, were also found to negatively affect the precipitation recovery of REEs. For example, when 0.1 mol/L SO42− occurs in a solution containing 1 × 10−4 mol/L Ce3+ and 4 × 10−4 mol/L oxalate, the pH needed to be elevated from 2.0 to 3.3 to achieve the acceptable recovery. Overall, findings from this study provide guidance for the obtainment of high-purity rare earth products from solutions containing a considerable amount of contaminant metal ions by means of oxalic acid precipitation.
- Flotation separation of scheelite from calcite using mixed collectorsYan, Weiping; Liu, Cheng; Ai, Guanghua; Feng, Qiming; Zhang, Wencai (Elsevier, 2017-12)Flotation separation of scheelite from calcite is difficult due to the similarities in their surface properties. In this work, the flotation behavior of scheelite and calcite using oxidized paraffin soap(OPS), benzohydroxamic acid(BHA) and the mixed OPS/BHA collectors was investigated through micro-flotation experiments. The flotation results of single mineral experiments demonstrated a higher selectivity for the flotation of scheelite from calcite at pH 9 than individual OPS and BHA when using water glass as depressant. In order to probe the validity of the findings, mixed binary minerals experiments, contact angle and zeta potential experiments were also carried out successfully.
- Leaching recovery of rare earth elements from the calcination product of a coal coarse refuse using organic acidsJi, Bin; Li, Qi; Zhang, Wencai (Elsevier, 2022-02-01)Due to the increasing criticality of rare earth elements (REEs), it has become essential to recover REEs from alternative resources. In this study, systematic REEs leaching tests were performed on the calcination product of a coal coarse refuse using hydrochloric acid and different types of organic acid as lixiviants. Experimental results show that the recovery of REEs, especially heavy REEs (HREEs) and scandium (Sc), is improved by using selected organic acids. Citric acid and DL-malic acid afford the best leaching performances; whereas, malonic acid, oxalic acid, and DL-tartaric acid are inferior to hydrochloric acid. Results of zeta potential measurements and solution chemical equilibrium calculations show that malonic acid is more likely adsorbed on the surface of the calcined material compared with citric acid and DL-malic acid. The adsorption may reduce the effective concentration of malonic species in solution and/or increase the amount of REEs adsorbed on the surface, thereby impairing the leaching recovery. Compared with light REEs (LREEs), a stronger adsorption of the HREEs on the surface is observed from electro-kinetic test results. This finding explains why organic acids impose a more positive impact on the leaching recovery of HREEs. By complexing with the HREEs, organic acids can keep the metal ions in solution and improve the leaching recovery. The adsorption of Sc3+ on the surface is the lowest compared with other REEs. Therefore, rather than complexing, the organic anionic species likely play a function of solubilizing Sc from the solid, which is similar to that of hydrogen ions.
- Notes on the Potential for the Concentration of Rare Earth Elements and Yttrium in Coal Combustion Fly AshHower, James; Groppo, John; Henke, Kevin; Hood, Madison; Eble, Cortland; Honaker, Rick; Zhang, Wencai; Qian, Dali (MDPI, 2015-06-23)Certain Central Appalachian coals, most notably the Fire Clay coal with a REY-enriched volcanic ash fall tonstein, are known to be enriched in rare earth elements. The Fire Clay tonstein has a greater contribution to the total coal + parting REY than would be inferred from its thickness, accounting for about 20%–35% of the REY in the coal + parting sequence. Underground mining, in particular, might include roof and floor rock and the within-seam partings in the mined product. Beneficiation, necessary to meet utility specifications, will remove some of the REY from the delivered product. In at least one previously published example, even though the tonstein was not present in the Fire Clay coal, the coal was enriched in REY. In this case, as well as mines that ship run-of-mine products to the utility, the shipped REY content should be virtually the same as for the mined coal. At the power plant, however, the delivered coal will be pulverized, generally accompanied by the elimination of some of the harder rock, before it is fired into the boiler. Overall, there are a wide range of variables between the geologic sample at the mine and the power plant, any or all of which could impact the concentration of REY or other critical materials in the coal combustion products.
- Particle size and mineralogy distributions in respirable dust samples from 25 US underground coal minesSarver, Emily A.; Keles, Cigdem; Ghaychi Afrouz, Setareh (Elsevier, 2021-11-01)Detailed characterization of respirable coal mine dust is critical to understanding occupational health outcomes, as well as improving exposure monitoring and dust controls in mines. However, data on characteristics such as particle size and mineralogy are still scarce, and there are virtually no datasets available that allow direct comparisons across many mines. Following up on a previous effort to characterize dust from eight underground mines in the Appalachian region of the United States, the current study expands the dataset to cover a total of 25 mines across the country. A total of 171 respirable dust samples were collected in standard locations of each mine and analyzed by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). Results demonstrate that significant differences in particle size and mineralogy distributions exist both within and between mines based on sampling location, mine region and/or mining method–and characteristics can be indicative of dust sources. In locations nearby to production or roof bolting, the respirable dust was clearly sourced from the mine strata. Interestingly, in the production location rock-strata sourced dust appeared to be inordinately abundant relative to the actual coal and rock strata heights being mined during sampling. With respect to particle size, diesel particulates and coal dust were generally found to be finer than mineral dust; and mineral dust likely sourced from the rock strata in the mine was finer than that associated with rock dusting products. On average, when considering all particles analyzed between 100 and 10,000 nm, results indicate that about 75% are in the submicron range, however these particles are estimated to account for only about 6% of the mass.
- Study on the activation mechanism of lead ions in wolframite flotation using benzyl hydroxamic acid as the collectorLiu, Cheng; Zhang, Wencai; Song, Shaoxian; Li, Hongqiang (Elsevier, 2019-09)The activation mechanism of Pb(II) on the flotation of wolframite was systematically investigated. Micro-flotation test results showed that Pb(II) effectively improved the flotation of wolframite in the presence of benzyl hydroxamic acid (BHA). Maximum floatability of wolframite was achieved at approximately pH 8.5. Adsorption of the hydrolyzed species of Pb(II) occurred at this pH value, which provided more activated sites on the wolframite surface. As such, BHA-Pb complexes were formed on the wolframite surface, which increased the BHA adsorption. In addition, BHA-Pb complexes were also formed in solution, which replaced the Fe and interacted with the Mn on the wolframite surface. These findings were proved by the results of zeta-potential measurements, adsorption measurements, solution chemistry calculations, Fourier transform infrared spectroscopy (FTIR) analysis, and X-ray photoelectron spectroscopy (XPS) characterization.