Study on the activation mechanism of lead ions in wolframite flotation using benzyl hydroxamic acid as the collector

Files
TR Number
Date
2019-09
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier
Abstract

The activation mechanism of Pb(II) on the flotation of wolframite was systematically investigated. Micro-flotation test results showed that Pb(II) effectively improved the flotation of wolframite in the presence of benzyl hydroxamic acid (BHA). Maximum floatability of wolframite was achieved at approximately pH 8.5. Adsorption of the hydrolyzed species of Pb(II) occurred at this pH value, which provided more activated sites on the wolframite surface. As such, BHA-Pb complexes were formed on the wolframite surface, which increased the BHA adsorption. In addition, BHA-Pb complexes were also formed in solution, which replaced the Fe and interacted with the Mn on the wolframite surface. These findings were proved by the results of zeta-potential measurements, adsorption measurements, solution chemistry calculations, Fourier transform infrared spectroscopy (FTIR) analysis, and X-ray photoelectron spectroscopy (XPS) characterization.

Description
Keywords
Mining & Metallurgy, 0306 Physical Chemistry (incl. Structural), 0904 Chemical Engineering, 0914 Resources Engineering and Extractive Metallurgy
Citation