Virginia Tech
    • Log in
    View Item 
    •   VTechWorks Home
    • ETDs: Virginia Tech Electronic Theses and Dissertations
    • Doctoral Dissertations
    • View Item
    •   VTechWorks Home
    • ETDs: Virginia Tech Electronic Theses and Dissertations
    • Doctoral Dissertations
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Electrochemical Studies of Copper-Activation of Sphalerite and Pyrite

    Thumbnail
    View/Open
    title.PDF (3.759Kb)
    Downloads: 43
    abstract.PDF (34.73Kb)
    Downloads: 75
    chapter1.PDF (60.71Kb)
    Downloads: 96
    chapter2.PDF (279.8Kb)
    Downloads: 89
    chapter3.PDF (72.71Kb)
    Downloads: 103
    chapter4.PDF (165.5Kb)
    Downloads: 107
    chapter5.PDF (103.1Kb)
    Downloads: 71
    chapter6.PDF (72.08Kb)
    Downloads: 495
    chapter7.PDF (254.8Kb)
    Downloads: 277
    chapter8.PDF (29.84Kb)
    Downloads: 321
    appendix.PDF (30.99Kb)
    Downloads: 54
    vita.PDF (3.892Kb)
    Downloads: 39
    Date
    1998-08-07
    Author
    Chen, Zhuo
    Metadata
    Show full item record
    Abstract
    Carbon matrix composite (CMC) electrode and surface conducting (SC) electrode have been developed to study the copper-activation and the subsequent xanthate adsorption on insulating sphalerite. Fabricating CMC electrode involves embedding sphalerite particles in carbon to form a carbon matrix composite; and SC electrode is designed by contacting a platinum wire to the sphalerite surface. When these electrodes are activated by heavy metal ions such as copper, a conducting layer is formed on the mineral surfaces that allows dynamic electrochemical studies to be conducted. Voltammetric studies on the copper activated CMC:ZnS electrodes in inert electrolytes show that although the activation product and kinetics may differ with pH, copper-activation occurs at all pH ranges. At acidic pH, a Cu2S-like activation product was formed at open circuit. When activation was conducted at near neutral and alkaline pH at open circuit, the surface products formed were identified to be CuS-like. It was also established that the amount of copper uptaken by sphalerite is strongly dependent on the time of activation and on the electrochemical potential applied during activation. Activation at potentials positive of the rest potential decreases the amount of copper on the surface. Indeed, activation at potentials of 50 to 100 mV more positive of the rest potential in the activating solution completely inhibits copper activation. This result is consistent with the anodic stripping voltammetry that shows copper can be removed from the surface of sphalerite at oxidizing potentials. Activation at potentials mildly negative of the rest potential causes a progressive increase in the amount of copper on the surface, consistent with the diffusion controlled reduction process between ZnS and Cu2+ ions observed in the activating solution. At very low potentials, however, elemental copper is formed, which may worsen the selectivity of the sphalerite flotation. Controlled potential contact angle measurements showed that xanthate adsorption does occur on copper-activated sphalerite at all pH ranges. However, the contact angles and flotation recovery decrease at near neutral pH. This problem is caused by the adsorption of the copper-hydroxy species on the activated sphalerite surface. It was found that addition of small amount of complexing reagent can improve the flotation recovery at the near neutral pH. The results obtained in the present work show that potential control of the activation process can provide a means of controlling copper uptake and, hence, the selectivity and recovery of sphalerite flotation. The development of CMC:ZnS and SC:ZnS electrodes provides a practical and reliable way to quantitatively estimate the amount of copper uptake on sphalerite surface after activation.
    URI
    http://hdl.handle.net/10919/27142
    Collections
    • Doctoral Dissertations [15775]

    If you believe that any material in VTechWorks should be removed, please see our policy and procedure for Requesting that Material be Amended or Removed. All takedown requests will be promptly acknowledged and investigated.

    Virginia Tech | University Libraries | Contact Us
     

     

    VTechWorks

    AboutPoliciesHelp

    Browse

    All of VTechWorksCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsThis CollectionBy Issue DateAuthorsTitlesSubjects

    My Account

    Log inRegister

    Statistics

    View Usage Statistics

    If you believe that any material in VTechWorks should be removed, please see our policy and procedure for Requesting that Material be Amended or Removed. All takedown requests will be promptly acknowledged and investigated.

    Virginia Tech | University Libraries | Contact Us