Manufacture of and Environmental Effects on Carbon Fiber-Reinforced PhenylEthynyl-Terminated Poly(EtherImide)
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Thermal characterization of neat and CFR 2.5kPETU via differential scanning calorimetry, dynamic mechanical thermal analysis, and parallel plate rheometry resulted in an understanding of the influence of cure time and temperature on reaction progress via both reaction kinetics and monitoring of the glass transition temperature. From the rheological characterization, a two-stage, dual-Arrhenius model was developed to successfully model isothermal complex viscosity over the range of processing temperatures.
Neat 2.5kPETU and CFR 2.5kPETU specimens were exposed separately to elevated temperature environments of different moisture and different oxygen concentrations to evaluate the effects of moisture absorption, moisture desorption, and thermal oxidation on material properties. Moisture absorption took place in a 90 Â°C / 85% relative humidity environment followed by moisture desorption in a 90 Â°C / 10% relative humidity environment. Thermal-oxidative aging for up to 5000 hours took place at 204 204 Â°C in environments of four different oxygen partial pressures: 0.0 kPa, 2.84 kPa, 20.2 kPa, and 40.4 kPa. Following exposure to the different aging environments, the specimens were tested for retention of mechanical properties. In addition, moisture sorption properties were measured.
Results from the moisture sorption studies on CFR 3kPETU and CFR 2.5kPETU suggest that fully cured composites will withstand moisture absorption and desorption with negligible effects on mechanical properties, whereas, lack of full cure allows moisture sorption to permanently damage the composites. Despite a lack of mass loss or visual evidence of degradation following thermal-oxidative aging, a decline in mechanical properties was observed with the reduction becoming greater with longer aging times and higher oxygen partial pressures.
- Doctoral Dissertations