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A new Ru (II) Rh (III) bimetallic with a single Rh-Cl bond as a supramolecular photocatalyst for proton reduction

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dc.contributor.authorZhou, Rongweien
dc.contributor.authorManbeck, Gerald F.en
dc.contributor.authorWimer, Dexter G.en
dc.contributor.authorBrewer, Karen J.en
dc.contributor.departmentChemistryen
dc.date.accessed2016-03-17en
dc.date.accessioned2016-03-18T22:24:57Zen
dc.date.available2016-03-18T22:24:57Zen
dc.date.issued2015-07-01en
dc.description.abstractA new RuIIRhIII structural motif [(bpy)2Ru(dpp)RhCl(tpy)]4+ with one halide on the RhIII center demonstrates light-driven proton reduction ability, establishing that two halide ligands are not mandatory despite all prior systems containing a cis-RhCl2 catalytic site. This new design provides a novel approach to modulate RhIII redox behavior and catalytic activity with insight into catalytic intermediates.en
dc.description.notesContains supplementary information fileen
dc.description.notes2015 Royal Society of Chemistry Open Access Gold Articleen
dc.description.sponsorshipUnited States. Department of Energy. Office of Basic Energy Sciences. Chemical Sciences, Geosciences and Biosciences Divisionen
dc.format.extent4 p.en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationZhou, R., Manbeck, G. F., Wimer, D. G., & Brewer, K. J. (2015). A new Ru (II) Rh (III) bimetallic with a single Rh-Cl bond as a supramolecular photocatalyst for proton reduction. Chemical Communications, 51(65), 12966-12969. doi:10.1039/C5CC04123Fen
dc.identifier.doihttps://doi.org/10.1039/C5CC04123Fen
dc.identifier.issn1359-7345en
dc.identifier.issue65en
dc.identifier.other2015_Zhou_A_new_RuII_RhIII_bimetallic.pdfen
dc.identifier.otherNew_RuIIRhIII_bimetallic_supp_info.pdfen
dc.identifier.otherDE FG02-05-ER15751en
dc.identifier.urihttp://hdl.handle.net/10919/64971en
dc.identifier.volume51en
dc.language.isoenen
dc.publisherThe Royal Society of Chemistryen
dc.rightsCreative Commons Attribution-NonCommercial 3.0 Unporteden
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/en
dc.titleA new Ru (II) Rh (III) bimetallic with a single Rh-Cl bond as a supramolecular photocatalyst for proton reductionen
dc.title.serialChemical Communicationsen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten

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