Influence of buried hydrogen-bonding groups within monolayer films on gas-surface energy exchange and accommodation

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dc.contributorVirginia Techen
dc.contributor.authorFerguson, M. K.en
dc.contributor.authorLohr, J. R.en
dc.contributor.authorDay, Brian Scotten
dc.contributor.authorMorris, J. R.en
dc.contributor.departmentChemistryen
dc.date.accessed2013-12-10en
dc.date.accessioned2013-12-10T17:31:17Zen
dc.date.available2013-12-10T17:31:17Zen
dc.date.issued2004-02-20en
dc.description.abstractSelf-assembled monolayers (SAMs) of carbonyl-containing alkanethiols on gold are employed to explore the influence of hydrogen-bonding interactions on gas-surface energy exchange and accommodation. H-bonding, COOH-terminated SAMs are found to produce more impulsive scattering and less thermal accommodation than non-H-bonding, COOCH3-terminated monolayers. For carbamate-functionalized SAMs of the form Au/S(CH2)(16)OCONH(CH2)(n-1)CH3, impulsive scattering decreases and accommodation increases as the H-bonding group is positioned farther below the terminal CH3.en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationFerguson, MK ; Lohr, JR ; Day, BS ; et al., Feb 20, 2004. “Influence of buried hydrogen-bonding groups within monolayer films on gas-surface energy exchange and accommodation,” PHYSICAL REVIEW LETTERS 92(7): 073201. DOI: 10.1103/PhysRevLett.92.073201en
dc.identifier.doihttps://doi.org/10.1103/PhysRevLett.92.073201en
dc.identifier.issn0031-9007en
dc.identifier.urihttp://hdl.handle.net/10919/24492en
dc.identifier.urlhttp://link.aps.org/doi/10.1103/PhysRevLett.92.073201en
dc.language.isoenen
dc.publisherAmerican Physical Societyen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjectself-assembled monolayersen
dc.subjectcollisionsen
dc.subjectau(111)en
dc.subjectchainen
dc.subjectgolden
dc.subjectPhysicsen
dc.titleInfluence of buried hydrogen-bonding groups within monolayer films on gas-surface energy exchange and accommodationen
dc.title.serialPhysical Review Lettersen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten

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